The present work discusses a systematic approach to model grinding parameters of coal in a ball mill. A three level Box-Behnken design combined with response surface methodology using second order model was applied to...The present work discusses a systematic approach to model grinding parameters of coal in a ball mill. A three level Box-Behnken design combined with response surface methodology using second order model was applied to the experiments done according to the model requirement. Three parameters ball charge （numbers 10-20）, coal content （100-200 g） and the grinding time （4-8 rain） were chosen for the experiments as well as for the modeling work. Coal fineness is defined as the dso （80 % passing size）. A quadratic model was developed to show the effect of parameters and their interaction with fineness of the product. Three different sizes （4, 1 and 0.65 mm） of Indian coal were used. The model equations for each fraction were developed and different sets of experiments were performed. The predicted values of the fineness of coal were in good agreement with the experimental results （R2 values of dso varies between 0.97 and 0.99）. Fine size of three different coal sizes were obtained with larger ball charge with less grinding time and less solid content. This work represents the efficient use of response surface methodology and the Box-Behnken design use for grinding of Indian coal.展开更多
In order to apply grinding method for degradation of pentachlorophenol(PCP) to an industrial scale,the proportion of different materials[CaO,SiO_2 and CO(NH_2)_2]and the size of grinding balls were examined.For saving...In order to apply grinding method for degradation of pentachlorophenol(PCP) to an industrial scale,the proportion of different materials[CaO,SiO_2 and CO(NH_2)_2]and the size of grinding balls were examined.For saving energy and increasing dechlorination efficiency,the rotation speed and grinding time were maintained at relatively low values.At a mass ratio of grinding balls to materials(40:1),PCP was added into a big steel jar(300 ml) with other materials to grind at 300 r ·min^(-1)for 5 h.The results indicated that when PCP was mixed with CaO and SiO_2in a molar ratio of 1:60:60,the best dechlorination of 58.4%was achieved.CO(NH_2)_2 could not be used as hydrogen donor in the dehalogenation by mechanochemical reaction,since it restrained the dechlorination process.The size of grinding balls has significant effect on the reaction.The experiment with 5 mm steel balls indicates that the weight is too light to provide appropriate energy for the reaction,while steel balls of 10 and 15 mm could give better dechlorination reaction.It indicates that dechlorination depends on the mass of balls and fill rate.展开更多
In this study, pyrolusiteore （MnO2） was subjected to mechanical milling with a high-energy mill with carbonized tea plant wastes and the effect of grinding time on the crystal structure of the material was investiga...In this study, pyrolusiteore （MnO2） was subjected to mechanical milling with a high-energy mill with carbonized tea plant wastes and the effect of grinding time on the crystal structure of the material was investigated. The ratio of Mn/Fe was 8/1, the ratio of C/（MnO2 ＋ Fe3O4） was 2 and the ratio of ball to ore was 10/1. The samples were mechanically ground at 10, 15, 20, 30, 60, 90 and 120 hours. In the processes performed on the attritor, the rotation speed of the mill shaft was determined to be 350 rpm. The results were characterized by TG-DTA, SEM and XRD analyzes. As a result of the experimental studies, it was observed that the samples subjected to mechanical grinding for 120 hours were gradually reduced due to the increasing grinding time at all the diffraction peaks when the XRD peaks were compared with the grinding times. In the thermogravimetric analysis, the sample milled for 120 hours, 50% weight loss was observed at 470 ℃, weight loss of up to 56% was observed at progressive temperatures.展开更多
文摘The present work discusses a systematic approach to model grinding parameters of coal in a ball mill. A three level Box-Behnken design combined with response surface methodology using second order model was applied to the experiments done according to the model requirement. Three parameters ball charge （numbers 10-20）, coal content （100-200 g） and the grinding time （4-8 rain） were chosen for the experiments as well as for the modeling work. Coal fineness is defined as the dso （80 % passing size）. A quadratic model was developed to show the effect of parameters and their interaction with fineness of the product. Three different sizes （4, 1 and 0.65 mm） of Indian coal were used. The model equations for each fraction were developed and different sets of experiments were performed. The predicted values of the fineness of coal were in good agreement with the experimental results （R2 values of dso varies between 0.97 and 0.99）. Fine size of three different coal sizes were obtained with larger ball charge with less grinding time and less solid content. This work represents the efficient use of response surface methodology and the Box-Behnken design use for grinding of Indian coal.
文摘In order to apply grinding method for degradation of pentachlorophenol(PCP) to an industrial scale,the proportion of different materials[CaO,SiO_2 and CO(NH_2)_2]and the size of grinding balls were examined.For saving energy and increasing dechlorination efficiency,the rotation speed and grinding time were maintained at relatively low values.At a mass ratio of grinding balls to materials(40:1),PCP was added into a big steel jar(300 ml) with other materials to grind at 300 r ·min^(-1)for 5 h.The results indicated that when PCP was mixed with CaO and SiO_2in a molar ratio of 1:60:60,the best dechlorination of 58.4%was achieved.CO(NH_2)_2 could not be used as hydrogen donor in the dehalogenation by mechanochemical reaction,since it restrained the dechlorination process.The size of grinding balls has significant effect on the reaction.The experiment with 5 mm steel balls indicates that the weight is too light to provide appropriate energy for the reaction,while steel balls of 10 and 15 mm could give better dechlorination reaction.It indicates that dechlorination depends on the mass of balls and fill rate.
文摘In this study, pyrolusiteore （MnO2） was subjected to mechanical milling with a high-energy mill with carbonized tea plant wastes and the effect of grinding time on the crystal structure of the material was investigated. The ratio of Mn/Fe was 8/1, the ratio of C/（MnO2 ＋ Fe3O4） was 2 and the ratio of ball to ore was 10/1. The samples were mechanically ground at 10, 15, 20, 30, 60, 90 and 120 hours. In the processes performed on the attritor, the rotation speed of the mill shaft was determined to be 350 rpm. The results were characterized by TG-DTA, SEM and XRD analyzes. As a result of the experimental studies, it was observed that the samples subjected to mechanical grinding for 120 hours were gradually reduced due to the increasing grinding time at all the diffraction peaks when the XRD peaks were compared with the grinding times. In the thermogravimetric analysis, the sample milled for 120 hours, 50% weight loss was observed at 470 ℃, weight loss of up to 56% was observed at progressive temperatures.
