Here we report a quantitative study of the orientational structure and motion of water molecule at the air/water interface. Analysis of Sum Frequency Generation （SFG） vibrational peak of the free O-H stretching band...Here we report a quantitative study of the orientational structure and motion of water molecule at the air/water interface. Analysis of Sum Frequency Generation （SFG） vibrational peak of the free O-H stretching band at 3700 cm^-1 in four experimental configurations showed that orientational motion of water molecule at air/water interface is libratory within a limited angular range. The free OH bond of the interracial water molecule is tilted around 33°from the interface normal and the orientational distribution or motion width is less than 15°. This picture is significantly different from the previous conclusion that the interracial water molecule orientation varies over a broad range within the ultrafast vibrational relaxation time, the only direct experimental study concluded for ultrafast and broad orient, ational motion of a liquid interface by Wei et al. （Phys. Rev. Lett. 86, 4799, （2001）） using single SFG experimental configuration.展开更多
This study proposes a new approach in which an impermeable plate is placed under the pipeline to prevent the local scour around the pipeline.In order to understand the performance of this approach,the finite volume me...This study proposes a new approach in which an impermeable plate is placed under the pipeline to prevent the local scour around the pipeline.In order to understand the performance of this approach,the finite volume method(FVM) and volume of fluid(VOF) method are adopted to simulate the flow field around the pipeline.The pressure distribution along the sandy bed surface is obtained by considering the variation of water surface.Furthermore,the effects of water depth,unidirectional and bidirectional impermeable plates on pressure difference are discussed.The seepage flow field of sandy bed near underwater pipeline is numerically simulated using the laminar and porous media model.On this basis,the effect of the impermeable plate length on hydraulic gradient is investigated and the critical length of impermeable plate is obtained.The simulated results show that when the water depth is smaller than 5.00D(D is the diameter of pipeline),the effect of the water depth on the pressure difference is remarkable.The pressure differences between two endpoints of both the unidirectional and bidirectional plates decrease with the increase of the plate length.The variations of the pressure differences for both the unidirectional and bidirectional plates are similar.With the increase of plate length,the hydraulic gradient decreases and the piping at the seepage exit is avoided effectively as long as it reaches a certain length.Such a critical length of the plate decreases with the increase of the water depth.When water depth is larger than 4.00D,the effect of the water depth on the critical length is small.For the same water depth,the critical length of impermeable plate increases with the increase of the dimensionless flow parameter.Numerical simulation results are in good agreement with the available experimental measurements.展开更多
基金This work was supported by Chines Academy of Scieuces（No.CMS-cx200305）,National Natural Science Foundation of China（NSFC No.20425309,No.20573117）and Chinese Ministry of Science and Technology （M0ST No.G1999075305）.
文摘Here we report a quantitative study of the orientational structure and motion of water molecule at the air/water interface. Analysis of Sum Frequency Generation （SFG） vibrational peak of the free O-H stretching band at 3700 cm^-1 in four experimental configurations showed that orientational motion of water molecule at air/water interface is libratory within a limited angular range. The free OH bond of the interracial water molecule is tilted around 33°from the interface normal and the orientational distribution or motion width is less than 15°. This picture is significantly different from the previous conclusion that the interracial water molecule orientation varies over a broad range within the ultrafast vibrational relaxation time, the only direct experimental study concluded for ultrafast and broad orient, ational motion of a liquid interface by Wei et al. （Phys. Rev. Lett. 86, 4799, （2001）） using single SFG experimental configuration.
基金supported by the National Natural Science Foundation of China(Grant No.51279189)the National Hi-Tech Research and Development Program of China("863"Project)(Grant No.2008AA09Z309)China Scholarship Council and University of Aberdeen
文摘This study proposes a new approach in which an impermeable plate is placed under the pipeline to prevent the local scour around the pipeline.In order to understand the performance of this approach,the finite volume method(FVM) and volume of fluid(VOF) method are adopted to simulate the flow field around the pipeline.The pressure distribution along the sandy bed surface is obtained by considering the variation of water surface.Furthermore,the effects of water depth,unidirectional and bidirectional impermeable plates on pressure difference are discussed.The seepage flow field of sandy bed near underwater pipeline is numerically simulated using the laminar and porous media model.On this basis,the effect of the impermeable plate length on hydraulic gradient is investigated and the critical length of impermeable plate is obtained.The simulated results show that when the water depth is smaller than 5.00D(D is the diameter of pipeline),the effect of the water depth on the pressure difference is remarkable.The pressure differences between two endpoints of both the unidirectional and bidirectional plates decrease with the increase of the plate length.The variations of the pressure differences for both the unidirectional and bidirectional plates are similar.With the increase of plate length,the hydraulic gradient decreases and the piping at the seepage exit is avoided effectively as long as it reaches a certain length.Such a critical length of the plate decreases with the increase of the water depth.When water depth is larger than 4.00D,the effect of the water depth on the critical length is small.For the same water depth,the critical length of impermeable plate increases with the increase of the dimensionless flow parameter.Numerical simulation results are in good agreement with the available experimental measurements.
