Arsenic is selectively extracted from high-arsenic dust by NaOH-Na2S alkaline leaching process. In the leaching arsenic process, the effects of alkali-to-dust ratio, sodium sulfide addition, leaching temperature, leac...Arsenic is selectively extracted from high-arsenic dust by NaOH-Na2S alkaline leaching process. In the leaching arsenic process, the effects of alkali-to-dust ratio, sodium sulfide addition, leaching temperature, leaching time and liquid-to-solid ratio on metals leaching efficiencies were investigated. The results show that the arsenic can be effectively separated from other metals under the optimum conditions of alkali/dust mass ratio of 0.5, sodium sulfide addition of 0.25 g/g, leaching temperature of 90 ℃, leaching time of 2 h, and liquid-to-solid ratio of 5：1 （mL/g）. Under these conditions, the average leaching efficiencies of arsenic, antimony, lead, tin and zinc are 92.75%, 11.68%, 0.31%, 29.75% and 36.85%, respectively. The NaOH-Na2S alkaline leaching process provides a simple and highly efficient way to remove arsenic from high-arsenic dust, leaving residue as a suitable lead resource.展开更多
The metabolism of copper and arsenic in a copper pyrometallurgy process was studied through substance flow analysis method.The mass balance accounts and substance flow charts of copper and arsenic were established,ind...The metabolism of copper and arsenic in a copper pyrometallurgy process was studied through substance flow analysis method.The mass balance accounts and substance flow charts of copper and arsenic were established,indicators including direct recovery,waste recycle ratio,and resource efficiency were used to evaluate the metabolism efficiency of the system.The results showed that,the resource efficiency of copper was 97.58%,the direct recovery of copper in smelting,converting,and refining processes was 91.96%,97.13%and 99.47%,respectively.Meanwhile,for producing 1 t of copper,10 kg of arsenic was carried into the system,with the generation of 1.07 kg of arsenic in flotation tailing,8.50 kg of arsenic in arsenic waste residue,and 0.05 kg of arsenic in waste water.The distribution and transformation behaviors of arsenic in the smelting,converting,and refining processes were also analyzed,and some recommendations for improving copper resource efficiency and pollution control were proposed based on substance flow analysis.展开更多
The influence of crown ether on behaviors of arsenic at different temperatures and residence time was investigated during the pyrolysis of Tuanbo （TB） coal. The modes of occurrence of arsenic were determined by sequ...The influence of crown ether on behaviors of arsenic at different temperatures and residence time was investigated during the pyrolysis of Tuanbo （TB） coal. The modes of occurrence of arsenic were determined by sequential chemical extraction, density fractionation and demineralization. The results indicated that at the same temperature and residence time, the arsenic removal adding dibenzo-18-crown-6 was higher than that adding 18-crown-6, and were all higher than that of TB coal during pyrolysis. When temperature was 850 ℃ and residence time was 30 min, the arsenic removal of TB coal was 30.63%; at the same condition, the arsenic removal while adding 18-crown-6 was 33.21%, higher than that of TB coal; and the arsenic removal while adding dibenzo-18-crown-6 was 67.41%, significantly higher than that of TB coal. From the results, we can see that adding crown ether can improve the arsenic removal during coal pyrolysis, and especially be conducive to the arsenic which is mainly associated with sulfates ＆ monosulfides and that in stable forms.展开更多
A field study was conducted to determine the behavior and distribution of arsenic during the pyrometallurgy process in a typical SKS(Shuikoushan) lead smelter in Hunan province, China. Environmental influences of arse...A field study was conducted to determine the behavior and distribution of arsenic during the pyrometallurgy process in a typical SKS(Shuikoushan) lead smelter in Hunan province, China. Environmental influences of arsenic in selected samples were evaluated. Arsenic contents in all input and output samples vary from 0.11% in raw lead to 6.66% in collected dust-2. More arsenic is volatilized in blast furnace and fuming furnace(73.02% of arsenic input) than bottom blowing furnace(10.29% of arsenic input).There are 78.97%, 13.69%, 7.31% of total arsenic distributed in intermediate materials, stockpiled materials and unorganized emissions, respectively. Matte slag-2, collected dust-1 and secondary zinc oxide are hazardous based on the arsenic concentrations of toxicity characteristic leaching procedure. According to risk assessment code(RAC) guideline, arsenic in collected dust-1 poses a very serious risk to the surrounding environment, arsenic in speiss, matte slag-2, water-quenched slag and secondary zinc oxide show low risk, while arsenic in matte slag-1, collected dust-2 and post dust has no risk to the environment.展开更多
基金the financial supports from the National Natural Science Foundation of China(Nos.51904351,U20A20273)the National Key R&D Program of China(No.2019YFC1907400)+1 种基金the Science and Technology Innovation Program of Hunan Province,China(No.2021RC3005)the Innovation Driven Project of Central South University,China(No.2020CX028)。
基金Project(2012AA04022)supported by the Scientific Research and Technology Development Project of Guangxi,China
文摘Arsenic is selectively extracted from high-arsenic dust by NaOH-Na2S alkaline leaching process. In the leaching arsenic process, the effects of alkali-to-dust ratio, sodium sulfide addition, leaching temperature, leaching time and liquid-to-solid ratio on metals leaching efficiencies were investigated. The results show that the arsenic can be effectively separated from other metals under the optimum conditions of alkali/dust mass ratio of 0.5, sodium sulfide addition of 0.25 g/g, leaching temperature of 90 ℃, leaching time of 2 h, and liquid-to-solid ratio of 5：1 （mL/g）. Under these conditions, the average leaching efficiencies of arsenic, antimony, lead, tin and zinc are 92.75%, 11.68%, 0.31%, 29.75% and 36.85%, respectively. The NaOH-Na2S alkaline leaching process provides a simple and highly efficient way to remove arsenic from high-arsenic dust, leaving residue as a suitable lead resource.
基金financial supports from the National Key R&D Program of China(No.2019YFC1907400)the National Natural Science Foundation of China(Nos.51904351,51620105013)。
文摘The metabolism of copper and arsenic in a copper pyrometallurgy process was studied through substance flow analysis method.The mass balance accounts and substance flow charts of copper and arsenic were established,indicators including direct recovery,waste recycle ratio,and resource efficiency were used to evaluate the metabolism efficiency of the system.The results showed that,the resource efficiency of copper was 97.58%,the direct recovery of copper in smelting,converting,and refining processes was 91.96%,97.13%and 99.47%,respectively.Meanwhile,for producing 1 t of copper,10 kg of arsenic was carried into the system,with the generation of 1.07 kg of arsenic in flotation tailing,8.50 kg of arsenic in arsenic waste residue,and 0.05 kg of arsenic in waste water.The distribution and transformation behaviors of arsenic in the smelting,converting,and refining processes were also analyzed,and some recommendations for improving copper resource efficiency and pollution control were proposed based on substance flow analysis.
基金Supported by the Research Fund for the Doctoral Program of Higher Education of China for New Teachers （20091404120002） the Shanxi Provincial Science Foundation for Youths of China （2011021008-1）
文摘The influence of crown ether on behaviors of arsenic at different temperatures and residence time was investigated during the pyrolysis of Tuanbo （TB） coal. The modes of occurrence of arsenic were determined by sequential chemical extraction, density fractionation and demineralization. The results indicated that at the same temperature and residence time, the arsenic removal adding dibenzo-18-crown-6 was higher than that adding 18-crown-6, and were all higher than that of TB coal during pyrolysis. When temperature was 850 ℃ and residence time was 30 min, the arsenic removal of TB coal was 30.63%; at the same condition, the arsenic removal while adding 18-crown-6 was 33.21%, higher than that of TB coal; and the arsenic removal while adding dibenzo-18-crown-6 was 67.41%, significantly higher than that of TB coal. From the results, we can see that adding crown ether can improve the arsenic removal during coal pyrolysis, and especially be conducive to the arsenic which is mainly associated with sulfates ＆ monosulfides and that in stable forms.
基金Project(2011AA061001)supported by the National High Technology Research and Development Program of ChinaProject(51304251)supported by the National Natural Science Foundation of China+1 种基金Project(2013M542141)supported by China Postdoctoral FoundationProject(K1201010-61)supported by Planned Program of Science and Technology of Changsha,China
文摘A field study was conducted to determine the behavior and distribution of arsenic during the pyrometallurgy process in a typical SKS(Shuikoushan) lead smelter in Hunan province, China. Environmental influences of arsenic in selected samples were evaluated. Arsenic contents in all input and output samples vary from 0.11% in raw lead to 6.66% in collected dust-2. More arsenic is volatilized in blast furnace and fuming furnace(73.02% of arsenic input) than bottom blowing furnace(10.29% of arsenic input).There are 78.97%, 13.69%, 7.31% of total arsenic distributed in intermediate materials, stockpiled materials and unorganized emissions, respectively. Matte slag-2, collected dust-1 and secondary zinc oxide are hazardous based on the arsenic concentrations of toxicity characteristic leaching procedure. According to risk assessment code(RAC) guideline, arsenic in collected dust-1 poses a very serious risk to the surrounding environment, arsenic in speiss, matte slag-2, water-quenched slag and secondary zinc oxide show low risk, while arsenic in matte slag-1, collected dust-2 and post dust has no risk to the environment.
