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高岭石和硅/铝-氧化物对腐殖酸的吸附实验研究 被引量:29
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作者 吴宏海 张秋云 +1 位作者 方建章 曾丽璇 《岩石矿物学杂志》 CAS CSCD 北大核心 2003年第2期173-176,共4页
矿物结合的腐殖质可改变矿物的表面性质 ,矿物对腐殖酸的吸附强度与矿物的吸附位性质、密度、荷电性及比表面积有关。若按比表面积计算 ,矿物对腐殖酸的吸附强度顺序为氢氧化铝 >高岭石 >石英 ;按单位质量计算 ,吸附强度顺序为高... 矿物结合的腐殖质可改变矿物的表面性质 ,矿物对腐殖酸的吸附强度与矿物的吸附位性质、密度、荷电性及比表面积有关。若按比表面积计算 ,矿物对腐殖酸的吸附强度顺序为氢氧化铝 >高岭石 >石英 ;按单位质量计算 ,吸附强度顺序为高岭石 >氢氧化铝 >石英。研究表明 ,矿物表面活性受水溶液pH值的调控 ,且当 pH值在 4~ 7时 ,上述 3种矿物对腐殖酸的吸附机理为 :石英主要表现为氢键作用 ;氢氧化铝主要表现为配体交换表面配位作用 ;高岭石表现为多种形式并存 ,包括氢键。 展开更多
关键词 高岭石 硅/铝-氧化物 腐殖酸 吸附实验
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Preservation of organic matter in soils of a climobiosequence in the Main Range of Peninsular Malaysia
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作者 Amir Hossein JAFARZADEH-HAGHIGHI Jusop SHAMSHUDDIN +1 位作者 Jol HAMDAN Norhazlin ZAINUDDIN 《Journal of Mountain Science》 SCIE CSCD 2017年第9期1763-1775,共13页
Limited information is available about factors of soil organic carbon(SOC) preservation in soils along a climo-biosequence. The objective of this study was to evaluate the role of soil texture and mineralogy on preser... Limited information is available about factors of soil organic carbon(SOC) preservation in soils along a climo-biosequence. The objective of this study was to evaluate the role of soil texture and mineralogy on preservation of SOC in the topsoil and subsoil along a climo-biosequence in the Main Range of Peninsular Malaysia. Soil samples from the A and B-horizons of four representative soil profiles were subjected to particle-size fractionation and mineralogical analyses including X-ray diffraction and selective dissolution. The proportion of SOC in the 250-2000 μm fraction(SOC associated with coarse sand) decreased while the proportion of SOC in the <53 μm fraction(SOC associated with clay and silt)increased with depth. This reflected the importance of the fine mineral fractions of the soil matrix for SOC storage in the subsoil. Close relationships between the content of SOC in the <53 μm fraction and the content of poorly crystalline Fe oxides [oxalate-extractable Fe(Fe_o) – pyrophosphate-extractable Fe(Fe_p)] and poorly crystalline inorganic forms of Al [oxalateextractable Al(Al_o) – pyrophosphate-extractable Al(Al_p)] in the B-horizon indicated the importance of poorly crystalline Fe oxides and poorly crystalline aluminosilicates for the preservation of SOC in the Bhorizon. The increasing trend of Fe_o-Fe_p and Al_o-Al_p over elevation suggest that the importance of poorly crystalline Fe oxides and poorly crystalline aluminosilicates for the preservation of SOC in the Bhorizon increased with increasing elevation. This study demonstrates that regardless of differences in climate and vegetation along the studied climobiosequence, preservation of SOC in the subsoil depends on clay mineralogy. 展开更多
关键词 Particle-size fractionation Poorly crystalline minerals Soil organic matter Soil texture
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