碳硅性质的讨论

本文从结构观点和热力学观点,从微观结构到宏观性质,从现象到实质对碳、硅性质做了系统的分析比较,揭示了它们的相似性和差异性。通过理论分析及实例印证,对有机界和无机界的“主宰”元素——碳和硅作了深入浅出的描述。

不同性质硅肥影响土壤生物有效态镉砷的主要因素

为研究硅肥影响土壤中生物有效态镉(Cd)和砷(As)的主要因素,选择不同性质的3种碱性硅肥[Na_(2)SiO_(3)、 CaSiO_(3)与ASSF (pH 9~11)]和一种弱酸偏中性可溶硅肥(NSSF,pH 5~6)并通过添加不同用量硅肥(25~800 mg·kg^(-1),以Si计)开展室内土盆试验,淹水共育21 d后对土壤基本理化性质进行检测,同时利用薄膜扩散梯度(DGT)提取土壤生物有效态Cd和As.结果表明,不同性质硅肥施用对土壤基本理化性质的影响差异显著,具体来说:3种碱性硅肥均显著提升土壤pH值(P<0.05),其中Na_(2)SiO_(3)提升土壤pH能力最强;而NSSF的施用则显著降低土壤pH值但提升了土壤Eh值(P<0.05),每单位质量(mg) Si添加量的NSSF可使土壤pH下降0.001 7个单位;在Si添加量达到400 mg·kg^(-1)后,3种碱性硅肥和NSSF土壤pH和Eh变化都趋于平缓.4种不同性质硅肥提升土壤有效硅含量能力为:NSSF>Na_(2)SiO_(3)>ASSF>CaSiO_(3).3种碱性硅肥可显著降低土壤DGT-Cd浓度而提高土壤DGT-As浓度(P<0.05),但是在CaSiO_(3)添加量为100 mg·kg^(-1)(以Si计)时,可以在显著降土壤DGT-Cd浓度的同时(降低约50.89%)又不引起DGT-As浓度大幅度上升;而NSSF使得土壤DGT-As浓度显著降低,土壤DGT-Cd浓度显著增加(P<0.05),Si添加量为400 mg·kg^(-1)时,土壤DGT-As浓度基本达到稳定状态,降As率达85.87%.对影响DGT-Cd和DGT-As浓度因素进行相关性分析,发现土壤pH是影响DGT-Cd浓度和DGT-As浓度的主要因素,其次是土壤Eh;土壤有效硅与土壤有效磷本身对土壤Cd和As生物有效性影响可忽略不计;施用碱性硅肥当土壤pH为6.5~7.0时,土壤DGT-Cd浓度基本达到最低值;而施用NSSF使得土壤pH为5~5.5时,DGT-As浓度基本达到最低值.明确硅肥降低土壤中生物有效态Cd和As主要影响因素对确保农业绿色发展以及促进粮食安全生产有重要的指导意义.

Study on Properties of Composite Oxides TiO_2/SiO_2

The nanometer particles of TiO_2 and TiO_2/SiO_2 oxides wereprepared by sol-gel supercritical fluid drying method. The propertiesof TiO_2 and TiO_2/SiO_2 were characterized by means of BET(Brunner-Emmett- Teller method), TEM (transmission electronmicroscopy), SEM (scanning electron microscopy), XRD (X-ray diffrac-tion) and FTIR (Fourier transform-infrared) techniques. The effectsof different preparation route, prehydrolysis and non-prehydrolysis,on the properties of TiO_2/SiO_2 oxide were also examined.

Selective separation of silica from a siliceous-calcareous phosphate rock

Selective separation of silica from a siliceous-calcareous phosphate ore that had been sieved into different size fractions is investigated by a combination of chemical analysis,zeta potential measurement and FTIR and XPS techniques.Scrubbing is a better choice than flotation for removing silica from the coarse fractions.The P_2O_5 grade of the coarse fractions is increased to about 30%by scrubbing and the product yields are higher than those obtained by flotation.The silica in the fine fraction is separated by reverse flotation.An alkyl amine salt(DAH)is an effective collector and the P_2O_5 grade of the fine fraction can be increased by 7%to beyond 30%under acidic conditions.The higher zeta potential obtained using DAH suggests that it is more strongly absorbed onto the ore particles than the other cationic collectors. FTIR and XPS results confirm physical absorption of the cationic collector onto the ore surface.They also indicate that calcite is dissolved at low pH values,which increases the Si concentration on the ore surface.

Influence of polarized bias and porous silicon morphology on the electrical behavior of Au-porous silicon contacts

This paper reports the surface morphology and I-V curves of porous silicon （PS） samples and related devices. The observed fabrics on the PS surface were found to affect the electrical property of PS devices. When the devices were operated under different external bias （10 V or 3 V） for 10 min, their observed obvious differences in electrical properties may be due to the different control mechanisms in the A1/PS interface and PS matrix morphology.

First-Principles Calculations of Atomic and Electronic Properties of Tl and In on Si(111)

The atomic and electronic structures of T1 and In on Si（111） surfaces are investigated using the firstprinciples total energy calculations. Total energy optimizations show that the energetically favored structure is 1/3 ML T1 adsorbed at the T4 sites on Si（111） surfaces. The adsorption energy difference of one T1 adatom between （√3 × √3） and （1 × 1） is less than that of each In adatom. The DOS indicates that TI 6p and Si 3p electrons play a very important role in the formation of the surface states. It is concluded that the bonding of TI adatoms on Si（111） surfaces is mainly polar covalent, which is weaker than that of In on Si（111）. So T1 atom is more easy to be migrated than In atom in the same external electric field and the structures of T1 on Si（111） is prone to switch between （√3 × √3） and （1 × 1）.

A comparison of anionic and cationic flotation of a siliceous phosphate rock in a column flotation cell

Flotation performance of a de-slimed（-150＋53μm）Jordanian siliceous phosphate was evaluated in a batch laboratory flotation column 100 cm high and 5 cm inside diameter.The collector used during anionic flotation was sodium oleate while an amine acetate（AEROMINE 3100C）was used for cationic flotation.Flotation comparison at different collector dosage,superficial gas velocity,and frother concentration showed that the maximum difference in performance between cationic and anionic flotation was obtained with these flotation parameters：30×10^（-6）（mg/L）frother concentration,250 g/t collector concentration,and 3.4 cm/s superficial gas velocity.At these operating conditions amine （cationic）flotation gave 7%higher flotation recovery,a 6%cleaner concentrate grade,and was 6%more efficient at removing silica.

Molecular Dynamics Simulations of Silica Nanotube： Structural and Vibrational Properties Under Different Temperatures

Four-, six-, and eight-membered ring silica nanotubes at temperatures from 300 K to 1600 K are relaxed by classical molecular dynamics simulations with three potential models. The simulation results indicate that the stability of the end rings of the three silica nanotubes gradually decreases with increase in temperature. The validity of the vibrational features of silica nanotubes is shown by the vibrational density of states. Infrared spectra on the silica nanotubes under different temperatures are investigated. A detailed assignment of each spectral peak to the corresponding vibrational mode of the three nanotubes has been addressed. The results are in good agreement with the other theoretical and experimental

Study of Sandy Silica Properties in Area of Edree （Libya） and the Possibility of Using in Various Engineering Industries

Silica materials are located in various regions of Libya in large quantities and different mining conditions, so the purpose of this study is silica materials in the south-west of the Libyan region Edree in terms of quality and the possibility of using in various engineering industries, particularly construction. The results show that the sands of silica presented in Edree area are of a high degree of purity, as the percentage of silicon （SIO2） reached 99.5%, the percentage of impurities was negligible and represented in some chemical elements in different proportions, such as calcium 0.224%, sodium 0.004%, iron 0.0006%, zinc 0.0003%, boron 0.0003%, potassium 0.0001%, manganese 0.0001% and magnesium 0.0001%, making these materials very suitable in the manufacture of all types of glass, crystal and semi-crystalline high-quality without needing any important treatment, as well as its suitability as a refinement in manufacture of templates metal castings in addition to the possibility of use in the manufacture of cement, building materials and as a filler in paint and brick making and sand and concrete elements can also be used in electronic industries. A geological material of silica present in the form of a sequence of layers of clay and thin layers of sand stone and a large stock of high-quality near the surface, making mining operations of the type of surface and reduces the cost of extraction.

Transport Properties of Si and Ge Liquid Semiconductor Metals

In the present article, we study the electrical resistivity ρ, the thermoelectric power （TEP） α, thermal conductivity σ, Knight-Shifts and temperature coefficient of the Knight-Shifts of the liquid Si and Ge using the well known model potential for the first time. The structure factor used in the present work is derived from the Percus-Yevick （PY） theory. Various local field correction functions are used to study the screening influence. The present results of resistivity are found in qualitative agreement with available experimental and theoretical whenever exists.

14号元素的“自白”

硅元素的知识是高中化学必修1的内容,硅及其化合物在现代社会被广泛应用,具有重要的经济价值。文章以第一人称的视角,将硅及其化合物的知识以自白的形式娓娓道来,介绍了硅元素的化学性质、存在形式、发现过程、具体种类及用途等。

Effect of solids on pulp and froth properties in flotation

Froth flotation is a widely used process of particle separation exploiting differences in surface properties. It is important to point out that overall flotation performance(grade and recovery) is a consequence of the quality and quantity of the solid particles collected from the pulp phase, transported into the froth phase, and surviving as bubble-particle aggregates into the overflow. This work will focus on studying these phenomena and will incorporate the effects of particle hydrophobicities in the 3-phase system. Solids are classed as either hydrophilic non-sulphide gangue(e.g. silica, talc), hydrophilic sulphide(e.g. pyrite), or hydrophobic sulphide(e.g. sphalerite). Talc is a surface-active species of gangue that has been shown to behave differently from silica(frother adsorbs on the surface of talc particles). Both are common components of ores and will be studied in detail. The focus of this work is to investigate the role of solids on pulp hydrodynamics, froth bubble coalescence intensity, water overflow rate with solids present, and in particular, the interactions between solids, frother and gas on the gas dispersion parameters. The results show that in the pulp zone there is no effect of solids on bubble size and gas holdup; in the froth zone, although hydrophilic particles solely do not effect on the water overflow rate, hydrophobic particles produce higher intensity of rates on water overflow and bubble coalescence, and many be attributed to the water reattachment.

Sedimentary Environments, Geometry and Characteristics of the Sand Layers within the Basin of El Ma Labiod （Algero-Tunisian Borders）

The authors＇ work concerns the study of sedimentary environments, the geometry and the characteristics of the silicon-clastic deposits within the basin of EI Ma Labiod at the Algero-Tunisian confines. The sedimentological analysis has proved a Miocene age of the sediments with varied environments： marine, fluvial-deltaic and lake. The geological aspect of the sediment, in particular sandy, is of the movable type or very slightly consolidated. The size of the industrial sand layers can be very diverse, however to feed from the industrial consumers having a certain perenniality, our prospection was directed towards layers with very important reserves. It is about a sedimentary basin with dimensions exceeding very largely the conditions of operating for such projects, which are at least one to two million tons. With the exception of a thin quaternary soil horizon, the basin is almost of an exploitation with open sky. The mineralogical determination has revealed siliceous to extra-siliceous sands, which are absolutely usable in the industry of glass, foundry and also in other functions like the abrasives of sanding and the clothing industry of the sandpapers. Concerning the economic aspect, the materials are very close and this is why the area has known the installation of a glassmaking factory and a cement factory using at the same time the Maastrichtian limestone, the sandy material and the clays of the Western zone of the basin.

Effects of Ar ion assisted deposition on the optical and electrical characteristics of electron-beam-evaporated amorphous Si films

In this paper,the effects of Ar ion bombardment during the electron beam evaporation deposition of the amorphous Si film were investigated.It was found that the bombardment increases the light absorption by two to eleven times and increases the conductance of the film by 3 000 times.This has never been reported before of amorphous Si with electron beam evaporation deposition.

Stabilization of Magnetite Nanoparticles by Encapsulation into the Silica Matrix

Different methods have been investigated for the synthesis of magnetic nanoparticles. Control of the particle size, dispersion, purity and stability have been always regarded an issue. In this study magnetite （Fe304） superparamagnetic nanoparticles with a size range about 20 nm have been successfully synthesized using chemical co-precipitation method from the solution of ferrous/ferric mixed salt-solution in alkaline media in oxygen-free environment. The sol-gel method has been chose to encapsulate magnetic nanoparticles into silica matrix. The phase structures, morphologies, surface area, functional classes and magnetic properties have been characterized by X-ray diffraction, SEM and AFM, BET, FT-IR and VSM. The results showed that the resultant films, consisting of encapsulated magnetite have crack free and smooth surface with a roughness value 1.5 rim.

Electron-Irradiation Induced Nanocrystallization of Pb（ll） in Silica Gels Prepared in High Magnetic Field

In a previous study, structure of silica gels prepared in a high magnetic field was investigated. While a direct application of such anisotropic silica gels is for an optical anisotropic medium possessing chemical resistance, we show here their possibility of medium in materials processing. In this direction, for example, silica hydrogels have so far been used as media of crystal growth. In this paper, as opposed to the soft-wet state, dried silica gels have been investigated. We have found that lead （II） nanocrystallites were formed induced by electron irradiation to lead （ll）-doped dried Hydrogels made from a sodium metasilicate solution doped with silica gels prepared in a high magnetic field such as B = 10 T. lead （II） acetate were prepared. The dried specimens were irradiated by electrons in a transmission electron microscope environment. Electron diffraction patterns indicated the crystallinity of lead （II） nanocrystallites depending on B. An advantage of this processing technique is that the crystallinity can be controlled through the strength of magnetic field B applied during gel preparation. Specific skills are not required to control the strength of magnetic field.

Improved oxidation resistance of chemical vapor reaction SiC coating modified with silica for carbon/carbon composites

To protect carbon/carbon (C/C) composites from oxidation, a SiC coating modified with SiO2 was prepared by a complex technology. The inner SiC coating with thickness varying from 150 to 300 μm was initially coated by chemical vapor reaction (CVR): a simple and cheap technique to prepare the SiC coating via siliconizing the substrate that was exposed to the mixed vapor (Si and SiO2) at high temperatures (1 923?2 273 K). Then the as-prepared coating was processed by a dipping and drying procedure with tetraethoxysilane as source materials to form SiO2 to fill the cracks and holes. Oxidation tests show that, after oxidation in air at 1 623 K for 10 h and thermal cycling between 1 623 K and room temperature 5 times, the mass loss of the CVR coated sample is up to 18.21%, while the sample coated with modified coating is only 5.96%, exhibiting an obvious improvement of oxidation and thermal shock resistance of the coating. The mass loss of the modified sample is mainly contributed to the reaction of C/C substrate with oxygen diffusing through the penetrating cracks formed in thermal shock tests.

Adsorption and Transfer Properties for Toluene and pDichlorobenzene in Dense CO_2/Silica Gel Packed Bed System by Moment Method and Time-Domain Analysis

Based on chromatographic theory, the moment method and the time-domain fitting analysis were applied to measure and evaluate the adsorption equilibrium constant and mass transfer properties (axial dispersion coefficient and effective intra-particle diffusivity) for toluene and p-dichlorobenzene on silica gel adsorbent in the subcritical and supercritical CO2. An apparatus based on supercritical fluid chromatography was established and the experiments were performed at temperatures of 298.15-318.15 K and pressures of 7.5-17.8 MPa. The two methods have been compared. The results show that for the systems studied here the moment method can give reasonable values for both adsorption equilibrium constant and mass transfer properties, but the time-domain analysis only can obtain the adsorption equilibrium constant. The dependence of adsorption equilibrium constant and mass transfer properties on temperature and pressure was investigated.

Effects of Silylation on Zn-IM5 and Its Catalytic Activity for Butane Aromatization

Effects of silylation on surface properties and catalytic performance of Zn-IM5 for butane aromatization were studied in this paper. Collidine-IR and NH3-TPD analyses revealed that the silylation treatment not only decreased the quantity of both strong and weak acid sites but also led to a slightly reduced intensity of weak acidity. Silylation of the catalyst promoted the selectivity of BTX by narrowing the channel and cutting the acidity. The effect of temperature of silylation and amount of Si loading were evaluated. The best condition has specified a temperature of 50 ℃ and a SiO_2 loading of 4.0%.

Study of Changes in Physiochemical Properties of Soil by the Addition of Cement

The effect of cement on physiochemical properties of three types of soils i.e garden soil, agricultural soil and roadside soil was investigated. The ordinary Portland cement was used. The amount of cement added to soil samples, as dry mass percentage was 20%. The results of analysis showed that the addition of cement is capable of bringing about changes in physiochemical properties of soil. The electrical conductivity and organic matter content in three soils get decreased by the addition of cement. While the pH, bulk density and water holding capacity of soils after the addition of cement gets increased. The soil found most suitable to be treated with cement was roadside soil. It was concluded that cement can be used to change the physiochemical properties of soil and this technique has great utility in improving the quality of problematic soils.