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热解含铁聚硅氧烷原位生长硅氧碳纤维制备硅氧碳复合材料
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作者 殷正娥 杜贺宝 +2 位作者 周富强 宗文喜 李亚利 《硅酸盐学报》 EI CAS CSCD 北大核心 2012年第7期1046-1049,共4页
将铁氯化物混入聚硅氧烷前驱体进行交联成型和热解,利用热解中在聚硅氧烷中形成的孔隙和在孔隙中形成的铁颗粒为催化剂,在硅氧碳陶瓷基体中原位生长出硅氧碳纳米纤维,制备出硅氧碳陶瓷和硅氧碳纤维复合材料。用扫描电子显微镜观察材料断... 将铁氯化物混入聚硅氧烷前驱体进行交联成型和热解,利用热解中在聚硅氧烷中形成的孔隙和在孔隙中形成的铁颗粒为催化剂,在硅氧碳陶瓷基体中原位生长出硅氧碳纳米纤维,制备出硅氧碳陶瓷和硅氧碳纤维复合材料。用扫描电子显微镜观察材料断面,结果显示:在硅氧碳陶瓷基体中生长出纳米纤维,部分纤维取向分布,纤维紧贴于硅氧碳陶瓷基体,二者呈良好结合;能谱分析显示纤维中含硅、氧和碳,证实其为硅氧碳。所制得的硅氧碳陶瓷和硅氧碳纤维的复合结构不同于通常热解纯聚硅氧烷形成的单相的硅氧碳结构,在硅氧碳基体中的硅氧碳纤维是在聚硅氧烷前驱体中引入的铁催化剂在热解过程中通过催化聚硅氧烷一维生长形成的,该过程可用于发展一步法原位制备纳米纤维前驱体陶瓷复合材料。 展开更多
关键词 陶瓷 硅氧碳纤维 原位生长
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连续Si-C-Fe-O功能陶瓷纤维的制备
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作者 陈志彦 王军 +3 位作者 李效东 王应德 王亦菲 胡天娇 《硅酸盐学报》 EI CAS CSCD 北大核心 2005年第6期703-707,共5页
为了改善碳化硅纤维的电磁性能,首次由聚二甲基硅烷和二茂铁合成了聚铁碳硅烷,当二茂铁的添加量(以质量计)为2%时,所制得的聚铁碳硅烷经熔融纺丝、预氧化,惰性气氛中烧成后,可制得低电阻率(10-2Ω·cm)、拉伸强度为2.0GPa、长度大于... 为了改善碳化硅纤维的电磁性能,首次由聚二甲基硅烷和二茂铁合成了聚铁碳硅烷,当二茂铁的添加量(以质量计)为2%时,所制得的聚铁碳硅烷经熔融纺丝、预氧化,惰性气氛中烧成后,可制得低电阻率(10-2Ω·cm)、拉伸强度为2.0GPa、长度大于500m的连续SiC FeO纤维。探索了连续SiCFeO纤维的制备工艺。研究了铁对纤维电阻率和βSiC结晶的影响。结果表明:铁含量的增加有利于βSiC晶粒的增长和电阻率的降低。 展开更多
关键词 连续--铁-纤维 合成 电阻率 β-
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Preparation of Carbon Nano-fiber Washcoat on Porous Silica Foam as Structured Catalyst Support 被引量:1
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作者 刘平乐 L.Lefferts 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2006年第3期294-300,共7页
This paper reports how a hairy layer of carbon nano-fibers can be prepared on the macro-porous silica foam produced by the sphere templating method. Firstly, three-dimensional close-packed crystals of polystyrene sphe... This paper reports how a hairy layer of carbon nano-fibers can be prepared on the macro-porous silica foam produced by the sphere templating method. Firstly, three-dimensional close-packed crystals of polystyrene spheres are assembled on porous disk substrate by vacuum filtration or evaporation. The polystyrene template is annealed slightly above the glass transition temperature in order to strengthen the colloidal crystal and ensure interconnection of the spheres so as to obtain porous materials with open structure. Following the treatment of hexdecyltrimethylammonium bromide, the polystyrene template is filled with silica colloidal solution, which solidifies in the cavities. Then the polystyrene particles are removed by calcination at 843K, leaving behind porous silica foam. Scanning electron microscopy images demonstrate that silica foam has uniform and open structured pores. Nickel particles were deposited on porous silica foam layer by the dipping method and porous carbon nano-fiber washcoat was prepared by catalytic decomposition of ethene over small nickel particles. 展开更多
关键词 sphere template colloidal crystal silica foam carbon nano-fiber WASHCOAT
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Improvement of Impact Absorbed Energy of CFRPs on Adding the Nanoparticles into Epoxy Resins
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作者 Tsung-Han Hsieh Chih-Hsiang Liang 《Journal of Chemistry and Chemical Engineering》 2014年第7期692-697,共6页
The present study investigates the effect of the addition of nanoparticles into epoxy resins as the matrix on the impact absorbed energy of CFRP (carbon fiber reinforced polymer). Impact absorbed energy is one of th... The present study investigates the effect of the addition of nanoparticles into epoxy resins as the matrix on the impact absorbed energy of CFRP (carbon fiber reinforced polymer). Impact absorbed energy is one of the main properties to evaluate the CFRP's performance for transportation and aerospace structures. Two types of nanoparticle, namely nanofibers and nano-silica beads, were added into the epoxy resin to improve the impact absorption capacity of the CFRP. Two modified additives and conventional epoxy resins were quantitatively compared. The impact test results showed that impact absorbed energy for nanofibers was higher than nano-silica beads, and nanofibers as the additive promoted about 11% of impact absorbed energy compared with neat epoxy resin. 展开更多
关键词 Carbon fiber nanoparticle additive impact absorbed energy.
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Discussion on the Effects of Temperature, Carbon Fiber and Silica
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作者 Ran LI 《International Journal of Technology Management》 2015年第4期102-103,共2页
Concrete, as an essential construction material in the construction industry, is the main component of solid waste. To improve the strength and durability of concrete, some additives can be added into concrete to repl... Concrete, as an essential construction material in the construction industry, is the main component of solid waste. To improve the strength and durability of concrete, some additives can be added into concrete to replace parts of cement. Carbon fiber and silica powder are the most common additives. Under a series of experiments, the effects of temperature, carbon fiber and silica powder on the mechanical properties of concrete were studied under normal circumstances. In this paper, a conclusion on the effects was drawn up mainly through some experimental analyses, so as to discuss the effect laws and provide a reference to manufacture the concrete of high strength and properties. 展开更多
关键词 TEMPERATURE Carbon Fiber Silica Powder CONCRETE Mechanical Properties
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