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硅硼玻璃在可伐合金表面的润湿规律 被引量:8
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作者 罗大为 沈卓身 《材料工程》 EI CAS CSCD 北大核心 2009年第11期80-83,87,共5页
采用座滴法研究硅硼玻璃在分别具有FeO和FeO+Fe3O4氧化膜的可伐合金表面1000℃保温不同时间的润湿规律。用数码显微镜测量硅硼玻璃在可伐合金表面的接触角和润湿直径,用SEM研究晕圈的表面形貌以及玻璃和金属的截面形貌,并用能谱分析不... 采用座滴法研究硅硼玻璃在分别具有FeO和FeO+Fe3O4氧化膜的可伐合金表面1000℃保温不同时间的润湿规律。用数码显微镜测量硅硼玻璃在可伐合金表面的接触角和润湿直径,用SEM研究晕圈的表面形貌以及玻璃和金属的截面形貌,并用能谱分析不同晕圈处的化学成分。结果表明:随着润湿时间的延长,玻璃在具有FeO和FeO+Fe3O4氧化膜的可伐合金表面的接触角不断减小并最终分别在25°和23°趋于稳定。可以观察到,在润湿过程中,熔融玻璃周围存在两个晕圈,可以根据接触角、晕圈和润湿直径的变化将润湿过程分成润湿初始期、润湿铺展期和润湿稳定期三个阶段。 展开更多
关键词 可伐合金 硅硼玻璃 润湿 晕圈
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用于熔盐高硅硼玻璃隔膜银/氯化银参比电极研究 被引量:4
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作者 贾艳虹 何辉 +1 位作者 林如山 唐洪彬 《无机盐工业》 CAS 北大核心 2015年第3期60-63,共4页
研究了可用于高温熔盐电解精炼的高硅硼(Pyrex)玻璃隔膜银/氯化银(Ag/AgCl)参比电极。对参比电极的性能进行了评价:活化温度对活化时间影响大;温度可逆性和极化可逆性均良好;稳定性良好,但受氯化银离子浓度、温度及光线的影响;重现性好... 研究了可用于高温熔盐电解精炼的高硅硼(Pyrex)玻璃隔膜银/氯化银(Ag/AgCl)参比电极。对参比电极的性能进行了评价:活化温度对活化时间影响大;温度可逆性和极化可逆性均良好;稳定性良好,但受氯化银离子浓度、温度及光线的影响;重现性好,但要注意使用温度范围。 展开更多
关键词 高温熔盐 参比电极 硅硼玻璃 银/氯化银
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Utilisation of Borosilicate Glass Waste as a Micro-Filler for Concrete
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作者 Aleksandrs Korjakins Genadij Shakhmenko Girts Bumanis 《Journal of Civil Engineering and Architecture》 2012年第7期876-883,共8页
Glass from a light bulb is a waste product that cannot be utilised in a traditional way. This study looks into the possibilities of using lamp borosilicate glass powder as a cement replacing admixture in conventional ... Glass from a light bulb is a waste product that cannot be utilised in a traditional way. This study looks into the possibilities of using lamp borosilicate glass powder as a cement replacing admixture in conventional concrete. Experimental work provides preparation of standard concrete samples and sample testing after seven and 28-day ageing periods in standard conditions. The following glass materials were used for cement replacement: rough ground glass powder, glass dust from filters (both materials were obtained from a glass treatment plant) and additionally ground glass powder. The effect of glass powder on cement setting time was studied. The experimental results indicate that replacement of cement by rough glass powder decreases the compressive strength. Fine glass particles make it possible to replace up to 20% of cement without the loss in strength characteristics. Fine glass powder offers a long-term hardening effect. The best compressive strength results were achieved by using the glass that was additionally ground for 60 minutes. Glass dust obtained from filters shows a less significant effect. Summarising the research findings it may be concluded that ground borosilicate lamp glass may be successfully applied as a micro-filler for concrete as cement replacing material. 展开更多
关键词 WASTE borosilicate glass CONCRETE strength.
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可伐合金与玻璃封接工艺的优化 被引量:6
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作者 罗大为 沈卓身 《北京科技大学学报》 EI CAS CSCD 北大核心 2009年第1期62-67,共6页
研究了熔封气氛、熔封温度和熔封时间对玻璃与可伐合金封接件的外观、气密性、结合强度、弯曲次数和玻璃沿引线的爬坡高度的影响.结果表明:熔封气氛的影响很大,随着熔封气氛氧化性的增强,玻璃飞溅程度越来越严重.随着熔封时间的延长或... 研究了熔封气氛、熔封温度和熔封时间对玻璃与可伐合金封接件的外观、气密性、结合强度、弯曲次数和玻璃沿引线的爬坡高度的影响.结果表明:熔封气氛的影响很大,随着熔封气氛氧化性的增强,玻璃飞溅程度越来越严重.随着熔封时间的延长或者熔封温度的升高,可伐合金表面为单一FeO或单一Fe3O4氧化膜时与玻璃的结合强度缓慢增加且弯曲次数基本保持不变,双层氧化膜(FeO+Fe3O4或Fe3O4+Fe2O3)与玻璃的结合强度虽然较高,但弯曲次数却明显下降.可伐合金表面氧化膜类型与玻璃沿引线的爬坡高度关系不大,随着熔封温度的升高,玻璃沿引线的爬坡高度下降;而随着熔封时间的延长,玻璃沿引线的爬坡高度急剧下降,当降至140μm后逐渐趋于稳定.推荐的优化工艺条件是:熔封气氛为弱还原气氛,熔封温度在980℃左右,熔封时间为20~30 min. 展开更多
关键词 可伐合金 硅硼玻璃 封接 氧化膜
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Low temperature sintering and performance of aluminum nitride/borosilicate glass 被引量:3
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作者 Hong-sheng ZHAO Lei CHEN Nian-zi GAO Kai-hong ZHANG Zi-qiang LI 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2009年第1期109-113,共5页
Aluminum nitride (AlN)/borosilicate glass composites were prepared by the tape casting process and hot-press sintered at 950 ℃ with AIN and SiO2-B203-ZnO-Al2O3-Li2O glass as starting materials. We characterized and... Aluminum nitride (AlN)/borosilicate glass composites were prepared by the tape casting process and hot-press sintered at 950 ℃ with AIN and SiO2-B203-ZnO-Al2O3-Li2O glass as starting materials. We characterized and analyzed the variation of the microstructure, bulk density, porosity, dielectric constant, thermal conductivity and thermal expansion coefficient (TEC) of the ceramic samples as a function of AIN content. Results show that AIN and SiO2-B2O3-ZnO-Al2O3-Li2O glass can be sintered at 950 ℃, and ZnAI204 and Zn2SiO4 phase precipitated to form glass-ceramic. The performance of the ceramic samples was determined by the composition and bulk density of the composites. Lower AlN content was found redounding to liquid phase sintering, and higher bulk density of composites can be accordingly obtained. With the increase of porosity, corresponding decreases were located in the dielectric constant, thermal conductivity and TEC of the ceramic samples. When the mass fraction of AlN was 40%, the ceramic samples possessed a low dielectric constant (4.5-5.0), high thermal conductivity (11.6 W/(m.K)) and a proper TEC (3.0× 10^-6 K^-1 which matched that of silicon). The excellent performance makes this kind of low temperature co-fired ceramic a promising candidate for application in the micro-electronics packaging industry. 展开更多
关键词 Aluminum nitride (AlN) Borosilicate glass Low temperature sintering PERFORMANCE
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