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渣—铁之间硅迁移的实验室研究
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作者 方菊英 《华东冶金学院学报》 1989年第3期9-14,共6页
本文介绍渣—铁之间静止状态下的反应对高炉内硅迁移曲作用及炉渣成份和渣铁湿度对硅迁移的影响。
关键词 炉渣 后铁 硅迁移 高炉
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竹子化学制浆中的硅迁移分析 被引量:3
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作者 刘一山 李桂芳 +4 位作者 朱友胜 张玉红 刘连丽 伍安国 肖和芹 《纸和造纸》 2021年第3期10-13,共4页
采用硅钼蓝分光光度法对竹片、竹浆、蒸煮废液、绿液、白液中的硅含量进行测定,探索竹子化学制浆系统中硅迁移的规律。研究发现:蒸煮过程硅的溶出量与碱性强弱有关,碱性越强硅溶出量越多,纸浆中残留的硅含量越少;绿液苛化时溶出的硅与... 采用硅钼蓝分光光度法对竹片、竹浆、蒸煮废液、绿液、白液中的硅含量进行测定,探索竹子化学制浆系统中硅迁移的规律。研究发现:蒸煮过程硅的溶出量与碱性强弱有关,碱性越强硅溶出量越多,纸浆中残留的硅含量越少;绿液苛化时溶出的硅与钙离子结合形成硅酸钙进入白泥被去除,从而避免了硅的无限积累,但对白泥的回用造成影响。 展开更多
关键词 竹子 化学制浆 硅迁移
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三甲基硅基肼的合成 被引量:1
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作者 丁可伟 李陶琦 +3 位作者 肖啸 刘庆 朱勇 葛忠学 《含能材料》 EI CAS CSCD 北大核心 2017年第6期498-502,共5页
以无水肼和三甲基氯硅烷为原料,合成了1,2-二(三甲基硅基)肼,收率83%;再经丁基锂活化合成了三(三甲基硅基)肼,总收率75%;进一步通过三(三甲基硅基)肼锂和三甲基氯硅烷的溶剂热反应合成了四(三甲基硅基)肼,总收率34%。通过核磁、红外、... 以无水肼和三甲基氯硅烷为原料,合成了1,2-二(三甲基硅基)肼,收率83%;再经丁基锂活化合成了三(三甲基硅基)肼,总收率75%;进一步通过三(三甲基硅基)肼锂和三甲基氯硅烷的溶剂热反应合成了四(三甲基硅基)肼,总收率34%。通过核磁、红外、质谱和元素分析对上述产物进行了表征。分析了单(三甲基硅基)肼的自缩合反应和双(三甲基硅基)肼在热作用下的重排反应,结果表明,这些反应都是由三甲基硅基在肼基上的分子间和分子内迁移引起的,并且发现75℃以上双(三甲基硅基)就能发生异构体间的转化与平衡。 展开更多
关键词 三甲基基肼 三甲基基肼锂 三甲基迁移反应 合成
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低迁移导热硅凝胶的制备与性能研究 被引量:3
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作者 杨丹 王智健 +2 位作者 叶能 李京超 卢咏来 《高分子通报》 CAS CSCD 北大核心 2023年第3期329-337,共9页
针对导热硅凝胶在宇航环境中服役时出现的硅油迁移问题,本文设计合成了一种具备多长支链结构的聚硅氧烷(B-PDMS),并在B-PDMS中填充纳米ZnO,得到基于物理缠结网络的导热硅凝胶,以同黏度的线型聚硅氧烷(L-PDMS)为对比。通过核磁和红外表征... 针对导热硅凝胶在宇航环境中服役时出现的硅油迁移问题,本文设计合成了一种具备多长支链结构的聚硅氧烷(B-PDMS),并在B-PDMS中填充纳米ZnO,得到基于物理缠结网络的导热硅凝胶,以同黏度的线型聚硅氧烷(L-PDMS)为对比。通过核磁和红外表征,证明了B-PDMS的成功合成,并发现B-PDMS相较于同黏度的L-PDMS具备更大的分子量、更低的分子运动能力。通过对导热硅凝胶进行环境扫描电镜、导热性能、流变性能、渗油性能以及热真空损失测试,发现纳米ZnO在B-PDMS中的分散性更好;虽然B-PDMS基导热凝胶的热导率略低、零切黏度更大,但是其具备良好的触变性,随着剪切速率的提高,黏度与L-PDMS基导热凝胶趋同。重要的是,B-PDMS基导热凝胶的渗油性能有很大改善,填充200质量份的纳米ZnO制得的导热硅凝胶的渗油率仅为1.08,基本实现了无硅油迁移,且其热真空质损率(TML)仅为0.26 wt%,满足空间环境对材料放气性能的要求。 展开更多
关键词 支链结构 氧烷 物理缠结网络 导热凝胶 迁移
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火管式转化废锅出口温度缓升原因探讨 被引量:1
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作者 孔凡谦 李敬珂 《大氮肥》 CAS 2001年第2期125-126,共2页
介绍火管式废热锅炉的应用情况 。
关键词 火管式 转化气废热锅炉 出口温度 硅迁移
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火管式转化废锅出口温度缓升原因探讨 被引量:2
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作者 张振伍 《石油和化工设备》 CAS 2006年第3期33-34,共2页
介绍火管式废热锅炉的应用情况,并对其工艺气出口温度缓升原因及对系统的影响进行分析。
关键词 废锅 温度 硅迁移
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Fabrication and Characterization of Strained Si Material Using SiGe Virtual Substrate for High Mobility Devices 被引量:2
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作者 梁仁荣 张侃 +3 位作者 杨宗仁 徐阳 王敬 许军 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2007年第10期1518-1522,共5页
The fabrication and characterization of strained-Si material grown on a relaxed Si0.79 Ge0.21/graded Si1-x- Gex/Si virtual substrate, using reduced pressure chemical vapor deposition, are presented. The Ge concentrati... The fabrication and characterization of strained-Si material grown on a relaxed Si0.79 Ge0.21/graded Si1-x- Gex/Si virtual substrate, using reduced pressure chemical vapor deposition, are presented. The Ge concentration of the constant composition SiGe layer and the grading rate of the graded SiGe layer are estimated with double-crystal X-ray diffraction and further confirmed by SIMS measurements. The surface root mean square roughness of the strained Si cap layer is 2.36nm,and the strain is about 0.83% as determined by atomic force microscopy and Raman spectra, respectively. The threading dislocation density is on the order of 4 × 10^4cm^-2. Furthermore, it is found that the stress in the strained Si cap layer is maintained even after the high thermal budget process, nMOSFET devices are fabricated and measured in strained-Si and unstrained bulk-Si channels. Compared to the co-processed bulk-Si MOSFETs at room temperature,a significant low vertical field mobility enhancement of about 85% is observed in the strained-Si devices. 展开更多
关键词 strained Si RPCVD SiGe virtual substrate mobility enhancement
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塔西南化肥厂转化与变换系统典型事故案例总结与提炼 被引量:1
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作者 王爱民 钱浩 +2 位作者 武新河 林美玲 哈力木·牙生 《中氮肥》 2019年第5期28-31,共4页
塔西南化肥厂200kt/a合成氨装置采用Kellogg加压催化转化工艺。结合转化与变换系统的工艺流程及生产实际,对多年来出现的几类典型事故案例——罗茨鼓风机(140-J)损坏、转化系统的硅迁移、炉水磷酸盐暂时消失、低变炉热波现象等事故现象... 塔西南化肥厂200kt/a合成氨装置采用Kellogg加压催化转化工艺。结合转化与变换系统的工艺流程及生产实际,对多年来出现的几类典型事故案例——罗茨鼓风机(140-J)损坏、转化系统的硅迁移、炉水磷酸盐暂时消失、低变炉热波现象等事故现象进行描述,通过事故原因分析、总结与提炼提出可采取的应对措施,以利系统的安、稳、长、满、优运行,并通过典型事故案例的分享为业内提供一些参考和借鉴。 展开更多
关键词 合成氨装置 转化与变换系统 罗茨鼓风机损坏 转化系统硅迁移 炉水磷酸盐暂时消失 低变炉热波现象 原因分析 应对措施
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向高炉风口回旋区喷吹矿粉
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作者 Kushi.,K 龙春安 《国外钢铁》 1990年第6期10-20,共11页
关键词 高炉 风口 喷吹 矿粉 硅迁移
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An Analytical Model of Electron Mobility for Strained-Si Channel nMOSFETs 被引量:1
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作者 李小健 谭耀华 田立林 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2008年第5期863-868,共6页
An analytical model of electron mobility for strained-silicon channel nMOSFETs is proposed in this paper. The model deals directly with the strain tensor,and thus is independent of the manufacturing process. It is sui... An analytical model of electron mobility for strained-silicon channel nMOSFETs is proposed in this paper. The model deals directly with the strain tensor,and thus is independent of the manufacturing process. It is suitable for (100〉/ 〈110) channel nMOSFETs under biaxial or (100〉/〈 110 ) uniaxial stress and can be implemented in conventional device simulation tools . 展开更多
关键词 STRAINED-SI electron mobility analytical model NMOSFET uniaxial stress/strain
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Strained Si-Channel Heterojunction n-MOSFET 被引量:1
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作者 史进 黄文涛 陈培毅 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2002年第7期685-689,共5页
The process parameters are adjusted and the process procedure is simplified on the basis of precursor's work and the strained Si channel SiGe n MOSFET is fabricated successfully.This n MOSFET takes the strained... The process parameters are adjusted and the process procedure is simplified on the basis of precursor's work and the strained Si channel SiGe n MOSFET is fabricated successfully.This n MOSFET takes the strained Si layer(which is deposited on the relaxed SiGe buffer layer) as current channel and can provide a 48 5% improvement in electron mobility while keeping the gate voltage as 1V. 展开更多
关键词 STRAIN SIGE TRANSCONDUCTANCE MOBILITY
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Screening, identification and desilication of a silicate bacterium 被引量:5
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作者 周洪波 曾晓希 +2 位作者 刘飞飞 邱冠周 胡岳华 《Journal of Central South University of Technology》 EI 2006年第4期337-341,共5页
The strain Lv(1- z) isolated from the Henan bauxite was characterized by morphological observation, biochemical and physiological identification, and 16S rDNA sequence analysis. The influences of temperature, initia... The strain Lv(1- z) isolated from the Henan bauxite was characterized by morphological observation, biochemical and physiological identification, and 16S rDNA sequence analysis. The influences of temperature, initial pH value, the volume of medium, shaking speed and illite concentration on the desilicating ability of the strain Lv(1- z) were investigated. The results show that the bacterium is a Gram-negative rod-shaped bacterium with oval endspores and thick capsule, but without flagellum. The biochemical and physiological tests indicate that the strain Lv(1- z) is similar to Bacillus rnucilaginosus. In GenBank the 16S rDNA sequence similarity of the strain Lv(1- z) and the B. rnucilaginosus YNUCC0001(AY571332) is more than 99%. Based on the above results, the strain Lv(1- z) is identified as B. rnucilaginosus. The optimum conditions for the strain L(1- z) to remove silicon from illite are as follows., temperature is 30℃ ;initial pH value is 7.5; medium volume in 200 mL bottle is 60 mL; shaking speed of rotary shaker is 220 r/m ; illite concentration is 1%. 展开更多
关键词 SCREENING IDENTIFICATION Bacillus rnucilaginosus silicon removal
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Carrier Transport Properties in the Doped Micro - crystalline Silicon Films
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作者 ZHONG Bo-qiang (Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050 ,CHN) 《Semiconductor Photonics and Technology》 CAS 1999年第3期186-189,共4页
Doped micro-crystalline silicon films are deposited at temperatures as low as 400 ℃ by the catalytic chemical vapor deposition method using a silane and hydrogen gas mixture. Electrical properties such as the carrier... Doped micro-crystalline silicon films are deposited at temperatures as low as 400 ℃ by the catalytic chemical vapor deposition method using a silane and hydrogen gas mixture. Electrical properties such as the carrier concentration and the Hall mobility are investigated for various measuring temperatures. It is found that the grains of micro-crystalline silicon are preferentially oriented along the (220) direction , and that the Hall mobility is larger than 8 cm 2·V -1 ·s -1 , the carrier concentration is about 1×10 17 cm -1 ~1×10 19 cm -3 at room temperature. 展开更多
关键词 Catalytic Chemical Vapor Deposition Hall Mobility Micro-crystalline Silicon CLC number:TN201 O431 Document code:A
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Impact of 〈100〉Channel Direction for High Mobility p-MOSFETs on Biaxial Strained Silicon
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作者 顾玮莹 梁仁荣 +1 位作者 张侃 许军 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2008年第10期1893-1897,共5页
Biaxial strain technology is a promising way to improve the mobility of both electrons and holes, while (100) channel direction appears as to be an effective booster of hole mobility in particular. In this work, the... Biaxial strain technology is a promising way to improve the mobility of both electrons and holes, while (100) channel direction appears as to be an effective booster of hole mobility in particular. In this work, the impact of biaxial strain together with (100) channel orientation on hole mobility is explored. The biaxial strain was incorporated by the growth of a relaxed SiGe buffer layer,serving as the template for depositing a Si layer in a state of biaxial tensile strain. The channel orientation was implemented with a 45^o rotated design in the device layout,which changed the channel direction from (110) to (100) on Si (001) surface. The maximum hole mobility is enhanced by 30% due to the change of channel direction from (110) to (100) on the same strained Si (s-Si) p-MOSFETs,in addition to the mobility enhancement of 130% when comparing s-Si pMOS to bulk Si pMOS both along (110) channels. Discussion and analysis are presented about the origin of the mobility enhancement by channel orientation along with biaxial strain in this work. 展开更多
关键词 P-MOSFET strained Si channel direction hole mobility enhancement
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Penetration depth at various Raman excitation wavelengths and stress model for Raman spectrum in biaxially-strained Si 被引量:3
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作者 SONG JianJun YANG Chao +3 位作者 HU HuiYong DAI XianYing WANG Cheng ZHANG HeMing 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2013年第11期2065-2070,共6页
The carrier mobility of Si material can be enhanced under strain,and the stress magnitude can be measured by the Raman spectrum.In this paper,we aim to study the penetration depths into biaxially-strained Si materials... The carrier mobility of Si material can be enhanced under strain,and the stress magnitude can be measured by the Raman spectrum.In this paper,we aim to study the penetration depths into biaxially-strained Si materials at various Raman excitation wavelengths and the stress model corresponding to Raman spectrum in biaxially-strained Si.The experimental results show that it is best to use 325 nm excitation to measure the material stress in the top strained Si layer,and that one must pay attention to the distortion of the buffer layers on measuring results while 514 nm excitation is also measurable.Moreover,we established the stress model for Raman spectrum of biaxially-strained Si based on the Secular equation.One can obtain the stress magnitude in biaxially-strained Si by the model,as long as the results of the Raman spectrum are given.Our quantitative results can provide valuable references for stress analysis on strained materials. 展开更多
关键词 strained Si RAMAN STRESS MODEL
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Metamorphic AlInAs/GaInAs HEMTs on silicon substrates by MOCVD 被引量:2
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作者 LI HaiOu HUANG Wei +2 位作者 LI SiMin TANG ChakWah LAU KeiMay 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2011年第10期1815-1818,共4页
Metamorphic Al0.50In0.50As/Ga0.47In0.53As high electron mobility transistors (mHEMTs) grown by Metal Organic ChemicalVapor Deposition (MOCVD) on n-type silicon substrates with introduction of a novel multi-stage buffe... Metamorphic Al0.50In0.50As/Ga0.47In0.53As high electron mobility transistors (mHEMTs) grown by Metal Organic ChemicalVapor Deposition (MOCVD) on n-type silicon substrates with introduction of a novel multi-stage buffering stack scheme havebeen fabricated for the first time. 1.0- m-gate-length depletion-mode mHEMTs with maximum transconductance up to 613mS/mm are achieved. The unity current gain cut-off frequency (fT) and the maximum oscillation frequency (fmax) are 36.9 and55.6 GHz, respectively. This device has the highest fTyet reported for 1.0- m-gate-length HEMTs grown on silicon byMOCVD. Also, this performance is comparable to that of similar GaAs-based mHEMTs. These are encouraging initial resultsleading to the manufacturing potential of integrated high-speed metamorphic devices for logic applications on silicon sub-strates by MOCVD. 展开更多
关键词 GAAS METAMORPHIC HEMT MOCVD
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Effect of ground granulated blast-furnace slag(GGBFS) and silica fume(SF) on chloride migration through concrete subjected to repeated loading 被引量:3
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作者 ZHANG WuMan BA HengJing 《Science China(Technological Sciences)》 SCIE EI CAS 2012年第11期3102-3108,共7页
The effect of ground granulated blast-furnace slag(GGBFS) and silica fume(SF) on the chloride migration through concrete subjected to repeated loading was examined.Portland cement was replaced by 20%,30%,40% GGBFS and... The effect of ground granulated blast-furnace slag(GGBFS) and silica fume(SF) on the chloride migration through concrete subjected to repeated loading was examined.Portland cement was replaced by 20%,30%,40% GGBFS and 5%,10% SF,respectively.Five times repeated loadings were applied to specimens,the maximum loadings were 40% and 80% of the axial cylinder compressive strength(f′c),respectively.Chloride migration through concretes was evaluated using the rapid chloride migration test and the chloride concentration in the anode chamber was measured.The results indicate that the transport number of chloride through concrete containing 20% and 30% GGBFS replacements and 5% and 10% SF replacements is lower than that of the control concrete,but 40% GGBFS replacement increases the transport number of chloride.Five loadings at 40% f′cor 80% f′c increase the transport number of chloride for all mixes investigated in this study.5% SF replacement has a very close effect on the chloride permeability of concrete with 20% GGBFS when concrete is subjected to 40% f′cor 80% f′c. 展开更多
关键词 CONCRETE ground granulated blast-furnace slag (GGBFS) silica fume (SF) chloride migration repeated loading
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Hole mobility of strained Si/(001)Si_(1-x)Ge_x
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作者 WANG XiaoYan ZHANG HeMing +2 位作者 MA JianLi WANG GuanYu QU JiangTao 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2012年第1期48-54,共7页
The hole mobility of strained silicon along the <110> orientation on (001) Si1?xGex is obtained by solving collision term in the Boltzmann transport equation. The analytical model is proposed that considers the ... The hole mobility of strained silicon along the <110> orientation on (001) Si1?xGex is obtained by solving collision term in the Boltzmann transport equation. The analytical model is proposed that considers the effect of strain-induced splitting at valence band valleys in silicon, doping dependence and three scattering mechanisms, i.e., ionized impurity scattering, acoustic phonon scattering and non-polar optical phonon scattering. The hole occupancy at top band indicates a non-monotonic variation under biaxial tensile strain at low temperature (77 K). What's more, a non-monotonic variation of hole mobility at room temperature (300 K) is presented. Compared with the room temperature hole mobility, the low temperature hole mobility is affected greatly by ionized impurity scattering at lower impurity concentration. At the same time, the room temperature hole mobility is lower than that of electron with the same germanium content and doping concentration. If the parameters are correctly chosen, the model can also be used to calculate the hole mobility of other crystal faces with arbitrary orientation. So, it lays a useful foundation for strained silicon devices and circuits. 展开更多
关键词 subband hole occupancy scattering model germanium content hole mobility
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Fabrication of 0.3-m T-gate metamorphic AlInAs/GaInAs HEMTs on silicon substrates using metal organic chemical vapor deposition 被引量:1
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作者 TANG ChakWah LAU KeiMay 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2012年第4期644-648,共5页
We present an InGaAs metamorphic high electron mobility transistor (mHEMT) grown using Metalorganic Chemical Vapor Deposition (MOCVD) on an n-type silicon substrate with the introduction of an effective multi-stag... We present an InGaAs metamorphic high electron mobility transistor (mHEMT) grown using Metalorganic Chemical Vapor Deposition (MOCVD) on an n-type silicon substrate with the introduction of an effective multi-stage buffering scheme. Fabrication and performance of a high-frequency 0.3μm gate-length depletion-mode A10.s0In0.s0As/Ga0.47In0.53As mHEMT is re- ported for the first time. Using a combined optical and e-beam photolithography technology, submicron mHEMT devices on Si have been achieved. The non-alloyed ohmic contact resistance Rc was as low as 0.065 Ω-mm. A maximum transconductance up to 761 mS/ram was measured. The unity current gain cut-off frequency (fT) and the maximum oscillation frequency (fmax) were 72.8 and 74.5 GHz, respectively. This device has the highest fw yet reported for a 0.3-μm gate-length Si-based mHEMT grown using MOCVD. A high voltage gain, gm/gds, of 40.6 is observed in the device. 展开更多
关键词 silicon METAMORPHIC HEMT MOCVD
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