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西藏甲玛矿床硅钙界面对矽卡岩成岩及多金属成矿的影响 被引量:15
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作者 姚晓峰 叶天竺 +4 位作者 唐菊兴 郑文宝 丁帅 李永胜 甄世民 《中国地质》 CAS CSCD 北大核心 2014年第5期1577-1593,共17页
西藏甲玛铜多金属矿床为冈底斯成矿带的超大型矿床之一,其矽卡岩型主矿体受林布宗组砂板岩、角岩(硅铝质岩石)和多底沟组大理岩(钙质岩石)的岩性界面所控制。基于岩、矿心地质编录,开展矽卡岩岩石、矿物分带及矽卡岩地球化学、矿物化学... 西藏甲玛铜多金属矿床为冈底斯成矿带的超大型矿床之一,其矽卡岩型主矿体受林布宗组砂板岩、角岩(硅铝质岩石)和多底沟组大理岩(钙质岩石)的岩性界面所控制。基于岩、矿心地质编录,开展矽卡岩岩石、矿物分带及矽卡岩地球化学、矿物化学研究,探讨硅钙岩性界面对矽卡岩及多金属矿体形成的影响。从顶板至底板由石榴子石矽卡岩、硅灰石石榴子石矽卡岩至硅灰石矽卡岩表现出Si O2、Ca O逐渐增加和Al2O3、Fe2O3+Fe O逐渐减少的趋势,石榴子石矽卡岩、硅灰石矽卡岩的稀土元素和微量元素特征对顶板、底板岩石表现出明显的继承性。靠近顶板的矽卡岩中石榴子石属于钙铝-钙铁过渡系列,由石榴石核部向外环带具有Al含量减少、Fe含量增加的特点;靠近底板矽卡岩相对于靠近顶板具有钙铁榴石比例增加、钙铝榴石比例减少特征,由核部向外围未见明显的环带成分演变特征。矽卡岩是流体与硅铝质、钙质岩石水岩反应的产物,沿硅钙界面流体减压沸腾、地下水混合作用和界面内垂向的流体地球化学障是主要的致矿机制。硅、铝质岩石化学性质、物理性质差异是界面控矿的主要因素,硅钙面复合张性构造带、岩浆热事件增加界面渗透率差异有利于矿体规模的增加和品位提高。 展开更多
关键词 甲玛 硅钙界面 矽卡岩 岩石地球化学 矿物化学 成矿作用
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福建潘田铁矿床花岗岩岩石地球化学特征、锆石U-Pb年代学及其与成矿的关系 被引量:19
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作者 来守华 陈仁义 +4 位作者 张达 狄永军 龚勇 袁远 陈良 《岩石学报》 SCIE EI CAS CSCD 北大核心 2014年第6期1780-1792,共13页
潘田铁矿床矿体主要赋存于潘田花岗岩体外接触带的"硅钙岩性界面"中,其成矿与花岗岩侵入关系密切,是一个具有很大找矿潜力的富铁矿床。但前人对该花岗岩的研究还很薄弱,本文对潘田铁矿花岗岩进行了岩石地球化学特征、锆石U-P... 潘田铁矿床矿体主要赋存于潘田花岗岩体外接触带的"硅钙岩性界面"中,其成矿与花岗岩侵入关系密切,是一个具有很大找矿潜力的富铁矿床。但前人对该花岗岩的研究还很薄弱,本文对潘田铁矿花岗岩进行了岩石地球化学特征、锆石U-Pb定年研究,探讨其岩石成因、形成时代、构造环境、及其与成矿的关系。LA-ICP-MS锆石U-Pb定年获得其结晶年龄为131.68±0.48Ma。该岩体为高钾钙碱性系列,属弱过铝质-准铝质岩石;稀土元素总量较低,轻稀土相对于重稀土富集,具有明显铕负异常,重稀土配分模式相对平坦,中稀土相对亏损。微量元素中相对富集大离子亲石元素而亏损高场强元素。岩石地球化学特征表明潘田岩体为高分异I型花岗岩,形成于碰撞后拉张环境。潘田铁矿床矿体与花岗岩体的空间分布规律与成因关系表明,花岗岩侵入作用是控制主成矿阶段矿体空间定位的地质作用,花岗岩是铁矿床的成矿地质体,林地组碎屑岩与黄龙组-栖霞组碳酸盐岩的接触界面是成矿有利部位,矿床类型属于典型"硅钙岩性界面"成矿,本矿床的成因类型属于"多因耦合、临界转换、边界成矿"的典型案例。 展开更多
关键词 高分异I型花岗岩 锆石U—Pb年代学 硅钙岩性界面 铁矿床 潘田
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Adsorption of sodium polyacrylate at interface of dicalcium silicate-sodium aluminate solution 被引量:5
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作者 于海燕 潘晓林 +3 位作者 丁婷婷 张武 刘涵 毕诗文 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2011年第10期2323-2326,共4页
The adsorption isotherm of sodium polyacrylate on dicalcium silicate(2CaO-SiO2) in sodium aluminate solution at 80 ℃ was studied.The type of surface adsorption of sodium polyacrylate is saturated adsorption,and the... The adsorption isotherm of sodium polyacrylate on dicalcium silicate(2CaO-SiO2) in sodium aluminate solution at 80 ℃ was studied.The type of surface adsorption of sodium polyacrylate is saturated adsorption,and the adsorption behavior belongs to L-type,according with the monolayer adsorption model of Langmuir equation.The surface coverage of sodium polyacrylate is 1.06 mol/μm2.The relation curve between the surface pressure and the molecular area of adsorption film was obtained by Gibbs formula.The variation of interfacial energy caused by adsorption as well as the relationship between the relation curve and the type of adsorption was discussed. 展开更多
关键词 sodium aluminate solution sodium polyacrylate dicalcium silicate INTERFACE ADSORPTION
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A molecular dynamics study of calcium silicate hydrates-aggregate interfacial interactions and influence of moisture 被引量:3
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作者 ZHOU Yang PENG Ze-chuan +3 位作者 HUANG Jia-le MA Tao HUANG Xiao-ming MIAO Chang-wen 《Journal of Central South University》 SCIE EI CAS CSCD 2021年第1期16-28,共13页
The interface properties between hydrated cement paste(hcp)and aggregates largely determine the various performances of concrete.In this work,molecular dynamics simulations were employed to explore the atomistic inter... The interface properties between hydrated cement paste(hcp)and aggregates largely determine the various performances of concrete.In this work,molecular dynamics simulations were employed to explore the atomistic interaction mechanisms between the commonly used aggregate phase calcite/silica and calcium silicate hydrates(C-S-H),as well as the effect of moisture.The results suggest that the C-S-H/calcite interface is relatively strong and stable under both dry and moist conditions,which is caused by the high-strength interfacial connections formed between calcium ions from calcite and high-polarity non-bridging oxygen atoms from the C-S-H surface.Silica can be also adsorbed on the dry C-S-H surface by the H-bonds;however,the presence of water molecules on the interface may substantially decrease the affinities.Furthermore,the dynamics interface separation tests of C-S-H/aggregates were also implemented by molecular dynamics.The shape of the calculated stress-separation distance curves obeys the quasi-static cohesive law obtained experimentally.The moisture conditions and strain rates were found to affect the separation process of C-S-H/silica.A wetter interface and smaller loading rate may lead to a lower adhesion strength.The mechanisms interpreted here may shed new lights on the understandings of hcp/aggregate interactions at a nano-length scale and creation of high performance cementitious materials. 展开更多
关键词 calcium silicate hydrate AGGREGATE interfacial connections molecular dynamics simulation MOISTURE
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