聚γ-甲硒基丙基硅氧烷铂配合物的合成与催化硅氢化性能

γ－氯丙基三乙氧基硅烷依次与气相法二氧化硅、甲硒基钠、氯亚铂酸钾作用，合成了聚γ－甲硒基丙基硅氧烷铂配合物，研究了该配合物对烯烃与三乙氧基硅烷硅氢加成反应的催化特性．

SYNTHESIS AND CATALYTIC ACTIVITY OF PLATINUM COMPLEX OF ACRYLATE TERPOLYMER WITH Se, N BIDENTATE LIGAND

Acrylate terpolymer- bound Se, N bidentate ligand was synthesized fromthe side chain chlorine of copolymer and β- dimethylamino -β - hydroxyl diethyl selenoether. The polymer - supported platinum complex exhibited highcatalytic activity in the hodrosilylation of olefins with triethoxysilane.