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用差示红外光谱法测定旧汽油机油中氧化值和硝化值 被引量:13
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作者 冯心凭 戴月菊 周毅 《石油与天然气化工》 CAS CSCD 北大核心 2002年第3期154-155,164,共3页
根据差示红外光谱法原理 ,测定并记录在用油和新油在 185 0~ 15 5 0cm- 1的红外光谱图 ,运用计算机进行差谱分析处理 ,在差谱图中读取 185 0cm- 1和 172 0cm- 1及 16 30cm- 1处的吸收值 ,再根据基线法分别求出旧油中的氧化值和硝化值... 根据差示红外光谱法原理 ,测定并记录在用油和新油在 185 0~ 15 5 0cm- 1的红外光谱图 ,运用计算机进行差谱分析处理 ,在差谱图中读取 185 0cm- 1和 172 0cm- 1及 16 30cm- 1处的吸收值 ,再根据基线法分别求出旧油中的氧化值和硝化值。试验结果表明 ,使用该分析方法所得的数据准确性高、重复性好。差示红外光谱法测定油品中氧化值。 展开更多
关键词 差示红外光谱法 测定 旧汽油机油 氧化 硝化值 润滑油
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FT-IR测定内燃机油中氧化值和硝化值
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作者 张华 王璧人 张红革 《光谱实验室》 CAS CSCD 1997年第6期58-61,共4页
使用NICOLET20DXB傅里叶变换红外光谱仪,应用差示红外光谱法测定经过规定的台架试验后内燃机油中氧化值和硝化值。考察了台架试验条件,试验时间对内燃机油中氧化值和稍化值的影响。
关键词 氧化 硝化值 内燃机油 机油 FTIR
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甲醇汽油对汽油机油氧化和硝化的影响 被引量:4
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作者 董元虎 王娇 朱心阔 《润滑与密封》 CAS CSCD 北大核心 2007年第6期90-92,120,共4页
应用红外光谱技术,根据不同物质在红外光谱仪中的吸光度不同,研究了在汽油机油中加入不同配比和含量的甲醇、甲醛和甲酸对汽油机油的抗氧化性和抗硝化性的影响。结果表明,加入甲醇、甲醛和甲酸后的油样和汽油机油相比,氧化和硝化程度都... 应用红外光谱技术,根据不同物质在红外光谱仪中的吸光度不同,研究了在汽油机油中加入不同配比和含量的甲醇、甲醛和甲酸对汽油机油的抗氧化性和抗硝化性的影响。结果表明,加入甲醇、甲醛和甲酸后的油样和汽油机油相比,氧化和硝化程度都增大了;加入甲醇汽油的油样和加入甲酸或甲醛的油样相比,硝化值和氧化值都比较大,表明甲醇汽油对汽油机油的抗氧化性和抗硝化性的影响最大,甲醛和甲酸的影响较小。 展开更多
关键词 甲醇汽油 汽油机油 氧化 硝化值
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基于红外光谱技术的柴油机油氧化降解换油指标研究 被引量:12
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作者 徐金龙 易如娟 《润滑油》 CAS 2011年第4期37-40,共4页
利用中红外光谱仪,依据ASTM E2412测定了7种装备上使用的4种柴油机油累计469个油样的氧化值、硝化值及磺化值,通过对数据的频数分布直方图的计算分析,研究得出了氧化值、硝化值和磺化值的换油指标分别为0.25A/0.1 mm、0.25A/0.1 mm和0.2... 利用中红外光谱仪,依据ASTM E2412测定了7种装备上使用的4种柴油机油累计469个油样的氧化值、硝化值及磺化值,通过对数据的频数分布直方图的计算分析,研究得出了氧化值、硝化值和磺化值的换油指标分别为0.25A/0.1 mm、0.25A/0.1 mm和0.20A/0.1 mm,为国内外柴油机油换油指标的制定提供一种新的方法或依据。 展开更多
关键词 红外光谱 在用油 氧化 硝化值 磺化 界限
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Decreased Soil Nitrification Rate with Addition of Biochar to Acid Soils 被引量:2
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作者 Shiyu LI Xiangshu DONG +2 位作者 Dandan LIU Li LIU Feifei HE 《Agricultural Science & Technology》 CAS 2017年第10期1932-1934,共3页
This study was conducted to investigate the effects of mixed biochar on the nitrification rate in acidic soils. A15 N tracer experiment with(15 NH4)2 SO4 was conducted to determine the nitrification rates of 4 acidic ... This study was conducted to investigate the effects of mixed biochar on the nitrification rate in acidic soils. A15 N tracer experiment with(15 NH4)2 SO4 was conducted to determine the nitrification rates of 4 acidic agricultural soils with p H 4.03-6.02 in Yunnan Province, Southern China. The accumulation of15 N-NO3-and nitrification rates decreased with the addition of biochar at the end of incubation, suggesting that biochar could be a nitrification inhibitor in acidic fertilized soil. Nitrification rates in soil with p H 4.03 were evidently lower than those in soil with p H 4.81-6.02 with or without biochar. Decreased nitrification rates were detected in the acidic soils with biochar. Soil p H controlled nitrification more than biochar in certain strongly acidic soils. 展开更多
关键词 Nitrification rate BIOCHAR 15N tracer Acidic soil
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Nitrification Potential of Soils Under Liquid Incubation Conditions 被引量:4
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作者 YUANFei RANWei SHENQi-Rong 《Pedosphere》 SCIE CAS CSCD 2005年第3期379-385,共7页
A red soil, a fluvo-aquic soil and a permeable paddy soil were used in a long-term investigation to study changes in nitrification with treatments: 1) soil incubation, 2) liquid incubation inoculated with soil samples... A red soil, a fluvo-aquic soil and a permeable paddy soil were used in a long-term investigation to study changes in nitrification with treatments: 1) soil incubation, 2) liquid incubation inoculated with soil samples, and 3) liquid incubation inoculated with ammonia-oxidizing bacteria (AOB) from the soils. There were significant differences (P < 0.001) in nitrification rates among the three soils when measured for 28 days by adding (NH4)SO4 at the rate of 154 mg N kg-1 dry soil to fresh soil. However, t… 展开更多
关键词 ammonia-oxidizing bacteria NITRIFICATION PH soil type
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Denitrification in Natural Nutritious Medium 被引量:1
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作者 H. Bougherara O. Bentabet R. Meribout W. Cheurfi B. Kebabi 《Journal of Environmental Science and Engineering》 2011年第9期1093-1099,共7页
The intensive use of nitrogen fertilizers in Algeria caused a pollution of the waters by nitrates. This concentration reached in the region of Collo (Wilaya of Skikda, Algeria) 570 mg/L, which is beyond the WHO stan... The intensive use of nitrogen fertilizers in Algeria caused a pollution of the waters by nitrates. This concentration reached in the region of Collo (Wilaya of Skikda, Algeria) 570 mg/L, which is beyond the WHO standard (50 mg/L). This has negative consequences on human health (Methemoglobinemia) and on the environment (eutrophication). In our works, we studied the elimination of this pollution with the use of a mixed culture of microorganisms. We replaced the standard synthetic carbon source and the nutritious medium by date powder. This contains minerals and sugars that can enhance bacterial growth. Our study showed that the effectiveness of denitrification is proportional to bacterial growth. It rises exponentially after a latency period of 8 hours. During the reaction of degradation we noticed a rise in pH in our engine, it moved from 7.00 to 8.38. In studying the influence of initial pH on the denitrification of the microorganisms, we observed that the ion hydrogen concentration modified the growth rate of bacteria and degradation of nitrates. An acid pH, the reduction of nitrates is incomplete; this is accounted for the accumulation of nitrous and nitric oxide that interferes in the reaction of denitrification. The velocity of the nitrate reduction is less important in an acid pH (0.0096 g.L^-l.h^-1) than in a basic pH (0.013 g.L^-1.h^-1). The denitrification is optimal at temperature 35 ℃ for a ratio C/N = 2.5. In these conditions 95% of the nitrate initial quantity is eliminated after approximately 100 hour treatment. 展开更多
关键词 Mixed culture DENITRIFICATION carbon source nutritious medium date powder
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Effect of Anions on Adsorbability and Extractability of Lead Added in Soil 被引量:6
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作者 CHEN HUAI-MAN, ZHENG CHUN-RONG and SUN XIAO-HUALaboratory of Material Cycling in Pedosphere, ’Institute of Soil Science, A cademia Sinica, P. O. Box 821, Nanjing (China) 《Pedosphere》 SCIE CAS CSCD 1991年第1期51-62,共12页
The effect of accompanying anions on the adsorbability and extractability of Pb added in soils was studied by using bach equilibria and incubation-extraction mothods.Pb concentration ranged between 0.48-2.41 mM in the... The effect of accompanying anions on the adsorbability and extractability of Pb added in soils was studied by using bach equilibria and incubation-extraction mothods.Pb concentration ranged between 0.48-2.41 mM in the adsorption experiment,and Pb added to soil from 2.14 to 19.31mM Pb/kg with an incubation time of 2-16 weeks in the incubation-extraction test in which 1M NH4OAc(pH 7) was taken as an extraction agent,and the Pb compounds used are PbCl2,Pb(NO3)2 and Pb(OAc)2.The values of pH50 for Pb retention and the parameters,b and k values,of Langmuir equation were used to distinguish the difference of adsorbability and extractability of Pb affected by anions,respectively.Judging from the results of either pH50 value or b value,the influences of Cl^- and NO3^- on the adsorbability and extractability of Pb in soils were similar but quite different from those of OAc^-.The relative loading capacities of soils to Pb calculated according to the extraction rate showed that the values of Pb(OAc)2 were higher than those of PbCl2 and Pb(NO3)2. 展开更多
关键词 ANION Langmuir equation PB pH50 SOIL
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Development Trends and Evaluation of Egbe Reservoir Water Nutrient Status in Ekiti State, Nigeria
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作者 Josephine Bolaji Edward Adiaha Aldah Alex Ugwumba 《Journal of Life Sciences》 2010年第1期7-16,共10页
A study about some physicochemical parameters of Egbe reservoir was carried out from September 2005 to December 2006. The parameters include mean temperature, pH, conductivity, alkalinity, TSS, TDS, DO and BOD which h... A study about some physicochemical parameters of Egbe reservoir was carried out from September 2005 to December 2006. The parameters include mean temperature, pH, conductivity, alkalinity, TSS, TDS, DO and BOD which have values of 28.7±0.9 ℃ ; 8.3±0.3; 831±172.5 μS/cm; 165.4±18.3 mg/L; 0.06±0.1 mg/L; 0.4±0.6 mg/L; 7.8±2.4 mg/L and 5.2±1.6mg/L, respectively. Temperature and pH were measured in the field using mercury-in-glass thermometer calibrated in degrees Celsius and pH meter, respectively. TSS and TDS were measured by grayimetric methods, while alkalinity was measured titrimetrically and DO and BOD were measured by Winkler's method. For the nutrients, nitrate was measured color±metrically, phosphate by Stannous Chloride method and sulphate by turbidimetric method. Mean concentration of nitrate, phosphate, and sulphate were 15.6±8.6 rag/L; 42.5±19.4 mg/L and 72.3±14.7 mg/L respectively. Nowadays, eutrophication of natural waters is one of the most significant causes of deterioration of water quality, and nitrates and phosphates are probably the key nutrients in controlling the growth of aquatic plants. Though the mean concentration of nitrates and phosphates in the reservoir water were within the acceptable limit, yet their concentrations in some locations of reservoir were high enough to encourage the growth of aquatic macrophytes which would increase productivities. Hence, it is necessary to check their further increase, and periodic monitoring and preventive measures must be adopted to save the reservoir from eutrophication. 展开更多
关键词 Physico-chemical parameters development trends NUTRIENTS Egbe reservoir.
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SL15W/40汽油机油质量特性的应用研究
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作者 耿向 尤帆 《中国石油和化工标准与质量》 2016年第2期15-17,共3页
经实验室模拟评定的SL15W/40汽油机油,全分析合格后,从实车试验的角度研究选取了试验车辆,对SL15W/40汽油机油的质量特性进行了应用研究,行车试验里程设为10 000 km,在行车试验过程中,分别在0、2 000 km、4 000 km、6 000 km、8 000 km... 经实验室模拟评定的SL15W/40汽油机油,全分析合格后,从实车试验的角度研究选取了试验车辆,对SL15W/40汽油机油的质量特性进行了应用研究,行车试验里程设为10 000 km,在行车试验过程中,分别在0、2 000 km、4 000 km、6 000 km、8 000 km、10 000 km时,采集行车试验油样并利用常规理化分析与仪器分析相结合的方法,分析了油品的100℃运动粘度、氧化值、硝化值、硫化值、金属元素、酸值、戊烷不溶物的变化及试验后油样的闪点、水分,并对实验结果进行了讨论。 展开更多
关键词 100℃运动粘度 氧化 硝化值 硫化 金属元素 戊烷不溶物的变化 闪点、水分
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Combined Use of Alkaline Slag and Rapeseed Cake to Ameliorate Soil Acidity in an Acid Tea Garden Soil 被引量:5
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作者 WANG Lei YANG Xing-Lun +4 位作者 K. RACHEL WANG Yu TONG De-Li YE Mao JIANG Xin 《Pedosphere》 SCIE CAS CSCD 2013年第2期177-184,共8页
Rapeseed cake (RC), the residue of rapeseed oil extraction, is effective for improving tea (Camellia sinensis) quality, especially taste and aroma, but it has limited ability to ameliorate strongly acidic soil. In... Rapeseed cake (RC), the residue of rapeseed oil extraction, is effective for improving tea (Camellia sinensis) quality, especially taste and aroma, but it has limited ability to ameliorate strongly acidic soil. In order to improve the liming potential of RC, alkaline slag (AS), the by-product of recovery of sodium carbonate, was incorporated. Combined effects of different levels of RC and AS on ameliorating acidic soil from a tea garden were investigated. Laboratory incubations showed that combined use of AS and RC was an effective method to reduce soil exchangeable acidity and A1 saturation and increase base saturation, but not necessarily for soil pH adjustment. The release of alkalinity from the combined amendments and the mineralization of organic nitrogen increased soil pH initially, but then soil pH decreased due to nitrifications. Various degrees of nitrification were correlated with the interaction of different Ca levels, pH and N contents. When RC was applied at low levels, high Ca levels from AS repressed soil nitrification, resulting in smaller pH fluctuations. In contrast, high AS stimulated soil nitrification, when RC was applied at high levels, and resulted in a large pH decrease. Based on the optimum pH for tea production and quality, high ratios of AS to RC were indicated for soil acidity amelioration, and 8.0 g kg-1 and less than 2.5 g kg-1 were indicated for AS and RC, respectively. Further, field studies are needed to investigate the variables of combined amendments. 展开更多
关键词 AMELIORATION amendments LIME pH
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