新疆北山早二叠世岩浆型铜镍硫化物矿床综合信息勘查模式

新疆北山发育有20~30个产于晚古生代北山裂谷带中的早二叠世超基性岩岩体。自2008年以来在坡北基性-超基性杂岩体中发现坡一大型镍矿床和坡十中型镍矿床。利用本项目资料结合前人研究成果,文章从构造、岩体基本特征、围岩条件、矿物学特征、化探异常特征、地球物理参数等多个方面总结了含矿岩体(相)与非含矿岩体(相)的区别。研究发现新疆北山铜镍矿矿床受深大断裂控制,多产于深大断裂一侧的次级断裂中。在预查阶段或预查以前,可以首先利用1∶20万和1∶5万勘查地球化学数据,对Cu、Ni、Co、Cr异常区进行调查研究,同时辅以ETM遥感线环解译、1∶5万航磁资料的化极和向上延拓图(关注高磁异常)和1∶5万重力资料的布格重力异常(关注△GB>-142×10g.u的区域)来圈定区域上的基性超基性岩体。地表的孔雀石蚀变、黄钾铁矾和镍华是寻找铜镍矿的重要线索。在普查阶段,若存在纯橄岩且岩相分异良好的杂岩体,则更有可能发现铜镍矿。同一地区,具有高Cr尖晶石且尖晶石Fe3+/ΣFe<0.3的基性-超基性杂岩体,成铜镍矿的潜力更大;含最超基性或接近最超基性的岩相的岩体成铜镍矿的可能性更大;含有高Fo、高NiO、低FeO*、低CaO、低TiO2的橄榄石且低Fe、Ca含量辉石的岩相是铜镍矿勘查的优选岩相。围岩有硫化物、硫酸盐或石墨层的超基性岩体的成矿潜力要大于围岩为无硫化物方解石大理岩的超基性岩体的成矿潜力。在此基础上,瞬变电磁(TEM)方法获得的瞬变响应感应电动势的垂直分量DBz/Dt(>1.2)数据和可控源声频大地电磁可以用来推断深部超基性岩体的分布,是深部验证的重要依据。三维磁化率反演可以为矿区的定位预测或确定超基性岩体的延伸情况提供一定的依据。井中磁测可以作为防止漏矿的一种补充方法。在详查阶段,通过精细钻孔编录和三维软件查明矿体的空间展布趋势规律可为定位预测提供依据。文章总结了针对新疆北山地区铜镍硫化物矿床的综合信息勘查模型和勘查策略,并对硫化物饱和机制进行了探讨。

高同型半胱氨酸血症与高血压病发病机制的研究进展

高血压病在我国患病率极高,同时它也是各类慢性非传染性公众疾病中最为常见,对国家卫生系统负担最重,对患者生活质量及生存率影响极大的疾病之一。既往关于高血压病发病危险因素的研究已经甚多,但仍然没有直接有力的证据表明众多危险因素与高血压病发病机制之间有直接的量化关系。同型半胱氨酸是人体内一种非必需氨基酸,当它在人体内质量浓度超过10μmol/L时,诊断为高同型半胱氨酸血症。大量的临床研究表明高同型半胱氨酸血症与高血压病的发生发展有着密不可分的关系。现对高同型半胱氨酸血症与高血压病发病机制的研究进展进行综述。

聚硫密封剂用降解剂的制备技术研究

通过分析聚硫密封剂的化学成分、硫化机制以及硫化后橡胶的分子结构,优选出相对最佳的亲电试剂与聚硫橡胶溶剂进行复配;然后分别探讨了复合溶剂对不同密封剂溶解性能的影响,从而优选出溶剂的溶解效率与溶解时间的关系,分析出溶解过程中橡胶的力学性能与溶解率之间的内在联系,确定了降解剂的制备方法。研究结果表明:二巯基苯并噻唑络合物溶剂与碳正离子亲电试剂进行复配,可制得室温快速降解聚硫橡胶的降解剂;该降解剂可迅速作用于聚硫橡胶的交联点,使交联点化学键发生断裂;当w(降解剂)=7%(相对于二巯基苯并噻唑络合物溶剂质量而言)时,其对聚硫密封剂的降解效率明显提高。

Study on Kinetics for Desulfurization of Model Diesel

In this study,by means of the experiments for desulfurization of model diesel through oxidative extraction,the changes associated with the rate of desulfurization of diesel and the mechanism for oxidation of sulfides in diesel were explored. Through studying the mechanism for oxidation of sulfides and the principle of solvent extraction,the kinetic equation of desulfurization via oxidative extraction were determined. By means of the evaluation of model parameters and curve fitting,the reaction order between organic sulfide and sulfone,the intrinsic oxidation rate constant of organic sulfide and sulfone,and the equilibrium constant between sulfone in model diesel and extractive solvent were determined. The experimental values of the desulfurization rate and the theoretical values of the corresponding model equation had closely demonstrated that the desulfurization reaction rate had high accuracy. And the reaction kinetics could provide an important basis for diesel desulfurization process in the future.

Activation flotation and mechanism of lime-depressed pyrite with oxalic acid

Flotation tests, contact angle measurements, infrared spectrum analyses, X-ray analyses and computer simulation were carried out in order to study the activation mechanism of lime-depressed pyrite with oxalic acid. The results show that the oxalic acid effectively eliminated the hydrophilic calcium film from the surface of pyrite. Therefore, the efficiency of pyrite flotation was also activated. The results indicate that after reacting with hydrophobic insoluble remainders on the surface of pyrite, oxalic acid can pro- duce hydrophilic compounds, such as CaC03, Ca（OH）2 and Fe（OH）3. As a consequence, a flesh pyrite layer was exposed and its flotation activated.

Hg^0 absorption in potassium persulfate solution

The aqueous phase oxidation of gaseous elemental mercury (Hg0) by potassium persulfate (KPS) catalyzed by Ag+ was investigated using a glass bubble column reactor. Concentration of gaseous mercury and potassium persulfate were measured by cold vapor atom absorption (CVAA) and ion chromatograph (IC), respectively. The effects of pH value, concentration of potassium persulfate and silver nitrate (SN), temperature, Hg0 concentration in the reactor inlet and tertiary butanol (TBA), free radical scavenger, on the removal efficiency of Hg0 were studied. The results showed that the removal efficiency of Hg0 increased with increasing concentration of potassium persulfate and silver nitrate, while temperature and TBA were negatively effective. Furthermore, the removal efficiency of Hg0 was much better in neutral solution than in both acidic and alkaline solution. But the influence of pH was almost eliminated by adding AgNO3. High Hg0 concentration has positive effect. The possible reaction mechanism of gaseous mercury was also discussed.

Mechanism of stibnite volatilization at high temperature

The volatilization of stibnite(Sb2S3) in nitrogen from 700 to 1000 °C was investigated by using thermogravimetric analysis. The results indicate that in inert atmosphere, stibnite can be volatilized most efficiently as Sb2S3(g) at a linear rate below850 °C, with activation energy of 137.18 k J/mol, and the reaction rate constant can be expressed as k=206901exp(-16.5/T). Stibnite can be decomposed into Sb and sulfur at temperature above 850 °C in a nitrogen atmosphere. However, in the presence of oxygen,stibnite is oxidized into Sb and SO2 gas at high temperature. Otherwise, Sb is oxidized quickly into antimony oxides such as Sb2O3 and Sb O2, while Sb2O3 can be volatilized efficiently at high temperature.

pH variation mechanism of high sulfur-containing bauxite

In order to fundamentally solve the acidification problem of high sulfur-containing bauxite during storage, by simulating the environment of minerals storage in laboratory, the acidification mechanism and influencing factors of high sulfur-containing bauxite were studied and confirmed using the single variable method to control the atmosphere, water and other variables. The results show that the acidification is mostly caused by the oxidation of sulfur-containing bauxite, which is mainly the natural oxidation of Pyrite(Fe S2), then the alkaline minerals dissolute in the presence of water, leading to the acidification phenomenon, which is influenced by moisture and air flow. Finally, more acid-producing substances are formed, resulting in the acidification of high sulfur-containing bauxite. The acidification of high sulfur-containing bauxite results from the combined effect of the oxygen in the air and water, which can be significantly alleviated by controlling the diffusion of the oxygen in air.

Optical Properties of CdS.Nanobelts and Nanosaws Synthesized by Thermal Evaporation Method

By a simple one-step H2-assisted thermal evaporation method, high quality CdS nanos- tructures have been successfully fabricated on Au coated Si substrates in large scale. The as-synthesized CdS nanostructures consisted of sword-like nanobelts and toothed nanosaws with a single-crystal hexagonal wurtzite structure. The deposition temperature played an important role in determining the size and morphology of the CdS nanostruetures. A combination of vapor-liquid-solid and vapor-solid growth mechanisms were proposed to interpret the formation of CdS nanostructures. Photoluminescence measurement indicated that the nanobelts and nanosaws have a prominent green emission at about 512 nm, which is the band-to-band emission of CdS. The waveguide characteristics of both types of CdS nanos-truetures were observed and discussed.

典型氧化铜铅锌矿物浮选的硫化及其强化研究新进展

硫化浮选是处理氧化铜铅锌矿最重要的方法,而硫化则是氧化铜铅锌矿硫化浮选中重要环节。然而,传统的氧化矿物硫化理论存在着不足之处,这已经在一定程度上制约着氧化矿物硫化浮选理论的发展。在现有研究基础上,本文总结了传统硫化理论的不足之处,提出了基于"氧化矿物—溶液界面耦合的溶解—沉淀"的硫化机制,分析了氧化矿物的硫化浮选行为,回顾了三种典型氧化矿物(孔雀石、白铅矿和菱锌矿)的硫化机制及其强化研究的脉络,介绍了最新研究进展,对氧化矿物浮选的硫化及其强化研究进行了展望。

Flotation separation of arsenopyrite from several sulphide minerals with organic depressants

In this paper, the separation of arsenopyrite from chalcopyrite, pyrite, galena with organic depressants （guergum and sodium humic ） was discussed, and the functioning mechanism of those organic depressants was discussed. The experimental results of monomineral flotation indicated that both guergum and sodium humic have depressing effect on arsenopyrite in the presence of ethyl xanthate. Guergum and sodium humic showed different depressing ability to pyrite, chalcopyrite and galena, and the higher the pH value in pulp, the stronger the depressing ability. Ultraviolet-Visible Spectrophotometric study showed that the adsorption layer of xanthate on surface of minerals had been desorhed by the two organic depressants, and the selective desorption of the collector layer was found from different minerals. The xanthate cover on minerals surface was set free when dosage of the organic depressants was high enough. For artificially-mixed minerals, the separation of arsenopyrite from other sulphides was successfully realized by controlling dosage of the organic depressants. And sodium humic had been concentrates in a commercial Lead-Zinc concentrator.

Electrochemical mechanism of rusticyanin (Rus.) isolated from A.ferrooxidans measured by Rus.-ZnS-QDs/L-Cys/Au electrode

Electrochimcal behaviors of rusticyanin （Rus.） isolated from Acidithiobacillus ferrooxidans were investigated through Rus.-ZnS-QDs/L-Cys/Au electrode. The cyclic voltammetric results indicate that rusticyanin immobilized on the surface of Rus.-ZnS-QDs/L-Cys/Au electrode can undergo a direct quasi-reversible electrochemical reaction. The immobilized rusticyanin is not denatured and still retains its activity in the temperature range of 19-43 ℃. The reduction ability of the protein increases and its oxidation ability becomes weak with the increase of pH from 6.0 to 7.8. Fe^2＋ ions in the solution can promote the electron transfer kinetics of the immobilized rusticyanin and make its peak potentials （φp） markedly move negatively.

The bond evolution mechanism of covalent sulfurized carbon during electrochemical sodium storage process

The excellent energy storage performance of covalent sulfur-carbon material has gradually attracted great interest. However, in the electrochemical sodium storage process, the bond evolution mechanism remains an elusive topic. Herein, we develop a one-step annealing strategy to achieve a high covalent sulfur-carbon bridged hybrid(HCSC)utilizing phenylphosphinic acid as the carbon-source/catalyst and sodium sulfate as the sulfur-precursor/salt template, in which the sulfur mainly exists in the forms of C–S–C and C–S–S–C. Notably, most of the bridge bonds are electrochemically cleaved when the cycling voltage is lower than0.6 V versus Na/Na+, leading to the appearance of two visible redox peaks in the following cyclic voltammogram(CV) tests.The in-situ and ex-situ characterizations demonstrate that S^2- is formed in the reduction process and the carbon skeleton is concomitantly and irreversibly isomerized. Thus, the cleaved sulfur and isomerized carbon could jointly contribute to the sodium storage in 0.01–3.0 V. In a Na-S battery system, the activated HCSC in cut off voltage window of 0.6–2.8 V achieves a high reversible capacity(770 mA h g^-1 at 300 mA g^-1). This insight reveals the charge storage mechanism of sulfur-carbon bridged hybrid and provides an improved enlightenment on the interfacial chemistry of electrode materials.

Kinetic study on desulfurization and denitrification using microwave irradiation over activated carbon

Sulfur dioxide （SO2） and nitrogen oxide （NOx） in flue gas can be removed by combining microwave induced catalysis and adsorption on activated carbon. The reaction mechanisms of desulfurization and denitrification by microwave irradiation were analyzed based on the measurement of reaction products. Thermodynamic parameters for desulfurization and denitrification by thermal-carbon reduction were predicted according to the principles of thermodynamics. The experimental results indicated that the desulfurization and denitrification reaction processes include three reaction stages： slow reaction zone, transitional zone and rapid reaction zone. In high temperature zone, activation energies for the reduction of SO2 and nitrogen monoxide （NO） are 30.69 and 24.06 kJ mo1-1, respectively. This study shows that microwave can effectively enhance the removal of pollutants through its heating effect and the induced catalysis.

A quantum chemistry study on reaction mechanisms of SO_2 with O_3 and H_2O_2

Reaction mechanisms of SO2 with O3 and H2O2 were investigated using quantum chemistry ab initio methods. Structures of all reactants, products, and transition states were optimized at the B3LYP/6-311G＋（3df,2p） level, and energy calculations were made at the G2M level. SO2 reactions with O3 and H2O2 occurred by O-abstraction and OH-abstraction by SO2, respectively, at length forming SO3＋O2 （3Eg） and H2SO4. For SO2＋O3 reactions the barrier height was predicted to be 9.68 kcal/mol with a rate constant of 3.61 × 10^-23 cm^3/（molecule.s） at 300 K, which is below the experimental upper limit. The rate constant predicted for this reaction accords well with the one provided by National Institute for Standards and Technology （NIST） in 250-500 K. For SO2＋H2O2 reactions the barrier height was predicted to be 62.39 kcal/mol with a rate constant of 2.48× 10^-61 cm^3/（molecule.s） at 300 K.

The reductive mechanism of nitrobenzene catalyzed by nine charcoals in sulfides solution

Due to the different sources of charcoals, there are significant differences in their properties. In order to study the catalytic effect of different charcoals to nitrobenzene (NB), we selected nine charcoal-sources to prepare nine charcoals with different properties. The experiments showed that NB could be rapidly reduced by sulfides in the presence of all charcoals. The surface area normalized reduction rate constants of NB increased with H/C and (O+N)/C ratio of charcoals increasing. The difference of catalytic effect for nine charcoals was mainly due to their different species and content of surface functional groups and original organic matter. Based on the theoretical calculation and experimental results, the reaction mechanism of NB catalyzed by charcoal in sulfides solution was analyzed. Some active surface functional groups and original organic matter of charcoals were regarded as the active sites and played an important role in catalyzing the reduction of NB by accelerating the transfer of electrons from sulfides to NB.

Mechanisms of carbon storage and the coupled carbon, nitrogen and sulfur cycles in regional seas in response to global change

1.Great challenges in scientific frontiers of marine carbon storage in the scenario of global change The marine carbon cycle is influenced by anthropogenic activities,affecting global climate change and casting a significant impact on ecosystems.However,the complex spatiotemporal process of the marine carbon cycle results in the uncertainty in the estimation of marine carbon budget。

The abnormal behavior of polymers glass transition temperature increase and its mechanism

In terms of the classical theory in textbooks, the two components with phase separation in a binary polymer blend will, depending on their compatibility, have their respective Tg get closer or remain in their original values. According to the classical theory, the Tg of plastic component shall remain unchanged or move toward the lower Tg of rubber component in a rubber/plastic blend. However, ultra-fine full-vulcanized powdered rubber (UFPR) with a diameter of ca. 100 nm can simultaneously increase the toughness and the Tg of plastics, which is abnormal and is difficult to explain by classical theory. In this feature article, the abnormal behavior and its mechanism are discussed in detail.