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锂/硫电池硫基复合电极材料的新进展 被引量:13
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作者 王静强 王存国 宋和伟 《功能材料》 EI CAS CSCD 北大核心 2018年第9期9007-9014,9019,共9页
锂/硫电池因其较高的理论能量密度被认为是最有前途的下一代高能二次电池,但是由于硫的导电性差、穿梭效应、体积膨胀效应等缺陷阻碍了其发展。介绍了硫/碳复合材料、硫/金属有机框架复合材料等载体材料与硫复合的新的制备方法及研究进... 锂/硫电池因其较高的理论能量密度被认为是最有前途的下一代高能二次电池,但是由于硫的导电性差、穿梭效应、体积膨胀效应等缺陷阻碍了其发展。介绍了硫/碳复合材料、硫/金属有机框架复合材料等载体材料与硫复合的新的制备方法及研究进展。其中硫/金属有机框架复合电极材料(S@Co-N-GC)的可逆容量达到了1 670mAh/g,非常接近于硫的理论比容量1 675mAh/g,有望在未来的3~5年中实现广泛的商品化。 展开更多
关键词 锂/硫电池 硫基复合材料 核-壳结构 金属有机物框架 锂离子电池
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高比容量锂硫电池复合正极材料 被引量:2
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作者 郭锦 张敏刚 +1 位作者 闫时建 孙钢 《储能科学与技术》 CAS 2014年第4期345-352,共8页
Li与S完全反应生成Li2S时,单质硫正极的理论比容量为1675 mA·h/g,比LiFePO4、LiCoO2等正极材料的比容量高很多。单质S价格低、无毒,是一种理想的正极材料,然而其导电性较低,循环比容量衰减较快,因此需要改善S正极材料的导电性来提... Li与S完全反应生成Li2S时,单质硫正极的理论比容量为1675 mA·h/g,比LiFePO4、LiCoO2等正极材料的比容量高很多。单质S价格低、无毒,是一种理想的正极材料,然而其导电性较低,循环比容量衰减较快,因此需要改善S正极材料的导电性来提高其电化学性能。本文综述了硫基复合正极材料的制备方法、结构与形貌、电化学性能。探讨了S与多孔碳、碳纳米管、石墨烯和聚吡咯等复合的正极材料的电化学性能,并对硫基正极材料的发展趋势进行了展望。 展开更多
关键词 锂硫电池 硫基复合材料 正极 充放电性能
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锂硫二次电池正极研究进展 被引量:23
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作者 姚真东 魏巍 +2 位作者 王久林 杨军 努丽燕娜 《物理化学学报》 SCIE CAS CSCD 北大核心 2011年第5期1005-1016,共12页
综述了锂硫电池中硫基正极材料的制备方法、结构特征以及电化学性能.简述了单质硫正极材料,重点探讨了有机硫化物、碳/硫复合材料、聚合物/硫复合材料的结构设计、材料制备、反应机理以及充放电特性,并对其中存在的问题进行了分析,还介... 综述了锂硫电池中硫基正极材料的制备方法、结构特征以及电化学性能.简述了单质硫正极材料,重点探讨了有机硫化物、碳/硫复合材料、聚合物/硫复合材料的结构设计、材料制备、反应机理以及充放电特性,并对其中存在的问题进行了分析,还介绍了硫化锂正极材料.最后对硫基正极的进一步发展,以及锂硫电池的商业化应用进行了展望. 展开更多
关键词 锂硫二次电池 正极 硫基复合材料 循环性能
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Effect of WS_2 addition on electrical sliding wear behaviors of Cu-graphite-WS_2 composites 被引量:6
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作者 钱刚 凤仪 +3 位作者 陈阳明 莫飞 王雨晴 刘文宏 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第6期1986-1994,共9页
Four kinds of Cu-based composites with different mass ratios of graphite and WS2 as lubricants were fabricated by hot-pressing method. Electrical sliding wear behaviors of the composites were investigated using a bloc... Four kinds of Cu-based composites with different mass ratios of graphite and WS2 as lubricants were fabricated by hot-pressing method. Electrical sliding wear behaviors of the composites were investigated using a block-on-ring tribometer rubbing against Cu-5%Ag alloy ring. The results demonstrated that 800 ~C was the optimum sintering temperature for Cu-graphite-WS2 dual-lubricant composites to obtain the best comprehensive properties of mechanical strength and lubrication performance. Contact voltage drops of the Cu-based composites increased with increasing the mass ratio of WS2 to graphite. The Cu-based composite with 20% graphite and 10% WS2 showed the best wear resistance due to the excellent synergetic lubricating effect of graphite and WS2. The reasonable addition of WS2 into the Cu-graphite composite can remarkably improve the wear resistance without much rise of electrical energy loss which provides a novel principle of designing suitable sliding electrical contact materials for industrial applications. 展开更多
关键词 Cu-based composites GRAPHITE WS2 synergetie lubrication wear rate contact voltage drop
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Effect of Ni-coated MoS2 on microstructure and tribological properties of(Cu−10Sn)-based composites 被引量:8
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作者 Tian-xu QIU Shi-yan PAN +2 位作者 Cang FAN Xu-fei ZHU Xiao-ping SHEN 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2020年第9期2480-2490,共11页
The(Cu−10Sn)−Ni−MoS2 composites,prepared by powder metallurgy,were studied for the effects of Ni-coated MoS2 on the microstructure,mechanical properties and lubricating properties.The mechanism of effects of Ni and Mo... The(Cu−10Sn)−Ni−MoS2 composites,prepared by powder metallurgy,were studied for the effects of Ni-coated MoS2 on the microstructure,mechanical properties and lubricating properties.The mechanism of effects of Ni and MoS2 on the properties of composites was analyzed through a comparative experiment by adding Ni and MoS2 separately.The results show that the nickel wrapping around the MoS2 particles decreases the reaction rate of MoS2 with the copper matrix,and greatly improves the bonding of the matrix.The composites with 12 wt.%Ni-coated MoS2(C12)show the optimum performance including the mechanical properties and tribological behaviors.Under oil lubrication conditions,the friction coefficient is 0.0075 with a pressure of 8 MPa and a linear velocity of 0.25 m/s.The average dry friction coefficient,sliding against 40Cr steel disc,is measured to be 0.1769 when the linear velocity and pressure are 0.25 m/s and 4 MPa,respectively. 展开更多
关键词 tribology solid-lubricating interface bonding Ni-coated MoS2 (Cu−10Sn)-based composites
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Effect of laser surface melting on surface integrity of Al-4.5Cu composites reinforced with SiC and MoS2 被引量:3
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作者 Praveen Kumar BANNARAVURI Anil Kumar BIRRU Uday Shanker DIXIT 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2020年第2期344-362,共19页
Two types of composites were prepared with Al-4.5Cu alloy as a matrix using stir casting method.One was reinforced with 10wt.%of Si C and 2wt.%of MoS2.The other was reinforced with 10wt.%of Si C and 4wt.%of MoS2.Their... Two types of composites were prepared with Al-4.5Cu alloy as a matrix using stir casting method.One was reinforced with 10wt.%of Si C and 2wt.%of MoS2.The other was reinforced with 10wt.%of Si C and 4wt.%of MoS2.Their surfaces were remelted using a CO2 laser beam with an objective to study the influence of laser surface melting(LSM).The topography,microhardness,corrosion resistance and wear resistance of the laser melted surfaces were studied.Overall surface integrity after LSM was compared with as-cast surface.LSM enhanced the microhardness and wear resistance of the surface in each case.Porosity of the laser melted surface was low and corrosion resistance was high.Thus,LSM can be conveniently applied to enhancing the surface integrity of the aluminium composites.However,there is an optimum laser specific energy,around 38 J/m^2 in this study,for obtaining the best surface integrity. 展开更多
关键词 aluminium composites silicon carbide molybdenum disulfide laser surface melting MICROHARDNESS corrosion resistance
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