A complex [Mn(NCS)2(Eim)4](where Eim=1-ethylimidazole)has been synthesized and structurally cha-racterized by X-ray diffraction single-crystal structure analysis.The compound crystallizes in the Orthorhombic space gro...A complex [Mn(NCS)2(Eim)4](where Eim=1-ethylimidazole)has been synthesized and structurally cha-racterized by X-ray diffraction single-crystal structure analysis.The compound crystallizes in the Orthorhombic space group Pbca with the cell parameters:a=1.618 9(3)nm,b=1.787 4(4)nm,c=1.999 4(4)nm,and V=5.786(2)nm3,Z=8.In the structure,each Mn atom is coordinated by four Eim ligands and a pair of monodentate isothiocyanic groups,affording a compressed octahedral MnN6 core.The NCS-anions are trans and four N atoms from the Eim ligands define the equatorial plane.The C-H…π supramolecular interactions between C-H and imidazole rings of Eim link the molecules into independent chains running along the c-axis.The thermal gravity(TG)data indicates that thermal decomposition of the title complex takes place in two steps,the residue is Fe.CCDC:646113.展开更多
A complex [Cd(NCS)2(Vim)4] (where Vim=1-vinylimidazole) was synthesized and it's crystal structure was determined by X-ray diffraction technique. The compound crystallizes in the Monoclinic space group P21/c with ...A complex [Cd(NCS)2(Vim)4] (where Vim=1-vinylimidazole) was synthesized and it's crystal structure was determined by X-ray diffraction technique. The compound crystallizes in the Monoclinic space group P21/c with the parameters: a=0.858 50(17) nm, b=0.909 90(18) nm, c=1.782 3(4) nm, β=100.14(3)°, V=1.370 5(5) nm3, Z=2. In the structure, each Cd atom is coordinated by four 1-vinylimidazole ligands and a pair of monodentate isothiocyanic groups, affording a compressed octahedral CdN6 core. The NCS-anions are trans and four N atoms from the 1-vinylimidazole ligands define the equatorial plane. From the cyclic voltammogram measurement in H2O, we know that the electrode reaction was展开更多
文摘A complex [Mn(NCS)2(Eim)4](where Eim=1-ethylimidazole)has been synthesized and structurally cha-racterized by X-ray diffraction single-crystal structure analysis.The compound crystallizes in the Orthorhombic space group Pbca with the cell parameters:a=1.618 9(3)nm,b=1.787 4(4)nm,c=1.999 4(4)nm,and V=5.786(2)nm3,Z=8.In the structure,each Mn atom is coordinated by four Eim ligands and a pair of monodentate isothiocyanic groups,affording a compressed octahedral MnN6 core.The NCS-anions are trans and four N atoms from the Eim ligands define the equatorial plane.The C-H…π supramolecular interactions between C-H and imidazole rings of Eim link the molecules into independent chains running along the c-axis.The thermal gravity(TG)data indicates that thermal decomposition of the title complex takes place in two steps,the residue is Fe.CCDC:646113.
文摘A complex [Cd(NCS)2(Vim)4] (where Vim=1-vinylimidazole) was synthesized and it's crystal structure was determined by X-ray diffraction technique. The compound crystallizes in the Monoclinic space group P21/c with the parameters: a=0.858 50(17) nm, b=0.909 90(18) nm, c=1.782 3(4) nm, β=100.14(3)°, V=1.370 5(5) nm3, Z=2. In the structure, each Cd atom is coordinated by four 1-vinylimidazole ligands and a pair of monodentate isothiocyanic groups, affording a compressed octahedral CdN6 core. The NCS-anions are trans and four N atoms from the 1-vinylimidazole ligands define the equatorial plane. From the cyclic voltammogram measurement in H2O, we know that the electrode reaction was
