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混凝土中硫酸根离子扩散系数劣化效应研究 被引量:3
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作者 马晏骏 陈党生 +1 位作者 孙忠民 丁凯伦 《水资源与水工程学报》 CSCD 2018年第1期198-202,共5页
鉴于硫酸根离子在扩散过程中会与混凝土材料的水化产物发生化学反应,在扩散方程中引入关于扩散系数的化学反应劣化效应系数,建立了考虑化学反应因素影响的混凝土硫酸根粒子扩散确定性理论模型。该模型解决了Fick第二定理在混凝土中的适... 鉴于硫酸根离子在扩散过程中会与混凝土材料的水化产物发生化学反应,在扩散方程中引入关于扩散系数的化学反应劣化效应系数,建立了考虑化学反应因素影响的混凝土硫酸根粒子扩散确定性理论模型。该模型解决了Fick第二定理在混凝土中的适应性问题,通过与实验结果进行比较,验证了确定性理论模型可以较好地预测硫酸根离子浓度均值。考虑到混凝土材料在其形成之初的微孔洞、微裂缝等初始缺陷具有随机性,采用高斯随机分布来描述初始扩散系数,研究建立了考虑化学反应因素影响的混凝土硫酸根离子扩散随机性理论模型。通过与实验值对比,验证了随机性理论模型能够较好地预测出硫酸根离子浓度的分布范围。 展开更多
关键词 混凝土 硫酸根离子扩散系数 化学反应 劣化效应系数 确定性理论模型 随机性理论模型
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Degradation of limestone calcined clay cement(LC^(3))mortars under sulfate attack
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作者 Cheng Yu Zhen Li Jiaping Liu 《Low-carbon Materials and Green Construction》 2023年第1期34-47,共14页
Limestone Calcined Clay Cement(LC^(3)) is a newly proposed low-carbon cement,which can effectively reduce energy consumption and carbon emissions of the traditional cement industry without changing the basic mechanica... Limestone Calcined Clay Cement(LC^(3)) is a newly proposed low-carbon cement,which can effectively reduce energy consumption and carbon emissions of the traditional cement industry without changing the basic mechanical properties of cement-based materials.In this study,the degradation process of mortar samples of limestone and calcined clay cementitious material under sulfate attack is studied by both macroscopic and microscopic analysis.The results show that compared with pure Portland cement,the addition of calcined clay and limestone can significantly reduce the expansion rate,loss of dynamic modulus and mass loss of mortar specimens under sulfate attack.The addition of calcined clay and limestone will refine the pore size distribution of mortar specimens,then inhibiting the diffusion of sulfate and formation of corrosive products,therefore leading to a significant improvement of the sulfate resistance. 展开更多
关键词 Limestone Calcined Clay Cement(LC^(3)) Sulfate attack Expansion Sulfate penetration profiles Corrosion product
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