研究采用硫酸铵焙烧—水浸工艺提高菱镁矿的利用效率,结合XRD和TG-DTA分析以及对比硫酸铵焙烧MgO的物相变化得到焙烧过程中矿相的转化过程。实验结果表明,在菱镁矿粒度为~74μm、硫酸铵与菱镁矿物料摩尔比为1.6:1、焙烧温度为475℃和焙...研究采用硫酸铵焙烧—水浸工艺提高菱镁矿的利用效率,结合XRD和TG-DTA分析以及对比硫酸铵焙烧MgO的物相变化得到焙烧过程中矿相的转化过程。实验结果表明,在菱镁矿粒度为~74μm、硫酸铵与菱镁矿物料摩尔比为1.6:1、焙烧温度为475℃和焙烧时间为2 h的条件下,镁的提取率达到98.7%。反应中物相转化过程可以概括如下:MgCO_(3)先转变为(NH_(4))_(2)Mg_(2)(SO_(4))_(3),再分解得到MgSO_(4)。反应遵循化学反应和扩散混合控制机理,其表观活化能为33.02 k J/mol。展开更多
Pilot experiments on Na;SO;-roasting of V-Ti magnetite(VTM) concentrate pellets were performed to activate vanadium with simulated grate-kiln machines. Combined with thermodynamic calculation, X-ray diffraction(XRD), ...Pilot experiments on Na;SO;-roasting of V-Ti magnetite(VTM) concentrate pellets were performed to activate vanadium with simulated grate-kiln machines. Combined with thermodynamic calculation, X-ray diffraction(XRD), scanning electron microscopy with energy-dispersive X-ray spectroscopy(SEM-EDS), and inductively coupled plasma-atomic emission spectrometry(ICP-AES) analyses, process parameters of pellet making were optimized, and the enhancement of vanadium oxidation and conversion was realized. The results show that, in balling stage, adding Na;SO;can promote the thermal decrepitation resistance of green pellets;in the drying stage, higher wind temperature can improve the dispersion of sodium salt in pellets;in preheating stage, using O;-rich hot gas can promote more thorough oxidation of vanadium;in roasting stage, the effect of vanadium conversion to sodium vanadate is better when the liquid amount is 15.5%-22.5%. Based on the above measures, the vanadium conversion rate achieved in the roasted pellets is 85.6%, proving the feasibility of vanadium recovery using an existing pellet production line.展开更多
基金appreciate financial supports from the National Natural Science Foundation of China(Nos.51774070,52004165)the Science and Technology Project of Yunnan Province,China(No.202101AS070029)。
文摘研究采用硫酸铵焙烧—水浸工艺提高菱镁矿的利用效率,结合XRD和TG-DTA分析以及对比硫酸铵焙烧MgO的物相变化得到焙烧过程中矿相的转化过程。实验结果表明,在菱镁矿粒度为~74μm、硫酸铵与菱镁矿物料摩尔比为1.6:1、焙烧温度为475℃和焙烧时间为2 h的条件下,镁的提取率达到98.7%。反应中物相转化过程可以概括如下:MgCO_(3)先转变为(NH_(4))_(2)Mg_(2)(SO_(4))_(3),再分解得到MgSO_(4)。反应遵循化学反应和扩散混合控制机理,其表观活化能为33.02 k J/mol。
基金financially supported by the Science and Technology Innovation Program of Hunan Province, China (No. 2021RC2003)the National Natural Science Foundation of China (No. 72088101)China Postdoctoral Science Foundation (No. 2021TQ0370)。
文摘Pilot experiments on Na;SO;-roasting of V-Ti magnetite(VTM) concentrate pellets were performed to activate vanadium with simulated grate-kiln machines. Combined with thermodynamic calculation, X-ray diffraction(XRD), scanning electron microscopy with energy-dispersive X-ray spectroscopy(SEM-EDS), and inductively coupled plasma-atomic emission spectrometry(ICP-AES) analyses, process parameters of pellet making were optimized, and the enhancement of vanadium oxidation and conversion was realized. The results show that, in balling stage, adding Na;SO;can promote the thermal decrepitation resistance of green pellets;in the drying stage, higher wind temperature can improve the dispersion of sodium salt in pellets;in preheating stage, using O;-rich hot gas can promote more thorough oxidation of vanadium;in roasting stage, the effect of vanadium conversion to sodium vanadate is better when the liquid amount is 15.5%-22.5%. Based on the above measures, the vanadium conversion rate achieved in the roasted pellets is 85.6%, proving the feasibility of vanadium recovery using an existing pellet production line.
