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有机-无机杂化的钼砷酸盐的水热合成和性质(英文) 被引量:1
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作者 李杰 田淑芳 刘云 《化学研究》 CAS 2019年第2期117-121,共5页
通过水热法合成了由As-Mo-O簇和CuI有机单元构筑而成的钼砷酸盐{[CuI(2,2′-bipy)2]3[As(OH)Mo4O14(OH)]·2H2O}2(1)(bipy=bipyridine),并用元素分析、红外光谱和X射线单晶衍射对其进行了定性.1属于单斜晶系,P2(1)/c空间群.1中的多... 通过水热法合成了由As-Mo-O簇和CuI有机单元构筑而成的钼砷酸盐{[CuI(2,2′-bipy)2]3[As(OH)Mo4O14(OH)]·2H2O}2(1)(bipy=bipyridine),并用元素分析、红外光谱和X射线单晶衍射对其进行了定性.1属于单斜晶系,P2(1)/c空间群.1中的多阴离子[As(OH)Mo4O14(OH)]3-是有四个交替的共面的和共边的{MoO6}八面体组成,在这些八面体上有一个{AsO2(OH)}单元. 展开更多
关键词 晶体结构 钼砷酸盐 硬配体 多阴离子
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Control effect of fracture on hard coal cracking in a fully mechanized longwall top coal caving face 被引量:1
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作者 WEI Jin-ping LI Zhong-hua +1 位作者 SANG Pei-miao CHEN Shang-qiang 《Journal of Coal Science & Engineering(China)》 2009年第1期38-40,共3页
Through theoretical analysis, simulation test and practice, the law of a fracture'sinfluence on hard top coal press cracking was studied. The study focused on the relationbetween fracture and coal strength, top co... Through theoretical analysis, simulation test and practice, the law of a fracture'sinfluence on hard top coal press cracking was studied. The study focused on the relationbetween fracture and coal strength, top coal caving ability and work face layout. Based onthe investigation of the fracture system, the control of press cracking was achieved bymatching working face to fracture orientation to improve top-coal caving ability and recovery. The matching principle was pointed out: The top-coal caving working face should beperpendicular to or obliquely cross the primary fracture at a large angle, and cross thesecondary fracture at a small angle. The rational match can increase the recovery ratio oftop-coal and avoid rib spalling. The application of control technology on hard top coalpress cracking was introduced at the Iongwall top-coal caving face. 展开更多
关键词 FRACTURE top-coal caving ability CONTROL
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