新型硬质合金可转位T形槽铣刀

分析了标准Ｔ形槽铣刀存在问题，介绍了新型Ｔ形槽铣刀的结构特点及其应用范围。

Microstructure and formation process of Ni-pool defect in WC-8Ni cemented carbides

The morphologies and formation process of Ni-pool defects in WC?8Ni cemented carbides were studied. The SEM images show that Ni-pool generally has two kinds of morphologies: “island” in isolation and “ring” around a new phase. In the obtained samples with “ring-like Ni-pool”, WC, Ni and Ni2W4C (η phase) phases were detected in XRD patterns. Combined with SEM, EDX and XRD results, it is found that the phase in the center of the “ring-like Ni-pool” is Ni2W4C (η phase) and the main chemical components of Ni-pool are Ni, W and C. In addition, the relationships among large size Ni (agglomerated) particles, volatile impurities, pores and carbon content vs forming process of the Ni-pool defects for WC?8Ni cemented carbides are also presented and discussed.

PERFORMANCE OF BRAZED DIAMOND CUP-TYPE WHEELS WITH DEFINED GRAIN PATTERN IN GRINDING CEMENTED CARBIDE

A new cup-type grinding wheel of the brazed monolayer diamond is developed with a defined grain pattern on the wheel surface. Grinding performance of the brazed wheel in the surface grinding of cemented carbide is studied. Experimental results show that when continuous dry grinding is employed, grits of the brazed diamond grinding wheel fail mainly in attritious wear and fracture modes and no pull-out ones are found in conventional electroplated and sintered diamond wheels. It indicates the strong retention of brazing alloy to diamond grits and the longer service life of the wheel. In addition, the ground surface has good roughness. The theoretical surface roughness agrees well with experimental results.

Effect of deposition parameters on micro-and nano-crystalline diamond films growth on WC-Co substrates by HFCVD

The characteristics of hot filament chemical vapor deposition（HFCVD） diamond films are significantly influenced by the deposition parameters, such as the substrate temperature, total pressure and carbon concentration. Orthogonal experiments were introduced to study the comprehensive effects of such three parameters on diamond films deposited on WC-Co substrates. Field emission scanning electron microscopy, atomic force microscopy and Raman spectrum were employed to analyze the morphology, growth rate and composition of as-deposited diamond films. The morphology varies from pyramidal to cluster features with temperature decreasing. It is found that the low total pressure is suitable for nano-crystalline diamond films growth. Moreover, the substrate temperature and total pressure have combined influence on the growth rate of the diamond films.

Amorphous SiO_2 interlayers for deposition of adherent diamond films onto WC-Co inserts

Amorphous Si O2（a-Si O2） films were synthesized on WC-Co substrates with H2 and tetraethoxysilane（TEOS） via pyrolysis of molecular precursor.X-ray diffraction（XRD） pattern shows that silicon-cobalt compounds form at the interface between a-Si O2 films and WC-Co substrates.Moreover,it is observed by transmission electron microscope（TEM） that the a-Si O2 films are composed of hollow mirco-spheroid a-Si O2 particles.Subsequently,the a-Si O2 films are used as intermediate films and chemical vapor deposition（CVD） diamond films are deposited on them.Indentation tests were performed to evaluate the adhesion of bi-layer（a-Si O2 ＋ diamond） films on cemented carbide substrates.And the cutting performance of bi-layer（a-Si O2 ＋ diamond） coated inserts was evaluated by machining the glass fiber reinforced plastic（GFRP）.The results show that a-Si O2 interlayers can greatly improve the adhesive strength of diamond films on cemented carbide inserts;furthermore,thickness of the a-Si O2 interlayers plays a significant role in their effectiveness on adhesion enhancement of diamond films.

Thermal expansion behavior, microhardness and electrochemical corrosion resistance properties of Au_(52)Cu_(27)Ag_(17-x)(NiZn_(0.5))_x alloys

The thermal expansion behavior, microhardness and electrochemical corrosion resistance of Au52Cu27Ag17-x（NiZn0.5）x （x=0,6 and 12） alloys were investigated by dilatometer （DIL）, microhardness tester, electrochemical workstation, X-ray diffractometer（XRD）, scanning electron microscopy （SEM）, transmission electron microscopy （TEM） and X-ray photoelectron spectroscopy （XPS）.With increasing x, the relative length expansion and DIL maximum temperature Tl m （i.e., thermal stability） of the alloys increase inthermal expansion measurements, which can be explained by the change of the atomic binding energy, mismatch entropy togetherwith phase transformation. With the increase of x, the microhardness can be improved, but the corrosion resistance decreases; inaddition, the anodic peak current densities of polarization curves decrease, which are related closely with the solid solution degreeand dissolution of Ag, Ni and Zn alloying elements in Cl^- -containing solution.

Influence of alloying elements on microstructure and microhardness of Mg-Sn-Zn-based alloys

The phase evolution in （88%-91%）Mg-8%Sn-l%Zn-X （X=A1, Mn and/or Ce） system was analyzed via CALPHAD method and simulations were used in precise selection of the chemical composition. The influence of the addition of different alloying elements such as A1, Mn and Ce on the microstructure and microhardness of Mg-8%Sn-l%Zn-based alloys was investigated. Combined addition of A1 and Mn shows features distinct from separate addition of A1 or Mn. Additions of l%AI and l%Mn to base alloy result in the formation of massive A1-Mn phase in a-Mg matrix grains. Addition of Ce element can refme the second eutectic precipitates and form intermetallic compounds with Sn. Fine rod-like Sn-Ce phase presents mainly on the grain boundaries and plays a role in inhibiting grain growth. The effects of alloying elements on Vickers microhardness and indentation size effect of base alloy were examined.

Thermodynamics and characterization of shape memory Cu-Al-Zn alloys

The thermodynamic properties and the microstructure, hardness and electrical conductivity of shape memory alloys （SMAs） belonging to ternary Cu？Al？Zn system were studied by Muggianu model and experiment, respectively. The isothermal section of phase diagram at 293 K was calculated using Thermo-Calc software. Experiments were conducted by X-ray diffraction, light optic microscopy, scanning electron microscopy with energy dispersive X-ray spectrometry, hardness and electrical conductivity measurements. The calculated values of thermodynamic properties indicate that Cu shows good miscibility with Al and Zn in all investigated alloys. The microstructural analysis of samples reveals that the structure consists of large and polygonal grains.

Microstructure and mechanical properties of Fe-doped NiAl-28Cr-6Mo eutectic alloys

Room temperature and high temperature microstructural and mechanical properties of arc melted Ni Al-28Cr-6Mo eutectic alloys doped with 0.1% Fe, 0.2% Fe and 0.5% Fe(mole fraction) were investigated. The homogenization heat treatment of the alloys was conducted at 1300℃ in Ar atmosphere. Microscopic analyses, hardness measurements, XRD measurements and compression tests were used to characterize the alloys. As-cast and homogenized alloys exhibit fine cellular eutectic structures with coarse intercellular eutectic structure. The increase in the content of Fe results in coarsening eutectic layers and the decrease in eutectic cells. All alloys have very high compressive stress and strain at room temperature. The addition of Fe has small negative impact on the strength and ductility of the alloys at room temperature. However, the addition of Fe increases the high temperature strength of the alloy. High temperature XRD patterns show that peaks shift to lower Bragg angles. This indicates that the lattice parameter of the alloys increases.

Microstructural evolution and mechanical performance of cast Mg−3Nd−0.2Zn−0.5Zr alloy with Y additions

This work investigated the effects of different Y additions(0,1.5,3.0 and 4.5 wt.%)on the microstructural evolution and mechanical performance of cast Mg−3Nd−0.2Zn−0.5Zr alloy.The results show that as the Y content increases,the key secondary phases in as-cast alloys change from the Mg_(12)Nd type to the Mg_(24)Y_(5) type.Meanwhile,the number density of Zn−Zr particles in the grains of as-quenched alloys gradually decreases.HAADF-STEM observations of peak-aged samples reveal that element Y is greatly enriched in the globularβ¢precipitates,leading to a significantly increased volume fraction and promoted precipitation kinetics ofβ¢precipitates,resulting in enhanced strength of the alloy.Tensile tests reveal that,with the addition of 4.5 wt.%Y,the yield strength of the base alloy is substantially increased by 88 and 61 MPa after being aged at 200 and 225°C under peak-aged conditions,respectively.

Fabrication and application of nano/microcrystalline composite diamond coated drawing dies using alternative carbon sources

Nano/microcrystalline composite diamond films were deposited on the holes of WC-6%Co drawing dies by a two-step procedure using alternative carbon sources, i.e., methane for the microcrystalline diamond（MCD） layer and acetone for the nanocrystalline diamond（NCD） layer. Moreover, the monolayer methane-MCD and acetone-NCD coated drawing dies were fabricated as comparisons. The adhesion and wear rates of the diamond coated drawing dies were also tested by an inner hole polishing apparatus. Compared with mono-layer diamond coated drawing die, the composite diamond coated one exhibits better comprehensive performance, including higher adhesive strength and better wear resistance than the NCD one, and smoother surface（Ra=65.3 nm） than the MCD one（Ra=95.6 nm） after polishing at the same time. Compared with the NCD coated drawing die, the working lifetime of the composite diamond coated one is increased by nearly 20 times.

Shot lining of magnesium alloy with hard powders

To improve the surface properties,lining of magnesium alloys with hard powders by shot peening was carried out in order. The hard powders were tried to bond to the workpiece surface due to the collision of many shots.In order to fix the hard powders to the surface of the workpiece,the powders were set on an uneven surface.To easily facilitate fixing of powders,lining of the workpiece with the powder sandwiched between two aluminum foil sheets was also attempted.In this experiment,a centrifugal shot peening machine with an electrical heater was employed.The workpieces were magnesium alloys AZ31B and AZ91D,and the hard powders were commercial cemented carbide,alumina,and zirconia.The joinability of hard powders near the lined surface was observed by a optical microscope.The wear resistance was also evaluated by a wear test.The hard powders were successfully bonded to the surface of workpieces by the shot lining process.The results show that the present method is effective in wear resistance of the magnesium alloys.

Effect of heat treatment conditions on microstructure and wear behaviour of Al4Cu2Ni2Mg alloy

Al4Cu2Ni2Mg alloy is an age-hardenable aluminum alloy. The effect of different solution and aging heat treatment conditions on the microstructure, hardness and wear resistance of the alloy was studied. The cast specimens were solution treated and then artificially aged. Optical microscopy and scanning electron microscopy were used to investigate the microstructures of the specimens. The hardness and wear tests were applied to understanding the effects of heat treatment. After aging for 8 h, the hardness of the alloy increases from HV 10 96.5 to 151.1. Aging treatment for a longer duration causes a drop in the hardness because of over aging. Increasing the hardness of the alloy increases the wear resistance. As a result of all tests, solution heat treatment at 540 °C for 8 h and aging at 190 °C for 8 h were chosen for optimum heat treatment conditions for this alloy.

Wear resistance,hardness,and microstructure of carbide dispersion strengthened high-entropy alloys

(CrFeCoNi)high-entropy alloy(HEA)was reinforced with various contents of WC particles from 5 wt%to 20 wt%,and prepared by powder metallurgy.The mixed powders were compacted under 700 MPa and then sintered at 1200℃in a vacuum furnace for 90 min.Density,phase composition,and microstructure of sintered samples were investigated.Hardness,compressive strength,wear resistance and coefficient of thermal expansion(CTE)were estimated.The results revealed the improvement of the density with the addition of WC.XRD results revealed the formation of new FCC chromium carbide phases.Scanning electron microscopy(SEM)results show a good distribution of the carbide phases over the alloy matrix.The CTE was decreased gradually by increasing the WC content.Compressive strength was improved by WC addition.A mathematical model was established to predict the behavior of the strength of the HEA samples.The hardness of the investigated HEAs was increased gradually with the increasing of WC content about 20.35%.Also,the wear rate of HEA without WC is 1.70×10^(−4)mm^(3)/(N·m),which is approximately 4.5 times the wear rate of 20 wt%WC HEA(3.81×10^(−5)mm^(3)/(N·m)),which means that wear resistance was significantly improved with the increase of WC content.

Microstructure and mechanical properties of extruded Mg-6.5Gd-1.3Nd-0.7Y-0.3Zn alloy

The Mg-6.5Gd-1.3Nd-0.7Y-0.3Zn alloy ingot and sheet were prepared by casting and hot extrusion techniques,and the microstructure,age hardening behavior and mechanical properties were investigated.The results show that the as-cast alloy mainly containsα-Mg solid solution and compounds of Mg5RE and Mg24RE5(RE=Gd,Y and Nd)phases.The grain size is refined after hot extrusion,and the Mg5RE and Mg24RE5 compounds are broken during the extrusion process.The extruded alloy exhibits remarkable age hardening response and excellent mechanical properties in the peak-aging state.The ultimate tensile strength,yield strength and elongation are 310 MPa,201 MPa and 5.8%at room temperature,and 173 MPa,133 MPa and 25.0%at 300℃,respectively.

Characterization of shear stresses in nickel-based superalloy Mar-M247 when orthogonal machining with coated carbide tools

Mar-M247 is a nickel-based alloy which is well known as difficult-to-machine material due to its characteristics of high strength, poor thermal diffusion and work hardening. Calculation of shear stress by an analytical force model to indicate the effect of coating material, cutting speed, feed rate on tool life and surface roughness was conducted experimentally. Cutting tests were performed using round inserts, with cutting speeds ranging from 50 to 300 rn/min, and feed rates from 0.1 to 0.4 mm/tooth, without using cooling liquids. The behavior of the TiN and TiCN layers using various cutting conditions was analyzed with orthogonal machining force model. Cutting results indicate that different coated tools, together with cutting variables, play a significant role in determining the machinability when milling Mar-M247.

High Density Plasma Nitriding of Al-Cu Alloys for Automotive Parts

Duralumin alloys have been utilized as structural components and parts for aircrafts, train-cars and so forth. Their high specific strength was attractive to those applications; however, their little corrosion resistance and low wear endurance became a fatal demerit in practical applications. In order to overcome these issues of high strength aluminum alloys, high density plasma nitriding is proposed as an effective surface treatment for duralumin. This process has a capability to control the RF- and DC-plasmas independently for nitriding. This enables us to temporally control and describe the plasma state by in-situ plasma diagnosis. This plasma diagnosis was instrumented to search for optimum processing condition to plasma nitriding the duralumin alloys of type A2011. Both type A2011 aluminum alloy plates and pipes were employed to describe the inner nitriding behavior for hardening the duralumin alloys by the present plasma nitriding.