Using a Temperature Programmed Reaction (TPR) technique, Gujiao coke loaded with alkali earth metal oxides were reacted with CO 2 The results indicated that BaO, CaO, MgO have positive catalysis on coke solution loss ...Using a Temperature Programmed Reaction (TPR) technique, Gujiao coke loaded with alkali earth metal oxides were reacted with CO 2 The results indicated that BaO, CaO, MgO have positive catalysis on coke solution loss reaction and the catalytic order is: BaO > CaO > MgO Reactions with different oxides have different kinetic parameters All kinetic parameters (initial reaction temperature, activation energy, pre exponential) but reaction order are changed with the increase of catalyst content There is a compensation effect between activation energy and the pre exponential factor [WT5H1]展开更多
文摘Using a Temperature Programmed Reaction (TPR) technique, Gujiao coke loaded with alkali earth metal oxides were reacted with CO 2 The results indicated that BaO, CaO, MgO have positive catalysis on coke solution loss reaction and the catalytic order is: BaO > CaO > MgO Reactions with different oxides have different kinetic parameters All kinetic parameters (initial reaction temperature, activation energy, pre exponential) but reaction order are changed with the increase of catalyst content There is a compensation effect between activation energy and the pre exponential factor [WT5H1]