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Changes in Soil Solution Cu and Zn Following Application of Alkaline Stab ilisedSewageSludgeand GammaIrradiation *1 被引量:1
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作者 YAN WEIDONG 1, LUO YONGMING 2 and P. CHRISTIE 2 1 Institute of Soil Science, the Chinese Academy of Sciences, P.O Box 821, Nanjing 210008 (China) 2 Agricultural and Environmental Science Department, the Queen’s University of Belfast, Ne 《Pedosphere》 SCIE CAS CSCD 1998年第2期134-142,共9页
A glasshouse pot experiment was conducted to study changes in the solubility of copper and zinc in the soil plant system following heavy application of sewage sludge and partial sterilisation of the sludge/soil mixtu... A glasshouse pot experiment was conducted to study changes in the solubility of copper and zinc in the soil plant system following heavy application of sewage sludge and partial sterilisation of the sludge/soil mixture. A slightly acid sandy loam was mixed with alkaline stabilised and composted urban sewage sludge solids (`Agri Soil', 180 t hm -2 ), and the soil/sludge mixture was γ irradiated (10 kGy). The contrasts without the application of sewage sludge and γ irradiation were also included in the experiment. Perennial ryegrass (Lolium perenne cv. Magella) was grown on irradiated and unirradiated soils for 50 days. Soil solution samples were obtained using soil suction samplers immediately before plant transplantation and every ten days thereafter. The soil solution samples were used directly for determination of Cu and Zn, together with pH, electrical conductivity (EC) and absorbance at wavelength 360 nm (A 360 ). Application of Agri Soil led to a substantial increase in dissolved Cu and a significant decrease in dissolved Zn in the soil solution and these effects were accompanied by increased soil solution pH, EC and A 360 . The alkaline sludge product (Agri Soil) in combination with γ irradiation also led to a pronounced elevation of Cu and A 360 but a marked decline in EC, indicating an increase in dissolved organic compounds and a decrease in the ionic strength of the soil solution. The dissolved Cu and Zn, EC and A 360 usually decreased while the pH increased after plant growth for 50 days. 展开更多
关键词 copper γ irradiation sewage sludge soil solution ZINC
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在线渗析-离子色谱法测定食品亚硫酸盐含量研究 被引量:17
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作者 王永根 王剑波 +1 位作者 包玲月 朱小琼 《预防医学》 2017年第1期44-48,共5页
目的建立一种适用于食品亚硫酸盐含量检测的方法。方法采用Metrosep A Supp 5-150/4.0阴离子分析柱,以含氟离子的碱性稳定液对样品进行超声提取和高速离心后,采用在线渗析-离子色谱法,以3.2 mmol/L碳酸钠-1.0 mmol/L碳酸氢钠-5%丙酮为... 目的建立一种适用于食品亚硫酸盐含量检测的方法。方法采用Metrosep A Supp 5-150/4.0阴离子分析柱,以含氟离子的碱性稳定液对样品进行超声提取和高速离心后,采用在线渗析-离子色谱法,以3.2 mmol/L碳酸钠-1.0 mmol/L碳酸氢钠-5%丙酮为淋洗液,电导检测器检测食品中亚硫酸盐含量。结果亚硫酸钠在含氟离子的碱性稳定液中稳定性增强,在室温下10 d内其浓度变化<3%;在淋洗液中加入5%丙酮后,SO32-和SO42-的分离度达到3.0。采用该方法测定浓度在0.50~50.00μg/m L范围内的亚硫酸盐(以二氧化硫计),得到亚硫酸盐浓度与峰面积的线性回归方程Y=4.299 7X-3.240 1,r=0.999 8;该方法的最小检出限为0.54 mg/kg;当加标浓度为10.0、100.0、500.0和900.0 mg/kg时,相对标准偏差分别为5.04%、1.20%、0.56%和0.98%(n=6),回收率在85.4%~104.4%。结论该方法可有效简化样品前处理过程,具有检出限低、重复性好和准确度高等优点,适用于食品中亚硫酸盐含量的测定。 展开更多
关键词 食品 亚硫酸盐 离子色谱法 碱性稳定液 在线渗析
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