期刊文献+
共找到4篇文章
< 1 >
每页显示 20 50 100
酸、碱处理对HY沸石酸性和环己酮肟液相贝克曼重排反应的影响 被引量:3
1
作者 李思洁 吴国星 +3 位作者 郭益铜 柳婧 王吉垒 郭洪臣 《分子催化》 CAS CSCD 北大核心 2021年第3期201-214,I0001,共15页
采用FT-IR、 NH3-TPD和27Al MAS NMR等催化剂表征手段和间歇反应方法,系统研究了NaOH溶液(0.2~0.4mol/L)的碱改性和NaOH溶液与硝酸溶液(0.2 mol/L)的碱-酸组合改性对一种氢型Y沸石(Si/Al=7.5)的物化性质和环己酮肟液相贝克曼重排反应性... 采用FT-IR、 NH3-TPD和27Al MAS NMR等催化剂表征手段和间歇反应方法,系统研究了NaOH溶液(0.2~0.4mol/L)的碱改性和NaOH溶液与硝酸溶液(0.2 mol/L)的碱-酸组合改性对一种氢型Y沸石(Si/Al=7.5)的物化性质和环己酮肟液相贝克曼重排反应性能的影响.结果表明,碱改性具有脱硅作用,可使Y沸石的表面Bro¨nsted酸中心和Lewis酸中心数量显著增加.酸处理具有脱铝作用,可以选择性地脱除Y沸石中的一部分非骨架铝,从而降低碱改性催化剂的Lewis酸性.用0.2 mol/L NaOH溶液和0.2 mol/L硝酸溶液通过碱-酸组合改性得到的催化剂DeSiAl-Y-0.2在环己酮肟液相重排反应中表现出较好性能.在以苯甲腈为溶剂、反应温度和时间分别为130℃和3 h的条件下,其环己酮肟转化率和己内酰胺选择性都达到了82.9%,分别比Y沸石母体提高了18%和1.5%.在DeSiAl-Y-0.2催化剂上初步开展了反应条件和溶剂效应的研究工作,从中可以看出研制用于环己酮肟液相重排反应的Y型沸石催化剂的关键在于提高其己内酰胺选择性. 展开更多
关键词 负Y沸石 碱-酸改性 环己酮肟 液相贝克曼重排反应
下载PDF
Alleviation of Soil Acidity and Aluminium Phytotoxicityin Acid Soils by Using Alkaline-Stabilized Biosolids 被引量:6
2
作者 LUOYONGMING P.CHRISTIE 《Pedosphere》 SCIE CAS CSCD 2002年第2期185-188,共4页
A pot experiment was catried out to study alleviation of soil acidity and Al toxicity by applying analkaline-stabilised sewage sludge product (biosolids) to an acid clay sandy loam (pH 5.7) and a strongly acidsandy lo... A pot experiment was catried out to study alleviation of soil acidity and Al toxicity by applying analkaline-stabilised sewage sludge product (biosolids) to an acid clay sandy loam (pH 5.7) and a strongly acidsandy loam (pH 4.5). Barley (Hondeum vulgare L. cv. Forrester) was used as a test crop and was grownin the sewage sludge-amended (33.5 t sludge DM ha-1) and unamended soils. The results showed that thealka1ine biosloids increased soil pH from 5.7 to 6.9 for the clay sandy loam and from 4.5 to 6.0 for the sandyloam. The sludge product decreased KCl-extractable Al from 0.1 to 0.0 cmol kg-1 for the former soil andfrom 4.0 to 0.1 cmol kg-1 for the latter soil. As a result, barley plants grew much better and grain yieldincreased greatly in the amended treatments compared with the unamended controls. These observationsindicate that alkaline-stabilised biosolids can be used as a liming material for remedying Al phytotoxicity instrongly acid soils by increasing soil pH and lowering Al bioavailability. 展开更多
关键词 alkaline biosolids phytotoxicity soil acidity soil remediation
下载PDF
Salt-free reactive dyeing of betaine-modified cationic cotton fabrics with enhanced dye fixation 被引量:6
3
作者 Wei Ma Mei Meng +1 位作者 Shumin Yan Shufen Zhang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2016年第1期175-179,共5页
Novel cationic cotton fabrics were prepared by an efficient and simple one-step pad–dry–bake pretreatment process with betaine as cationic reagent. Ester bonds formed between cotton fibers and betaine hydrochloride ... Novel cationic cotton fabrics were prepared by an efficient and simple one-step pad–dry–bake pretreatment process with betaine as cationic reagent. Ester bonds formed between cotton fibers and betaine hydrochloride were proved by Fourier transformed infrared attenuated total reflection(FTIR-ATR) spectra. Moreover, the properties of the cationic fabrics, including X-ray Diffraction(XRD), tensile strength and whiteness and yellowness index,were investigated in comparison with that of the untreated ones. The cationic fabrics were applied in salt-free dyeing of C.I. Reactive Red 195, C.I. Reactive Yellow 145 and C.I. Reactive Blue 19. Different dye fixation processes were applied and compared for untreated and cationic cotton. Dye fixation and color fastness properties of the dyes were tested, and the results presented that dye fixation on the cationic fabrics in the absence of salt was improved with satisfactory light fastness property and applicable wash and rub fastnesses. 展开更多
关键词 Salt-free dyeing Betaine Cationic cotton Reactive dyes
下载PDF
Effect of Furfural Residue on Control of Soil Alkalization and Amelioration of Solonetz 被引量:1
4
作者 CAIAXING SONGRONGHUA 《Pedosphere》 SCIE CAS CSCD 1998年第4期343-348,共6页
Furfural residue, an industrial waste, is a kind of strongly acidic organic materials. Its comprehensive utilization in agriculture showed a significant effect on control of soil alkalization, amelioration of solonetz... Furfural residue, an industrial waste, is a kind of strongly acidic organic materials. Its comprehensive utilization in agriculture showed a significant effect on control of soil alkalization, amelioration of solonetz and increase of crop yields. In detail it may adjust pH, depress alkalinity, reduce bulk density and compactness and increase water permeability and retention ability of the soil. Meanwhile agricultural use of furfural residue provided an effective way to avoid its pollution of the soil, Water and air. 展开更多
关键词 furfural residue soil alkalization solonetz amelioration
下载PDF
上一页 1 下一页 到第
使用帮助 返回顶部