Abstract: Two Canadian limestones with different properties were tested to determine the effect of SO2 during the carbonation of sorbent on the CO2 capture performance in Ca- looping. When the reaction gas is mixed w...Abstract: Two Canadian limestones with different properties were tested to determine the effect of SO2 during the carbonation of sorbent on the CO2 capture performance in Ca- looping. When the reaction gas is mixed with SO2, the carbonation ratio of the sorbent is always lower than that without SO2 for each cycle under the same conditions, and the sulfation ratio increases almost linearly with the increase in the cycle times. At 650 ℃, there is little difference in the carbonation ratio of the sorbent during the first four cycles for the two carbonation time, 5 and 10 rain at 0. 18% SO2. The indirect sulfation reaction that occurs simultaneously with the carbonation of CaO is responsible for the degradation of the sorbent for CO2 capture, and the carbonation duration is not the main factor that affects the ability of the sorbent. 680℃ is the best carbonation temperature among the three tested temperatures and the highest carbonation ratio can be obtained. Also, the sulfation ratio is the highest. The probable cause is the different effects of temperature on the carbonation rate and sulfation rate. A higher SO2 concentration will decrease the carbonation ratio clearly, but the decrease in the carbonation capability of the sorbent is not proportional to the increase of the SO2 concentration in flue gases.展开更多
Northern peatlands store a large amount of carbon and play a significant role in the global carbon cycle. Owing to the presence of waterlogged and anaerobic conditions, peatlands are typically a source of methane (CH4...Northern peatlands store a large amount of carbon and play a significant role in the global carbon cycle. Owing to the presence of waterlogged and anaerobic conditions, peatlands are typically a source of methane (CH4), a very potent greenhouse gas. This paper reviews the key mechanisms of peatland CH4 production, consumption and transport and the major environmental and biotic controls on peatland CH4 emissions. The advantages and disadvantages of micrometeorological and chamber methods in measuring CH4 fluxes from northern peatlands are also discussed. The magnitude of CH4 flux varies considerably among peatland types (bogs and fens) and microtopographic locations (hummocks and hollows). Some anthropogenic activities including forestry, peat harvesting and industrial emission of sulphur dioxide can cause a reduction in CH4 release from northern peatlands. Further research should be conducted to investigate the in fluence of plant growth forms on CH4 flux from northern peatlands, determine the water table threshold at which plant production in peatlands enhances CH4 release, and quantify peatland CH4 exchange at plant community level with a higher temporal resolution using automatic chambers.展开更多
1.Great challenges in scientific frontiers of marine carbon storage in the scenario of global change The marine carbon cycle is influenced by anthropogenic activities,affecting global climate change and casting a sign...1.Great challenges in scientific frontiers of marine carbon storage in the scenario of global change The marine carbon cycle is influenced by anthropogenic activities,affecting global climate change and casting a significant impact on ecosystems.However,the complex spatiotemporal process of the marine carbon cycle results in the uncertainty in the estimation of marine carbon budget。展开更多
基金The National Natural Science Foundation of China(No.51276064)the Natural Science Foundation of Beijing City(No.3132028)
文摘Abstract: Two Canadian limestones with different properties were tested to determine the effect of SO2 during the carbonation of sorbent on the CO2 capture performance in Ca- looping. When the reaction gas is mixed with SO2, the carbonation ratio of the sorbent is always lower than that without SO2 for each cycle under the same conditions, and the sulfation ratio increases almost linearly with the increase in the cycle times. At 650 ℃, there is little difference in the carbonation ratio of the sorbent during the first four cycles for the two carbonation time, 5 and 10 rain at 0. 18% SO2. The indirect sulfation reaction that occurs simultaneously with the carbonation of CaO is responsible for the degradation of the sorbent for CO2 capture, and the carbonation duration is not the main factor that affects the ability of the sorbent. 680℃ is the best carbonation temperature among the three tested temperatures and the highest carbonation ratio can be obtained. Also, the sulfation ratio is the highest. The probable cause is the different effects of temperature on the carbonation rate and sulfation rate. A higher SO2 concentration will decrease the carbonation ratio clearly, but the decrease in the carbonation capability of the sorbent is not proportional to the increase of the SO2 concentration in flue gases.
基金Project supported by the Canadian Carbon Program (Fluxnet-Canada Research Network) funded by the Canadian Foundation for Climate and Atmospheric Sciences (CFCAS)a Natural Sciences and Engineering Research Councilof Canada (NSERC) Discovery Grant to Nigel Roulet
文摘Northern peatlands store a large amount of carbon and play a significant role in the global carbon cycle. Owing to the presence of waterlogged and anaerobic conditions, peatlands are typically a source of methane (CH4), a very potent greenhouse gas. This paper reviews the key mechanisms of peatland CH4 production, consumption and transport and the major environmental and biotic controls on peatland CH4 emissions. The advantages and disadvantages of micrometeorological and chamber methods in measuring CH4 fluxes from northern peatlands are also discussed. The magnitude of CH4 flux varies considerably among peatland types (bogs and fens) and microtopographic locations (hummocks and hollows). Some anthropogenic activities including forestry, peat harvesting and industrial emission of sulphur dioxide can cause a reduction in CH4 release from northern peatlands. Further research should be conducted to investigate the in fluence of plant growth forms on CH4 flux from northern peatlands, determine the water table threshold at which plant production in peatlands enhances CH4 release, and quantify peatland CH4 exchange at plant community level with a higher temporal resolution using automatic chambers.
基金supported by State Key R&D Program (Grant No. 2016YFA0601104)the international IMBeR project
文摘1.Great challenges in scientific frontiers of marine carbon storage in the scenario of global change The marine carbon cycle is influenced by anthropogenic activities,affecting global climate change and casting a significant impact on ecosystems.However,the complex spatiotemporal process of the marine carbon cycle results in the uncertainty in the estimation of marine carbon budget。