Increasing evidence has shown that conservation tillage is an effective agricultural practice to increase carbon （C） sequestration in soils. In order to understand the mechanisms underlying the responses of soil org...Increasing evidence has shown that conservation tillage is an effective agricultural practice to increase carbon （C） sequestration in soils. In order to understand the mechanisms underlying the responses of soil organic carbon （SOC） to tillage regimes, physical fractionation techniques were employed to evaluate the effect of long-term no-tillage （NT） on soil aggregation and SOC fractions. Results showed that NT increased the concentration of total SOC by 18.1% compared with conventional tillage （CT） under a long-term maize （Zea mays L.） cropping system in Northeast China. The proportion of soil large macroaggregates （〉 2 000 μm） was higher in NT than that in CT, while small macroaggregates （250-2 000μm） showed an opposite trend. Therefore, the total proportion of macroaggregates （〉 2 000 and 250-2 000μm） was not affected by tillage management. However, C concentrations of macroaggregates on a whole soil basis were higher under NT relative to CT, indicating that both the amount of aggregation and aggregate turnover affected C stabilization. Carbon concentrations of intra-aggregate particulate organic matter associated with microaggregates （iPOM-m） and microaggregates occluded within macroaggregates （iPOM-mM） in NT were 1.6 and 1.8 times greater than those in CT, respectively. Carbon proportions of iPOM-n and iPOM-mM in the total SOC increased from 5.4% and 6.3% in CT to 7.2% and 9.7% in NT, respectively. Furthermore, the difference in the microaggregate protected C （i. e., iPOM-m and iPOM-mM） between NT and CT could explain 45.4% of the difference in the whole SOC. The above results indicate that NT stimulates C accumulation within microaggregates which then are further acted upon in the soil to form macroaggregates. The shift of SOC within microaggregates is beneficial for long-term C sequestration in soil. We also corroborate that the microaggregate protected C is useful as a pool for assessing the impact of tillage management on SOC storage.展开更多
A method for decomposition of cellulose to produce 5-hydroxymethyl-furaldehyde （5- HMF） in subcritical water-carbon dioxide binary system was proposed. A series of experiments were performed in a batch reaction vess...A method for decomposition of cellulose to produce 5-hydroxymethyl-furaldehyde （5- HMF） in subcritical water-carbon dioxide binary system was proposed. A series of experiments were performed in a batch reaction vessel. Main products of the decomposition of cellulose are 5-HMF, furfural, levulinic acid and 1, 2, 4-benzenetrioI.The optimum condition for the preparation of 5-HMF was found as 523.15 K, 5.0% carbon dioxide mole fraction, and 30 min reaction time. The addition of carbon dioxide to water conduced to the decomposition of cellulose to 5-HMF. As can be seen from the distribution of the prod-ucts, the decomposition mechanism of cellulose is similar to the hydrothermal reaction of D-glucose and D-fructose.展开更多
AIM:To assess the safety and efficacy of carbon dioxide (CO2) insufflation during endoscopic retrograde cholangiopancreatography (ERCP). METHODS:The Cochrane Library, Medical Literature Analysis and Retrieval System O...AIM:To assess the safety and efficacy of carbon dioxide (CO2) insufflation during endoscopic retrograde cholangiopancreatography (ERCP). METHODS:The Cochrane Library, Medical Literature Analysis and Retrieval System Online, Excerpta Medica Database, Science Citation Index Expanded, Chinese Biomedical Literature Database, and references in relevant publications were searched up to December 2011 to identify randomized controlled trials (RCTs) comparing CO2 insufflation with air insufflation during ERCP. The trials were included in the review irrespec-tive of sample size, publication status, or language. Study selection and data extraction were performed by two independent authors. The meta-analysis was performed using Review Manager 5.1.6. A random-effects model was used to analyze various outcomes.Sensitivity and subgroup analyses were performed if necessary. R ESULTS:Seven double-blind RCTs involving a total of 818 patients were identified that compared CO2 insufflation (n = 404) with air insufflation (n = 401) during ERCP. There were a total of 13 post-random- ization dropouts in four RCTs. Six RCTs had a high risk of bias and one had a low risk of bias. None of the RCTs reported any severe gas-related adverse events in either group. A meta-analysis of 5 RCTs (n = 459) indicated that patients in the CO2 insufflation group had less post-ERCP abdominal pain and distension for at least 1 h compared with patients in the air insuf-flation group. There were no significant differences in mild cardiopulmonary complications [risk ratio (RR) = 0.43, 95% CI:0.07-2.66, P = 0.36], cardiopulmonary (e.g., blood CO2 level) changes [standardized mean difference (SMD) = -0.97, 95% CI: -2.58-0.63, P = 0.23], cost analysis (mean difference = 3.14, 95% CI:-14.57-20.85, P = 0.73), and total procedure time (SMD = -0.05, 95% CI:-0.26-0.17, P = 0.67) between the two groups. C ONCLUSION:CO2 insufflation during ERCP appears to be safe and reduces post-ERCP abdominal pain and discomfort.展开更多
In this paper, we first overview some traditional relaying technologies, and then present a Network Coding-Aware Cooperative Relaying （NC2R） scheme to improve the performance of downlink transmission for relayaided ...In this paper, we first overview some traditional relaying technologies, and then present a Network Coding-Aware Cooperative Relaying （NC2R） scheme to improve the performance of downlink transmission for relayaided cellular networks. Moreover, systematic performance analysis and extensive simulations are performed for the proposed NC2R and traditional relaying and non-relaying schemes. The results show that NCR outperforms conventional relaying and non-relaying schemes in terms of blocking probability and spectral efficiency, especially for cell-edge users. Additionally, the location selections for relays with NCR are also discussed. These results will provide some insights for incorporating network coding into next-generation broadband cellular relay mobile systems.展开更多
During the decision-making process, especially in multi-disciplinary complex cases, assessment technique is needed to assist policy-makers in making the right decision. Many of such assessment techniques have been dev...During the decision-making process, especially in multi-disciplinary complex cases, assessment technique is needed to assist policy-makers in making the right decision. Many of such assessment techniques have been developed for policy-makers, but the inevitable subjectivity of policy-makers often becomes the main obstacle in making the right or proper policy. Interlink decision-making index （IDMI） is a newly proposed assessment method with the advantages of being simple to use and having less human interference over other methods, as it does not require a weighting process of each selection criterion. This paper implements IDMI to assist with decision-making in national or regional low-carbon development, using China as a case study. The Chinese government has annotmced its carbon emission reduction target along with other development targets by 2020. Many policy settings can be chosen in order to achieve those targets. The problem is how to determine the best setting and the means by which decision-makers can avoid subjectivity and extremes. A number of policy setting options are generated carefully by a system dynamic model under different policy scenarios. The IDMI demonstrates a perfect way to assist in selecting the ＂best＂ among all the options that can achieve the goals within the acceptable range.展开更多
Soil organic carbon(SOC)can act as a sink or source of atmospheric carbon dioxide;therefore,it is important to understand the amount and composition of SOC in terrestrial ecosystems,the spatial variation in SOC,and th...Soil organic carbon(SOC)can act as a sink or source of atmospheric carbon dioxide;therefore,it is important to understand the amount and composition of SOC in terrestrial ecosystems,the spatial variation in SOC,and the underlying mechanisms that stabilize SOC.In this study,density fractionation and acid hydrolysis were used to assess the spatial variation in SOC,the heavy fraction of organic carbon(HFOC),and the resistant organic carbon(ROC)in soils of the southern Hulun Buir region,northeastern China,and to identify the major factors that contribute to this variation.The results showed that as the contents of clay and silt particles(0–50μm)increased,both methylene blue(MB)adsorption by soil minerals and microaggregate contents increased in the 0–20 and 20–40 cm soil layers(P<0.05).Although varying with vegetation types,SOC,HFOC,and ROC contents increased significantly with the content of clay and silt particles, MB adsorption by soil minerals,and microaggregate content(P<0.05),suggesting that soil texture,the MB adsorption by soil minerals,and microaggregate abundance might be important factors influencing the spatial heterogeneity of carbon contents in soils of the southern Hulun Buir region.展开更多
Soil samples were taken from an Ermans birch （Betula ermanii）-dark coniferous forest （Picea jezoensis and Abies nephrolepis） ecotone growing on volcanic ejecta in the northern slope of Changbai Mountains of Northe...Soil samples were taken from an Ermans birch （Betula ermanii）-dark coniferous forest （Picea jezoensis and Abies nephrolepis） ecotone growing on volcanic ejecta in the northern slope of Changbai Mountains of Northeast China, to compare soil carbon （C） and nitrogen （N） transformations in the two forests. The soil type is Umbri-Gelic Cambosols in Chinese Soil Taxonomy. Soil samples were incubated aerobically at 20℃ and field capacity of 700 g kg^-1 over a period of 27 weeks. The amount of soil microbial biomass and net N mineralization were higher in the Ermans birch than the dark coniferous forest （P 〈 0.05）, whereas the cumulative C mineralization （as CO2 emission） in the dark coniferous forest exceeded that in the Ermans birch （P 〈 0.05）. Release of the cumulative dissolved organic C and dissolved organic N were greater in the Ermans birch than the dark coniferous forest （P 〈 0.05）. The results suggested that differences of forest types could result in considerable change in soil C and N transformations.展开更多
Soil organic carbon is of great importance to terrestrial ecosystems. Studies on the amount and spatial distribution of soil organic carbon stock in various types of soil can help to better understand the role of soil...Soil organic carbon is of great importance to terrestrial ecosystems. Studies on the amount and spatial distribution of soil organic carbon stock in various types of soil can help to better understand the role of soil in the global carbon cycle and provide a scientific basis for the assessment of the magnitude of carbon stored in a given area. Here we present estimates of soil organic carbon stock in soils in the upper reaches of the Yangtze River based on soil types as defined by Chinese Soil Taxonomy and recently compiled into a digital soil database. The results showed that the total soil organic carbon stock of the upper Yangtze River to a depth of 100 cm was 1.452x1013 kg. The highest soil organic carbon stock was found in felty soils （2.419x10TM kg）, followed by dark brown soils （1.269x10=kg）, and dark feltysoils （L139x10=kg）. Chernozems and irrigation silting soils showed the lowest soil organic carbon stock, mainly due to the small total area of such soils. The soil organic carbon density of these major soil types ranged from 5.6 to 26.1 kg m2- The average soil organic carbon density of the upper reaches of the Yangtze River was 16.4 kg m-2, which was higher than that of the national average. Soil organic carbon density indicated a distinct decreasing trend from west to east, which corresponds to the pattern of increasing temperature from cold to subtropical.展开更多
The paper deals with the comparative analysis of the performance of cooling and heating systems operating with NH3 （ammonia） or CO2 （carbon dioxide）, both natural refrigerants. The study is based on the exergetic ...The paper deals with the comparative analysis of the performance of cooling and heating systems operating with NH3 （ammonia） or CO2 （carbon dioxide）, both natural refrigerants. The study is based on the exergetic analysis that points out the location and the magnitude of a system malfunction. Both systems, with NH3 or CO2 operate in two stages. The exergetic analysis gives the direction of the structural optimization. The exergetic analysis has shown that the best structural schematic is not the same for the two agents. The exergetic analysis points out that the largest exergy destruction in the CO2 cycle is due to the throttling process and offers solutions to diminish it.展开更多
An electricity generation planning model of the six major Chinese power grids was developed based on the General Algebraic Modeling System to evaluate and analyze the CDM （clean development mechanism）, including con...An electricity generation planning model of the six major Chinese power grids was developed based on the General Algebraic Modeling System to evaluate and analyze the CDM （clean development mechanism）, including consideration of the environmental co-benefits of reductions in air pollutants （SO~, NO~ and particulate matter） achieved by advanced electricity generation technologies incorporating CCS （carbon capture and storage）. An objective function was developed that included revenue from sales of electric power, total system cost, the cost of CO2 transport and storage, and emissions reduction co-benefits for SOx, NO~, and particulate matter. The objective function was minimized using an optimization model. We also developed a method for evaluating and analyzing the potential for transferring advanced power generation technologies into the Chinese power system through the CDM. We found that： （1） thermal power generation is predominant in the Chinese electricity system and will remain so for a long time; （2） advanced thermal plants are being installed as a result of the CDM, which contribute to decreasing emissions of CO2 and other air pollutants; and （3） CCS projects have significant potential to reduce substantial and sustained CO2 emissions from the Chinese power and industrial sectors.展开更多
Fertilisers significantly affect crop production and crop biomass inputs to soil organic carbon(SOC). However, the long-term effects of fertilisers on C associated with aggregates are not yet fully understood. Based o...Fertilisers significantly affect crop production and crop biomass inputs to soil organic carbon(SOC). However, the long-term effects of fertilisers on C associated with aggregates are not yet fully understood. Based on soil aggregate and SOC fractionation analysis, this study investigated the long-term effects of organic manure and inorganic fertilisers on the accumulation and change in SOC and its fractions, including the C concentrations of free light fraction, intra-aggregate particulate organic matter(POM) and intra-aggregate mineral-associated organic matter(MOM). Long-term manure applications improved SOC and increased the concentrations of some C fractions. Manure also accelerated the decomposition of coarse POM(cPOM) into fine POM(fPOM) and facilitated the transformation of fPOM encrustation into intra-microaggregate POM within macroaggregates. However, the application of inorganic fertilisers was detrimental to the formation of fPOM and to the subsequent encrustation of fPOM with clay particles, thus inhibiting the formation of stable microaggregates within macroaggregates. No significant differences were observed among the inorganic fertiliser treatments in terms of C concentrations of MOM, intra-microaggregate MOM within macroaggregate(imMMOM) and intra-microaggregate MOM(imMOM). However, the long-term application of manure resulted in large increases in C concentrations of MOM(36.35%), imMMOM(456.31%) and imMOM(19.33%) compared with control treatment.展开更多
Aims There are different components of carbon(C)pools in a natural forest ecosystem:biomass,soil,litter and woody debris.We asked how these pools changed with elevation in one of China’s ecologically important forest...Aims There are different components of carbon(C)pools in a natural forest ecosystem:biomass,soil,litter and woody debris.We asked how these pools changed with elevation in one of China’s ecologically important forest ecosystem,i.e.beech(Fagus L.,Fagaceae)forests,and what were the underlying driving factors of such variation.Methods The four C pools in nine beech forests were investigated along an elevational gradient(1095–1930 m)on Mt.Fanjingshan in Guizhou Province,Southwest China.Variance partitioning was used to explore the relative effects of stand age,climate and other factors on C storage.In addition,we compared the four C pools to other beech forests in Guizhou Province and worldwide.Important Findings The total C pools of beech forest ecosystems ranged from 190.5 to 504.3 Mg C ha^(–1),mainly attributed to biomass C(accounting for 33.7–73.9%)and soil C(accounting for 23.9–65.5%).No more than 4%of ecosystem C pools were stored in woody debris(0.05–3.1%)and litter(0.2–0.7%).Ecosystem C storage increased significantly with elevation,where both the biomass and woody debris C pools increased with elevation,while those of litter and soil exhibited no such trend.For the Guizhou beech forests,climate and stand age were found to be key drivers of the elevational patterns of ecosystem and biomass C storage,while for beech forests globally,stand age was the most important predictor.Compared to beech forests worldwide,beech forests in Guizhou Province displayed a relatively higher biomass C accumulation rate,which may be explained by a much higher precipitation in this area.The present study provides basic data for understanding the C budgets of Chinese beech forests and their possible roles in regional C cycling and emphasizes the general importance of stand age and climate on C accumulation.展开更多
Ecosystem carbon allocation can indicate ecosystem carbon cycling visually through its quantification within different carbon pools and carbon exchange.Using the ecological inventory and eddy covariance measurement ap...Ecosystem carbon allocation can indicate ecosystem carbon cycling visually through its quantification within different carbon pools and carbon exchange.Using the ecological inventory and eddy covariance measurement applied to both a mature temperate mixed forest in Changbai Mountain (CBM)and a mature subtropical evergreen forest in Dinghu Mountain (DHM),we partitioned the ecosystem carbon pool and carbon exchange into different components,determined the allocation and analyzed relationships within those components.Generally, the total carbon stock of CBM was slightly higher than that of DHM due to a higher carbon stock in the arbor layer at CBM.It was interesting that the proportions of carbon stock in vegetation,soil and litter were similar for the two mature forests.The ratio of vegetation carbon pool to soil carbon stock was 1.5 at CBM and 1.3 at DHM.However, more carbon was allocated to the trunk and root from the vegetation carbon pool at CBM,while more carbon was allocated to foliage and branches at DHM.Moreover,77% of soil carbon storage was limited to the surface soil layer (0-20cm),while there was still plentiful carbon stored in the deeper soil layers at DHM.The root/shoot ratios were 0.30 and 0.25 for CBM and DHM,respectively.The rates of net ecosystem productivity (NPP)to gross ecosystem productivity (GPP)were 0.76 and 0.58,and the ratios of ecosystem respiration (Re)to GPP were 0.98and 0.87for CBM and DHM,respectively.The net ecosystem carbon exchange/productivity (NEP)was 0.24t C ha^-1 yr^-1 for CBM and 3.38t C ha^-1 yr^-1 for DHM.Due to the common seasonal and inter-annual variations of ecosystem carbon exchange resulting from the influence of environmental factors,it was necessary to use the long record dataset to evaluate the ecosystem sink capacity.展开更多
A synchronous increase in crop productivity, nutrient use efficiency, and soil carbon(C) sequestration is important from the point of view of food security and environmental protection. In recent years, integrated soi...A synchronous increase in crop productivity, nutrient use efficiency, and soil carbon(C) sequestration is important from the point of view of food security and environmental protection. In recent years, integrated soil-crop system management(ISSM), which uses crop models and advanced nutrient management to redesign cropping systems, has been successfully demonstrated to achieve both high crop productivity and high nutrient use efficiency in China, but the effects of ISSM on soil organic C(SOC) characteristics remain unknown. In this study, the effects of current farmers' practice(FP), high-yielding practice(HY), which maximizes yields without considering costs, and ISSM on the content and chemical composition of SOC were studied in a 4-year(2009–2013) field plot experiment with maize(Zea mays L.) monoculture in an Alluvic Primosol in Northeast China. The ISSM resulted in higher soil total organic C(TOC), water-soluble organic C, easily-oxidizable organic C, particulate organic C, and humic acid C compared with HY and FP in the region. The SOC contents in aggregate size fractions generally followed a similar pattern to TOC. Compared with FP,HY decreased the mean weight diameter, geometric mean diameter, percentage of > 0.25-mm water-stable aggregates, and the stability ratio of water-stable aggregates, and increased the structure-deterioration rate and index of unstable aggregates. The opposite trend was observed between ISSM and HY. Solid-state ^(13)C nuclear magnetic resonance spectra of bulk soil showed that ISSM had higher O-alkyl C and aliphatic C/aromatic C ratio, but lower aromatic C, carbonyl C, and alkyl C/O-alkyl C and hydrophobic C/hydrophilic C ratios than HY and FP. Our results suggest that ISSM improves the quantity and quality of SOC and has a positive effect on soil aggregation and aggregate stability.展开更多
Forests play an important role in acting as a carbon sink of terrestrial ecosystem.Although global forests have huge carbon carrying capacity(CCC)and carbon sequestration potential(CSP),there were few quantification r...Forests play an important role in acting as a carbon sink of terrestrial ecosystem.Although global forests have huge carbon carrying capacity(CCC)and carbon sequestration potential(CSP),there were few quantification reports on Chinese forests.We collected and compiled a forest biomass dataset of China,a total of 5841 sites,based on forest inventory and literature search results.From the dataset we extracted 338 sites with forests aged over 80 years,a threshold for defining mature forest,to establish the mature forest biomass dataset.After analyzing the spatial pattern of the carbon density of Chinese mature forests and its controlling factors,we used carbon density of mature forests as the reference level,and conservatively estimated the CCC of the forests in China by interpolation methods of Regression Kriging,Inverse Distance Weighted and Partial Thin Plate Smoothing Spline.Combining with the sixth National Forest Resources Inventory,we also estimated the forest CSP.The results revealed positive relationships between carbon density of mature forests and temperature,precipitation and stand age,and the horizontal and elevational patterns of carbon density of mature forests can be well predicted by temperature and precipitation.The total CCC and CSP of the existing forests are 19.87 and 13.86 Pg C,respectively.Subtropical forests would have more CCC and CSP than other biomes.Consequently,relying on forests to uptake carbon by decreasing disturbance on forests would be an alternative approach for mitigating greenhouse gas concentration effects besides afforestation and reforestation.展开更多
The Tibetan Plateau(TP)and Arctic permafrost constitute two large reservoirs of organic carbon,but processes which control carbon accumulation within the surface soil layer of these areas would differ due to the inter...The Tibetan Plateau(TP)and Arctic permafrost constitute two large reservoirs of organic carbon,but processes which control carbon accumulation within the surface soil layer of these areas would differ due to the interplay of climate,soil and vegetation type.Here,we synthesized currently available soil carbon data to show that mean organic carbon density in the topsoil(0-10 cm)in TP grassland(3.12±0.52 kg C m^(-2))is less than half of that in Arctic tundra(6.70±1.94 kg C m^(-2)).Such difference is primarily attributed to their difference in radiocarbon-inferred soil carbon turnover times(547 years for TP grassland versus 1609 years for Arctic tundra)rather than to their marginal difference in topsoil carbon inputs.Our findings highlight the importance of improving regional-specific soil carbon turnover and its controlling mechanisms across permafrost affected zones in ecosystem models to fully represent carbon-climate feedback.展开更多
We verified that the matrix method, a process analysis method used mainly for life cycle inventory analysis, has several advantages in the analysis of power systems, which have recently become more complex to enhance ...We verified that the matrix method, a process analysis method used mainly for life cycle inventory analysis, has several advantages in the analysis of power systems, which have recently become more complex to enhance efficiency and to reduce C02 emissions. While designing a conceptual thermodynamic model of a complex power system, the matrix method provides a definite procedure and facilitates calculations, even if there is a recttrsive loop between the upstream and downstream processes. Similarly, in the case of partial modification to the constructed model, the matrix method can potentially reduce the time and effort required to calculate the thermodynamic balances, even if the constructed model is designed by others. In this study, we obtained mass flow and energy balances of example model power systems by the matrix method from the common thermodynamic conditions including temperatures and pressures which are set on the basis of an existing industrial steam power system. While analyzing the environmental impact of complex multiproduct power systems, such as carbon emissions, the matrix method can be used to easily derive the environmental impact of each final product. We could verify the efficacy of the matrix method in accurately deriving that of an example model power system.展开更多
基金Supported by the National Basic Research Program(973Program)of China(No.2009CB118601)the Foundation of the Chinese Academy of Agricultural Sciences(No.082060302-19)+2 种基金the National Natural Science Foundation of China(No.30571094)the Program for New Century Excellent Talents in University,China(No.NCET-05-0492)the Doctoral Foundation of the Ministry of Education,China(No.B200608)
文摘Increasing evidence has shown that conservation tillage is an effective agricultural practice to increase carbon （C） sequestration in soils. In order to understand the mechanisms underlying the responses of soil organic carbon （SOC） to tillage regimes, physical fractionation techniques were employed to evaluate the effect of long-term no-tillage （NT） on soil aggregation and SOC fractions. Results showed that NT increased the concentration of total SOC by 18.1% compared with conventional tillage （CT） under a long-term maize （Zea mays L.） cropping system in Northeast China. The proportion of soil large macroaggregates （〉 2 000 μm） was higher in NT than that in CT, while small macroaggregates （250-2 000μm） showed an opposite trend. Therefore, the total proportion of macroaggregates （〉 2 000 and 250-2 000μm） was not affected by tillage management. However, C concentrations of macroaggregates on a whole soil basis were higher under NT relative to CT, indicating that both the amount of aggregation and aggregate turnover affected C stabilization. Carbon concentrations of intra-aggregate particulate organic matter associated with microaggregates （iPOM-m） and microaggregates occluded within macroaggregates （iPOM-mM） in NT were 1.6 and 1.8 times greater than those in CT, respectively. Carbon proportions of iPOM-n and iPOM-mM in the total SOC increased from 5.4% and 6.3% in CT to 7.2% and 9.7% in NT, respectively. Furthermore, the difference in the microaggregate protected C （i. e., iPOM-m and iPOM-mM） between NT and CT could explain 45.4% of the difference in the whole SOC. The above results indicate that NT stimulates C accumulation within microaggregates which then are further acted upon in the soil to form macroaggregates. The shift of SOC within microaggregates is beneficial for long-term C sequestration in soil. We also corroborate that the microaggregate protected C is useful as a pool for assessing the impact of tillage management on SOC storage.
文摘A method for decomposition of cellulose to produce 5-hydroxymethyl-furaldehyde （5- HMF） in subcritical water-carbon dioxide binary system was proposed. A series of experiments were performed in a batch reaction vessel. Main products of the decomposition of cellulose are 5-HMF, furfural, levulinic acid and 1, 2, 4-benzenetrioI.The optimum condition for the preparation of 5-HMF was found as 523.15 K, 5.0% carbon dioxide mole fraction, and 30 min reaction time. The addition of carbon dioxide to water conduced to the decomposition of cellulose to 5-HMF. As can be seen from the distribution of the prod-ucts, the decomposition mechanism of cellulose is similar to the hydrothermal reaction of D-glucose and D-fructose.
文摘AIM:To assess the safety and efficacy of carbon dioxide (CO2) insufflation during endoscopic retrograde cholangiopancreatography (ERCP). METHODS:The Cochrane Library, Medical Literature Analysis and Retrieval System Online, Excerpta Medica Database, Science Citation Index Expanded, Chinese Biomedical Literature Database, and references in relevant publications were searched up to December 2011 to identify randomized controlled trials (RCTs) comparing CO2 insufflation with air insufflation during ERCP. The trials were included in the review irrespec-tive of sample size, publication status, or language. Study selection and data extraction were performed by two independent authors. The meta-analysis was performed using Review Manager 5.1.6. A random-effects model was used to analyze various outcomes.Sensitivity and subgroup analyses were performed if necessary. R ESULTS:Seven double-blind RCTs involving a total of 818 patients were identified that compared CO2 insufflation (n = 404) with air insufflation (n = 401) during ERCP. There were a total of 13 post-random- ization dropouts in four RCTs. Six RCTs had a high risk of bias and one had a low risk of bias. None of the RCTs reported any severe gas-related adverse events in either group. A meta-analysis of 5 RCTs (n = 459) indicated that patients in the CO2 insufflation group had less post-ERCP abdominal pain and distension for at least 1 h compared with patients in the air insuf-flation group. There were no significant differences in mild cardiopulmonary complications [risk ratio (RR) = 0.43, 95% CI:0.07-2.66, P = 0.36], cardiopulmonary (e.g., blood CO2 level) changes [standardized mean difference (SMD) = -0.97, 95% CI: -2.58-0.63, P = 0.23], cost analysis (mean difference = 3.14, 95% CI:-14.57-20.85, P = 0.73), and total procedure time (SMD = -0.05, 95% CI:-0.26-0.17, P = 0.67) between the two groups. C ONCLUSION:CO2 insufflation during ERCP appears to be safe and reduces post-ERCP abdominal pain and discomfort.
基金supported by the State Key Laboratory of Rail Traffic Control and Safety,Beijing Jiaotong University under Grant No.RCS2012ZT008the National Key Basic Research Program of China(973Program)under Grant No.2012CB316100(2)+1 种基金the National Natural Science Foundation of China under Grants No.61201203,No.61171064the Fundamental Research Funds for the Central Universities under Grant No.2012JBM030
文摘In this paper, we first overview some traditional relaying technologies, and then present a Network Coding-Aware Cooperative Relaying （NC2R） scheme to improve the performance of downlink transmission for relayaided cellular networks. Moreover, systematic performance analysis and extensive simulations are performed for the proposed NC2R and traditional relaying and non-relaying schemes. The results show that NCR outperforms conventional relaying and non-relaying schemes in terms of blocking probability and spectral efficiency, especially for cell-edge users. Additionally, the location selections for relays with NCR are also discussed. These results will provide some insights for incorporating network coding into next-generation broadband cellular relay mobile systems.
基金Supported by National Natural Science Foundation of China(No.71273185)
文摘During the decision-making process, especially in multi-disciplinary complex cases, assessment technique is needed to assist policy-makers in making the right decision. Many of such assessment techniques have been developed for policy-makers, but the inevitable subjectivity of policy-makers often becomes the main obstacle in making the right or proper policy. Interlink decision-making index （IDMI） is a newly proposed assessment method with the advantages of being simple to use and having less human interference over other methods, as it does not require a weighting process of each selection criterion. This paper implements IDMI to assist with decision-making in national or regional low-carbon development, using China as a case study. The Chinese government has annotmced its carbon emission reduction target along with other development targets by 2020. Many policy settings can be chosen in order to achieve those targets. The problem is how to determine the best setting and the means by which decision-makers can avoid subjectivity and extremes. A number of policy setting options are generated carefully by a system dynamic model under different policy scenarios. The IDMI demonstrates a perfect way to assist in selecting the ＂best＂ among all the options that can achieve the goals within the acceptable range.
基金Project supported by the National Natural Science Foundation of China(Nos.40321101 and 40071036)the Major State Basic Research Development Program of China(973 Program)(No.2002CB412503)
文摘Soil organic carbon(SOC)can act as a sink or source of atmospheric carbon dioxide;therefore,it is important to understand the amount and composition of SOC in terrestrial ecosystems,the spatial variation in SOC,and the underlying mechanisms that stabilize SOC.In this study,density fractionation and acid hydrolysis were used to assess the spatial variation in SOC,the heavy fraction of organic carbon(HFOC),and the resistant organic carbon(ROC)in soils of the southern Hulun Buir region,northeastern China,and to identify the major factors that contribute to this variation.The results showed that as the contents of clay and silt particles(0–50μm)increased,both methylene blue(MB)adsorption by soil minerals and microaggregate contents increased in the 0–20 and 20–40 cm soil layers(P<0.05).Although varying with vegetation types,SOC,HFOC,and ROC contents increased significantly with the content of clay and silt particles, MB adsorption by soil minerals,and microaggregate content(P<0.05),suggesting that soil texture,the MB adsorption by soil minerals,and microaggregate abundance might be important factors influencing the spatial heterogeneity of carbon contents in soils of the southern Hulun Buir region.
基金Project supported by the National Natural Science Foundation of China(No.90411020)the National Key Basic Research Program(973 Program)of China(No.2002CB412502)
文摘Soil samples were taken from an Ermans birch （Betula ermanii）-dark coniferous forest （Picea jezoensis and Abies nephrolepis） ecotone growing on volcanic ejecta in the northern slope of Changbai Mountains of Northeast China, to compare soil carbon （C） and nitrogen （N） transformations in the two forests. The soil type is Umbri-Gelic Cambosols in Chinese Soil Taxonomy. Soil samples were incubated aerobically at 20℃ and field capacity of 700 g kg^-1 over a period of 27 weeks. The amount of soil microbial biomass and net N mineralization were higher in the Ermans birch than the dark coniferous forest （P 〈 0.05）, whereas the cumulative C mineralization （as CO2 emission） in the dark coniferous forest exceeded that in the Ermans birch （P 〈 0.05）. Release of the cumulative dissolved organic C and dissolved organic N were greater in the Ermans birch than the dark coniferous forest （P 〈 0.05）. The results suggested that differences of forest types could result in considerable change in soil C and N transformations.
基金funded by Special Program of Strategic Science and Technology of Chinese Academy of Sciences (Grant No. XDA05050506)State Key and Basic Research Development Planning (Grant No. 2012CB417101)+1 种基金Project of Natural Science Foundation of China (Grant No. 40901134)West Light Foundation of Chinese Academy of Sciences
文摘Soil organic carbon is of great importance to terrestrial ecosystems. Studies on the amount and spatial distribution of soil organic carbon stock in various types of soil can help to better understand the role of soil in the global carbon cycle and provide a scientific basis for the assessment of the magnitude of carbon stored in a given area. Here we present estimates of soil organic carbon stock in soils in the upper reaches of the Yangtze River based on soil types as defined by Chinese Soil Taxonomy and recently compiled into a digital soil database. The results showed that the total soil organic carbon stock of the upper Yangtze River to a depth of 100 cm was 1.452x1013 kg. The highest soil organic carbon stock was found in felty soils （2.419x10TM kg）, followed by dark brown soils （1.269x10=kg）, and dark feltysoils （L139x10=kg）. Chernozems and irrigation silting soils showed the lowest soil organic carbon stock, mainly due to the small total area of such soils. The soil organic carbon density of these major soil types ranged from 5.6 to 26.1 kg m2- The average soil organic carbon density of the upper reaches of the Yangtze River was 16.4 kg m-2, which was higher than that of the national average. Soil organic carbon density indicated a distinct decreasing trend from west to east, which corresponds to the pattern of increasing temperature from cold to subtropical.
文摘The paper deals with the comparative analysis of the performance of cooling and heating systems operating with NH3 （ammonia） or CO2 （carbon dioxide）, both natural refrigerants. The study is based on the exergetic analysis that points out the location and the magnitude of a system malfunction. Both systems, with NH3 or CO2 operate in two stages. The exergetic analysis gives the direction of the structural optimization. The exergetic analysis has shown that the best structural schematic is not the same for the two agents. The exergetic analysis points out that the largest exergy destruction in the CO2 cycle is due to the throttling process and offers solutions to diminish it.
文摘An electricity generation planning model of the six major Chinese power grids was developed based on the General Algebraic Modeling System to evaluate and analyze the CDM （clean development mechanism）, including consideration of the environmental co-benefits of reductions in air pollutants （SO~, NO~ and particulate matter） achieved by advanced electricity generation technologies incorporating CCS （carbon capture and storage）. An objective function was developed that included revenue from sales of electric power, total system cost, the cost of CO2 transport and storage, and emissions reduction co-benefits for SOx, NO~, and particulate matter. The objective function was minimized using an optimization model. We also developed a method for evaluating and analyzing the potential for transferring advanced power generation technologies into the Chinese power system through the CDM. We found that： （1） thermal power generation is predominant in the Chinese electricity system and will remain so for a long time; （2） advanced thermal plants are being installed as a result of the CDM, which contribute to decreasing emissions of CO2 and other air pollutants; and （3） CCS projects have significant potential to reduce substantial and sustained CO2 emissions from the Chinese power and industrial sectors.
基金Supported by the National Natural Science Foundation of China(No.31171997)the Fifth Session of Geping Green Action-123 Project of Liaoning Environmental Research and Education(No.CEPF2012-23-1-4)the Innovative Graduate Training Program of Shenyang Agricultural University of China
文摘Fertilisers significantly affect crop production and crop biomass inputs to soil organic carbon(SOC). However, the long-term effects of fertilisers on C associated with aggregates are not yet fully understood. Based on soil aggregate and SOC fractionation analysis, this study investigated the long-term effects of organic manure and inorganic fertilisers on the accumulation and change in SOC and its fractions, including the C concentrations of free light fraction, intra-aggregate particulate organic matter(POM) and intra-aggregate mineral-associated organic matter(MOM). Long-term manure applications improved SOC and increased the concentrations of some C fractions. Manure also accelerated the decomposition of coarse POM(cPOM) into fine POM(fPOM) and facilitated the transformation of fPOM encrustation into intra-microaggregate POM within macroaggregates. However, the application of inorganic fertilisers was detrimental to the formation of fPOM and to the subsequent encrustation of fPOM with clay particles, thus inhibiting the formation of stable microaggregates within macroaggregates. No significant differences were observed among the inorganic fertiliser treatments in terms of C concentrations of MOM, intra-microaggregate MOM within macroaggregate(imMMOM) and intra-microaggregate MOM(imMOM). However, the long-term application of manure resulted in large increases in C concentrations of MOM(36.35%), imMMOM(456.31%) and imMOM(19.33%) compared with control treatment.
基金supported by the National Key Research and Development Program of China(grant no.2017YFA0605101)Ministry of Science and Technology of China(grant no.2015FY210200)National Natural Science Foundation of China(grant nos.31700374,31621091).
文摘Aims There are different components of carbon(C)pools in a natural forest ecosystem:biomass,soil,litter and woody debris.We asked how these pools changed with elevation in one of China’s ecologically important forest ecosystem,i.e.beech(Fagus L.,Fagaceae)forests,and what were the underlying driving factors of such variation.Methods The four C pools in nine beech forests were investigated along an elevational gradient(1095–1930 m)on Mt.Fanjingshan in Guizhou Province,Southwest China.Variance partitioning was used to explore the relative effects of stand age,climate and other factors on C storage.In addition,we compared the four C pools to other beech forests in Guizhou Province and worldwide.Important Findings The total C pools of beech forest ecosystems ranged from 190.5 to 504.3 Mg C ha^(–1),mainly attributed to biomass C(accounting for 33.7–73.9%)and soil C(accounting for 23.9–65.5%).No more than 4%of ecosystem C pools were stored in woody debris(0.05–3.1%)and litter(0.2–0.7%).Ecosystem C storage increased significantly with elevation,where both the biomass and woody debris C pools increased with elevation,while those of litter and soil exhibited no such trend.For the Guizhou beech forests,climate and stand age were found to be key drivers of the elevational patterns of ecosystem and biomass C storage,while for beech forests globally,stand age was the most important predictor.Compared to beech forests worldwide,beech forests in Guizhou Province displayed a relatively higher biomass C accumulation rate,which may be explained by a much higher precipitation in this area.The present study provides basic data for understanding the C budgets of Chinese beech forests and their possible roles in regional C cycling and emphasizes the general importance of stand age and climate on C accumulation.
基金National Key Research and Development Program of China(2017YFC0503801,2016YFC0500202)National Natural Science Foundation of China(31570446)Science and Technology Service Network Initiative(KFJ-SW-STS-169)
文摘Ecosystem carbon allocation can indicate ecosystem carbon cycling visually through its quantification within different carbon pools and carbon exchange.Using the ecological inventory and eddy covariance measurement applied to both a mature temperate mixed forest in Changbai Mountain (CBM)and a mature subtropical evergreen forest in Dinghu Mountain (DHM),we partitioned the ecosystem carbon pool and carbon exchange into different components,determined the allocation and analyzed relationships within those components.Generally, the total carbon stock of CBM was slightly higher than that of DHM due to a higher carbon stock in the arbor layer at CBM.It was interesting that the proportions of carbon stock in vegetation,soil and litter were similar for the two mature forests.The ratio of vegetation carbon pool to soil carbon stock was 1.5 at CBM and 1.3 at DHM.However, more carbon was allocated to the trunk and root from the vegetation carbon pool at CBM,while more carbon was allocated to foliage and branches at DHM.Moreover,77% of soil carbon storage was limited to the surface soil layer (0-20cm),while there was still plentiful carbon stored in the deeper soil layers at DHM.The root/shoot ratios were 0.30 and 0.25 for CBM and DHM,respectively.The rates of net ecosystem productivity (NPP)to gross ecosystem productivity (GPP)were 0.76 and 0.58,and the ratios of ecosystem respiration (Re)to GPP were 0.98and 0.87for CBM and DHM,respectively.The net ecosystem carbon exchange/productivity (NEP)was 0.24t C ha^-1 yr^-1 for CBM and 3.38t C ha^-1 yr^-1 for DHM.Due to the common seasonal and inter-annual variations of ecosystem carbon exchange resulting from the influence of environmental factors,it was necessary to use the long record dataset to evaluate the ecosystem sink capacity.
基金supported by the National Key Technology R&D Program of China (No.2013BAD07B02)the Special Fund for Agro-scientific Research in the Public Interest of China (No.201103003)+1 种基金the Science and Technology Development Planning Project of Jilin Province, China (No.LFGC14301)the Science Research Planning Project of the Education Department of Jilin Province, China (No.2013-64)
文摘A synchronous increase in crop productivity, nutrient use efficiency, and soil carbon(C) sequestration is important from the point of view of food security and environmental protection. In recent years, integrated soil-crop system management(ISSM), which uses crop models and advanced nutrient management to redesign cropping systems, has been successfully demonstrated to achieve both high crop productivity and high nutrient use efficiency in China, but the effects of ISSM on soil organic C(SOC) characteristics remain unknown. In this study, the effects of current farmers' practice(FP), high-yielding practice(HY), which maximizes yields without considering costs, and ISSM on the content and chemical composition of SOC were studied in a 4-year(2009–2013) field plot experiment with maize(Zea mays L.) monoculture in an Alluvic Primosol in Northeast China. The ISSM resulted in higher soil total organic C(TOC), water-soluble organic C, easily-oxidizable organic C, particulate organic C, and humic acid C compared with HY and FP in the region. The SOC contents in aggregate size fractions generally followed a similar pattern to TOC. Compared with FP,HY decreased the mean weight diameter, geometric mean diameter, percentage of > 0.25-mm water-stable aggregates, and the stability ratio of water-stable aggregates, and increased the structure-deterioration rate and index of unstable aggregates. The opposite trend was observed between ISSM and HY. Solid-state ^(13)C nuclear magnetic resonance spectra of bulk soil showed that ISSM had higher O-alkyl C and aliphatic C/aromatic C ratio, but lower aromatic C, carbonyl C, and alkyl C/O-alkyl C and hydrophobic C/hydrophilic C ratios than HY and FP. Our results suggest that ISSM improves the quantity and quality of SOC and has a positive effect on soil aggregation and aggregate stability.
基金supported by the National Basic Research Program of China(2010CB833504)the CAS Strategic Priority Research Program(XDA05050702)the National Natural Science Foundation of China(31290221)
文摘Forests play an important role in acting as a carbon sink of terrestrial ecosystem.Although global forests have huge carbon carrying capacity(CCC)and carbon sequestration potential(CSP),there were few quantification reports on Chinese forests.We collected and compiled a forest biomass dataset of China,a total of 5841 sites,based on forest inventory and literature search results.From the dataset we extracted 338 sites with forests aged over 80 years,a threshold for defining mature forest,to establish the mature forest biomass dataset.After analyzing the spatial pattern of the carbon density of Chinese mature forests and its controlling factors,we used carbon density of mature forests as the reference level,and conservatively estimated the CCC of the forests in China by interpolation methods of Regression Kriging,Inverse Distance Weighted and Partial Thin Plate Smoothing Spline.Combining with the sixth National Forest Resources Inventory,we also estimated the forest CSP.The results revealed positive relationships between carbon density of mature forests and temperature,precipitation and stand age,and the horizontal and elevational patterns of carbon density of mature forests can be well predicted by temperature and precipitation.The total CCC and CSP of the existing forests are 19.87 and 13.86 Pg C,respectively.Subtropical forests would have more CCC and CSP than other biomes.Consequently,relying on forests to uptake carbon by decreasing disturbance on forests would be an alternative approach for mitigating greenhouse gas concentration effects besides afforestation and reforestation.
基金This work was supported by Preliminary Research on Three Poles Environment and Climate Change(2019YFC1509103)the National Natural Science Foundation of China(41861134036 and 41922004)+1 种基金the Second Tibetan Plateau Scientific Expedition and Research Program(2019QZKK0606)the Strategic Priority Research Program(A)of the Chinese Academy of Sciences(XDA19070303 and XDA20050101).
文摘The Tibetan Plateau(TP)and Arctic permafrost constitute two large reservoirs of organic carbon,but processes which control carbon accumulation within the surface soil layer of these areas would differ due to the interplay of climate,soil and vegetation type.Here,we synthesized currently available soil carbon data to show that mean organic carbon density in the topsoil(0-10 cm)in TP grassland(3.12±0.52 kg C m^(-2))is less than half of that in Arctic tundra(6.70±1.94 kg C m^(-2)).Such difference is primarily attributed to their difference in radiocarbon-inferred soil carbon turnover times(547 years for TP grassland versus 1609 years for Arctic tundra)rather than to their marginal difference in topsoil carbon inputs.Our findings highlight the importance of improving regional-specific soil carbon turnover and its controlling mechanisms across permafrost affected zones in ecosystem models to fully represent carbon-climate feedback.
文摘We verified that the matrix method, a process analysis method used mainly for life cycle inventory analysis, has several advantages in the analysis of power systems, which have recently become more complex to enhance efficiency and to reduce C02 emissions. While designing a conceptual thermodynamic model of a complex power system, the matrix method provides a definite procedure and facilitates calculations, even if there is a recttrsive loop between the upstream and downstream processes. Similarly, in the case of partial modification to the constructed model, the matrix method can potentially reduce the time and effort required to calculate the thermodynamic balances, even if the constructed model is designed by others. In this study, we obtained mass flow and energy balances of example model power systems by the matrix method from the common thermodynamic conditions including temperatures and pressures which are set on the basis of an existing industrial steam power system. While analyzing the environmental impact of complex multiproduct power systems, such as carbon emissions, the matrix method can be used to easily derive the environmental impact of each final product. We could verify the efficacy of the matrix method in accurately deriving that of an example model power system.
