The kinetics of carbon reduction of ZnFe2O4 in the temperature range of 550-950 °C was investigated in a microwave tank-type reactor. The mechanism of formation of ZnO and Fe3O4/FeO by the decomposition of ZnFe2O...The kinetics of carbon reduction of ZnFe2O4 in the temperature range of 550-950 °C was investigated in a microwave tank-type reactor. The mechanism of formation of ZnO and Fe3O4/FeO by the decomposition of ZnFe2O4 was detailed using the equilibrium calculations and thermodynamics analysis by HSC chemistry software 6.0. In addition, the effects of decomposition temperature, the C/ZnFe2O4 ratio, the particle size and the microwave power were assessed on the kinetics of decomposition. Zn recovery as high as 97.93%could be achieved at a decomposition temperature of 750 °C with C/ZnFe2O4 ratio of 1：3, particle size of 61-74 μm and microwave power of 1200 W. The kinetics of decomposition was tested with different kinetic models and carbon gasification control mechanism was identified to be the appropriate mechanism. The activation energy for the carbon gasification reaction was estimated to be 38.21 kJ/mol.展开更多
Phase equilibrium conditions of gas hydrate in several systems were measured by the step-heating method using the cylindrical transparent sapphire cell device.The experimental data for pure CH4 or CO2+deionized water ...Phase equilibrium conditions of gas hydrate in several systems were measured by the step-heating method using the cylindrical transparent sapphire cell device.The experimental data for pure CH4 or CO2+deionized water systems showed good agreement with those in the literatures.This kind of method was then applied to CH4/CO2+sodium dodecyl sulfate(SDS)aqueous solution,CH4/CO2+SDS aqueous solution+silica sand,and(CH4+C2H6+C3H8)gas mixture+SDS aqueous solution systems,where SDS was added to increase the hydrate formation rate without evident influence on the equilibrium conditions.The feasibility and reliability of the step-heating method,especially for porous media systems and gas mixtures systems were determined.The experimental data for CO2+silica sand data shows that the equilibrium pressure will change significantly when the particle size of silica sand is less than 96μm.The formation equilibrium pressure was also measured by the reformation of hydrate.展开更多
基金Projects (51004059,E041601) supported by the National Natural Science Foundation of ChinaProject (14051157) supported by Natural Science Foundation of Yunnan Province
文摘The kinetics of carbon reduction of ZnFe2O4 in the temperature range of 550-950 °C was investigated in a microwave tank-type reactor. The mechanism of formation of ZnO and Fe3O4/FeO by the decomposition of ZnFe2O4 was detailed using the equilibrium calculations and thermodynamics analysis by HSC chemistry software 6.0. In addition, the effects of decomposition temperature, the C/ZnFe2O4 ratio, the particle size and the microwave power were assessed on the kinetics of decomposition. Zn recovery as high as 97.93%could be achieved at a decomposition temperature of 750 °C with C/ZnFe2O4 ratio of 1：3, particle size of 61-74 μm and microwave power of 1200 W. The kinetics of decomposition was tested with different kinetic models and carbon gasification control mechanism was identified to be the appropriate mechanism. The activation energy for the carbon gasification reaction was estimated to be 38.21 kJ/mol.
基金Supported by the National Natural Science Foundation of China （20676145, U0633003）, the National Basic Research Program of China （2009CB219504） and the Program for New Century Excellent Talents in University of the State Ministry of Education.
文摘Phase equilibrium conditions of gas hydrate in several systems were measured by the step-heating method using the cylindrical transparent sapphire cell device.The experimental data for pure CH4 or CO2+deionized water systems showed good agreement with those in the literatures.This kind of method was then applied to CH4/CO2+sodium dodecyl sulfate(SDS)aqueous solution,CH4/CO2+SDS aqueous solution+silica sand,and(CH4+C2H6+C3H8)gas mixture+SDS aqueous solution systems,where SDS was added to increase the hydrate formation rate without evident influence on the equilibrium conditions.The feasibility and reliability of the step-heating method,especially for porous media systems and gas mixtures systems were determined.The experimental data for CO2+silica sand data shows that the equilibrium pressure will change significantly when the particle size of silica sand is less than 96μm.The formation equilibrium pressure was also measured by the reformation of hydrate.
