旱涝时空水污染监测失灵与低碳高值化方法学研究——以湘乡县域污染监测水土气数据相关性试验为例

基于化学生态学及化学信息学的低碳高值化方法学,坚持理论与方法相结合,以节约、环保、低碳、高产、高值、循环为价值理念与旨归,以人地关系为基础,以生态系统为中心,以整体调控为目标,以农业生态工程为手段,首先致力于破解农产品与粮食安全问题的瓶颈之一——环境污染监测;通过近两年(2009～2010年)旱涝频发、以旱为主的枯水年份的实地调查,以及典型小流域地表水流量监测与水质测定,发现县域局地水、土、气数据的相关性以及监测重点由水环境转移到大气环境的可能性与必要性。该研究推进了水、土、气数据相关性的定量研究,其阶段性成果与相关研究的结论相符合。

混凝土强度检测中如何调整混凝土的碳化深度值

在用回弹法来间接检测构件混凝土强度时,在工程实践中,如果遇到混凝土碳化深度过大时可采用人为降低碳化深度的做法来推定该检测批混凝土强度值。

县域环境污染综合整治中低碳高值农业技术研究——以韶山灌区在建生态循环农业园种养业发展为例

探索县域城乡环境污染综合整治方略,以微观、宏观与动态视角三结合的研究方法,揭示了韶山灌区湘乡湘潭等县市及其周边地区农村水质、土壤与大气污染的严重性;提出了城乡"四维污染"的控制对策——低碳高值农业及其技术创新;且以韶山灌区在建生态循环农业园种养业产前、产中与产后深加工三部分低碳高值化技术创新产业化示范为驱动力,力求推进稻、草、树、药和猪、牛、鸡、鸭、鱼的低碳生态种养业,缓解以往种养业结构失衡、"谷贱伤农"与社会-经济-生态效益"短腿"问题的解决。结果表明,低碳高值农业体系是一个基于生态学的促进物质多层分级利用、节能降耗、清洁生产的多联产技术系统。

低碳高值农业污染链阻控-产业链延展技术耦合模式研究——以韶山灌区及其主体湘乡市和湘潭县为例

为了破解我国县域治水治气、宜居宜游、清洁发展难题,采用环境经济评价综合法与比较法,剖析了近年生态农业发展处于相对低潮、驱动乏力的深层原因;并以稻糠清洁高值化利用技术项目为案例,首次提出并界定了"低碳高值农业"及其辅助概念"流体环境系统"与"城乡4维污染";通过案例分析,建立了该模式的概念体系与技术体系基础;最后论述了该模式的构建、分析与应用以及研究结论。

混凝土用钢抗碳化能力研究

通过采用电化学开路电位测试和动电位扫描的方法,测试了四种钢试样在不同pH值的模拟混凝土孔隙夜中的电位时间曲线和动电位扫描曲线,根据电位时间曲线的形态、自腐蚀电位和点蚀电位的变化得到HRB400钢、1~#钢、2~#钢、3~#钢的抗碳化临界pH值分别为10.5~11.0、10.5~11.0、11.0~11.5、8.5~9.0,结合钢的化学成分推出添加5%Cr元素可提高钢的抗碳化能力。

Effects of salinity fluctuation and dietary protein/ carbohydrate ratio on the survival and growth of Juvenile Litopenaeus vannamei

A factorial study was conducted to determine the effects of salinity （constant （SO） and fluctuating （S10）） and isoenergetic diet of different protein/carbohydrate ratios （P/C： 4.1, 1.9, 1.0 and 0.6） on the survival and growth of juvenile Litopenaeus vannamei. The experiment lasted for 35 days. The results showed that I） At S0 and S10, specific growth rate and apparent digestibility coefficient exhibited decreasing trend, while food conversion ratio exhibited increasing trend, with decreasing P/C ratio. At SO, food consumption and specific growth rate of the shrimp fed 4.1 P/C were significantly higher than those fed 1.0 and 0.6 P/C, whereas at S10, no significant differences were detected among different treatments; II） At 4.1 and 1.9 P/C, food consumption and specific growth rate were higher in the shrimp maintained at SO as compared with those at S10, while at 1.0 and 0.6 P/C, an inverse trend was observed. Among four P/C ratios, food conversion ratio of the shrimp at SO was the lowest.

Estimation of Digestible Energy Values of Plant Protein Supplement in Pig

[Objective] The aim of the study was to establish the effective and accurate formulas for estimating the digestible energy （DE） values of plant protein supplement in pig. [Method] By difference method with different amount of alternative feeds （20% -50%）, two4 x4 Latin- square-designed trials were taken on eight castrated male pigs [ Yorkshire x Landrace x Neijiang pig, initial body-weight： （46 ±2） kg ] to deter- mine the apparent digestible energy （ADE） of the eight kinds of plant protein supplement commonly used in China, that is, corn gluten meal （sol.）, soybean meal （ sol. ）, fababean, pea, rapeseed meal （ sol. ）, sesame meal （ sol. ）, rapeseed meal （ exp. ） and cotton seed meal （sol.）. [Resultl （1） Fiber was the most important factor to estimate the ADE of plant protein supplement in pigs, and ADF was the best one. （2） The most effective equations were as below： （ 1 ） OE （kJ/kg DM） = 14 741.86 - 185.01ADF＋54.01SCHO＋22.45CP （ R =0.988,RSD= 67.9,P〈0.01 ） ; （2） DE （kJ/kg DM） =22 223.26 -209.58ADF＋26.79SCHO-1.09GE （ Ff =0.989,RSD=66.9, P〈0.01 ） . [Conclusion] The accurate, practical and specific regression equations were established for DE prediction of plant protein supplement in pig.

日照港铁路Ⅰ场灯桥立柱无损检测的实际应用

运用超声回弹综合法,结合混凝土保护层厚度、碳化、电阻率、钢筋锈蚀程度等混凝土构件无损检测方法对既有构件进行检测,判断构件受损程度,为加固补强提供依据。

Influence of CO_2 pneumoperitoneum on intracellular pH and signal transduction in cancer cells

Object: The authors studied the influence of CO2 pneumoperitoneum on intracellular pH and signal transduction arising from cancer cell multiplication in laparoscopic tumor operation. Method: They set up a simulation of pneumoperitoneum under different CO2 pressure, and then measured the variation of intracellular pH (pHi) at different time and the activity of protein kinase C (PKC) and protein phosphatase 2a (PP2a) at the end of the pneumoperitoneum. After 1 week, the concentration of cancer cells in the culture medium was calculated. Result: When the pressure of CO2 pneumoperitoneum was 0, 10, 20, 30 mmHg respectively, the average pHi was 7.273, 7.075, 6.783, 6.693 at the end of the pneumoperitoneum; PKC activity was 159.4, 168.5,178.0, 181.6 nmol/(g.min) and PP2a was 4158.3, 4066.9, 3984.0, 3878.5 nmol/(g.min) respectively. After 1 week, the cancer cells concentration was 2.15×105, 2.03×105, 2.20×105, 2.18×105 L-1. Conclusion: CO2 pneumoperitoneum could promote acidosis in cancer cells, inducing the activation of protein kinase C and deactivation of protein phosphatase 2a, but it could not accelerate the mitosis rate of the cancer cells.

Critical Value of CO of Forecasting Coal Spontaneous Combustion

CO has been used widely in the production process of colliery as an index gas to predict spontaneous combustion of coal. But in some collieries there are CO gas in the upper corner of the face all the times, sometime CO gas even exceeds the regulated critical index. This phenomenon is much more obvious in the fully-mechanized longwall face and fully-mechanized longwall and top-coal caving face. Although many measures of fire-proof and fire-extinguishing have been adopted, the flowing amount of CO gas can be only decreasd, but can not be eliminated completely. Using the different kinds of coal, the experiment of coal oxidation was made at the low temperature. The experiment indicates that some kinds of coal can produce CO under the condition of normal temperature oxidation, sometime the CO consistency is very high, and the intension of CO can be decreased with oxidation time prolonging. Selecting rational critical value of CO is the kev to predicting spontaneous combustion of coal correctly and reliably. The problem of selecting retional critical value of CO was studied. Finally, the amount of CO gas released by different kinds of coal was obtained under normal temperature condition.

Accumulation of Organic Matter in Infertile Red Soils and Its Ecological Importance

Field experiments on the decomposition of organic materials and the accumulation of organic carbon ininfertile red soils were conducted at the Ecological Experimental Station of Red Soil, the Chinese Academyof Sciences, and the potential of CO2 sequestration by reclamation and improving the fertility of these soils was estimated. Results showed that in infertile red soils, the humification coefficients of organic materials were rather high, ranging from 0.28 to 0.63 with an average of 0.43, which was 41% higher than those incorresponding red soils with medium fertility. This was mainly attributed to the high clay content, highacidity and low native organic matter content of infertile red soils. Compared to those in correspondingnormal red soils, the decomposition rates of organic materials were significantly lower in infertile red soilsin the first 2 yearst thereafter no significant difference was observed between those in the two kinds of soils.Depending on the kind and amount of organic manure applied, the soil properties and the rotation systems,annual application of organic manure with a rate of 4500 to 9000 kg ha-1 increased the organic carboncontent in surface 20 cm of infertile red soils by 2.1~7.5 g kg-1 with an average of 4.7 g kg-1 within the first5 years. The organic carbon content in infertile red soils which received organic manure annually increasedlinearly in the first 10 years, thereafter it slowed down, implying that the fertility of the infertile red soilscould reach middle or high level in 1O years if the soil was managed properly It was estimated that throughexploitation of wastelands, re-establishment of fuel forests and improvement of soil fertility, soils in red soilregion of China could sequester an extra 1.50 × 1015 g of atmospheric CO2.

Experimental and Simulating Study of Supercritical CO_2 Extraction of Ginger Essential Oil

An experimental setup for separating ginger essential oil by supercritical fluid extraction is established. The effects of the extraction pressure, temperature, CO2 flow rate and particle size of raw material on the extraction rate are investigated, and the optimum process conditions of supercritical CO2 extraction are determined. A mathematical simulation model is established based on the mass conservation in differential units of extraction bed. The total mass transfer driving force and the equilibrium absorption constant are evaluated by the linear driving force theory. The results from numerical simulation agree well with the experimental data.

Variation of Bioaccumulation Ability of 2,2',4,4'-Tetrabromodiphenyl Ether by Marine Diatom Skeletonema costatum Under Different N:P Ratios

The growth, biochemical content and bioaccumulation quantity of 2,2',4,4'-tetrabromodiphenyl ether(BDE-47) in Skeletonema costatum were studied under different N:P ratios(1, 4, 16, 64 and 128). All cellular biochemical contents of S. costatum presented decreasing trend over cultivation time. At early stage of cultivation, the cellular protein, carbohydrate and lipid in S. costatum presented higher values in treatments of N:P=4 and 16. However, they were lower in these treatments at the late stage, but higher in treatments N:P=1 and 128. Similarly, BDE-47 levels per cell of S. costatum were higher in treatments of N:P=4 and 16 at early stage of cultivation, which were 3.8 and 3.7 ng(106 cells)-1, respectively. At the middle stage of cultivation, the BDE-47 level per S. costatum cell lowered; and it further reduced in the treatments of N:P=4 and 16 at the late stage with the values 0.6 and 0.5 ng(106 cells)-1, respectively. However, it rose in N:P=128, reaching up to 2.3 ng(106 cells)-1. Compared with BDE-47 per cell, BDE-47 per algal volume under different N:P ratios did not present obvious difference. The quantity BDE-47 accumulated per cell of S. costatum was positively correlated with protein, carbohydrate and lipid per cell; meanwhile, the BDE-47 per volume had a positive correlation with biochemical content per volume. The variation of bioaccumulation ability of BDE-47 in S. costatum can be explained by biochemical changes due to N:P ratios.

The economic impact of emission peaking control policies and China's sustainable development

To achieve the goals of national sustainable development, the peaking control of CO2 emissions is pivotal, as well as other pollutants. In this paper, we build a Chinese inter-regional CGE model and simulate 13 policies and their combinations. By analyzing the energy consumptions, coal consumptions, relating emissions and their impacts on GDP, we found that with the structure adjustment policy, the proportion of coal in primary fossil fuels in 2030 will decrease from 53% to 48% and CO2 emissions will decrease by 11.3%-22.8% compared to the baseline scenario. With the energy intensity reduction policy, CO2 emissions will decrease by 33.3% in 2030 and 47.8% in 2050 than baseline scenario. Other pollutants will also be controlled as synergetic effects. In this study we also find that although the earlier the peaking time the better for emission amounts control, the economic costs can not be ignored. The GDP will decrease by 2.96%-8.23% under different scenarios. Therefore, integrated policy solutions are needed for realizing the peaks package and more targeted measures are required to achieve the peaks of other pollutants earlier.

Numerical Simulation of CO_2 Concentrations in East Asia with RAMS-CMAQ

The regional air quality modeling system RAMS-CMAQ(Regional Atmospheric Modeling System and Models-3 Community Multi-scale Air Quality) was developed by incorporating a vegetation photosynthesis and respiration module(VPRM) and used to simulate temporal-spatial variations in atmospheric CO2 concentrations in East Asia,with prescribed surface CO2 fluxes(i.e.,fossil fuel emission,biomass burning,sea-air CO2 exchange,and terrestrial biosphere CO2 flux).Comparison of modeled CO2 mixing ratios with eight ground-based in-situ measurements demonstrated that the model was able to capture most observed CO2 temporal-spatial features.Simulated CO2 concentrations were generally in good agreement with observed concentrations.Results indicated that the accumulated impacts of anthropogenic emissions contributed more to increased CO2 concentrations in urban regions relative to remote locations.Moreover,RAMS-CMAQ analysis demonstrates that surface CO2 concentrations in East Asia are strongly influenced by terrestrial ecosystems.

Effect of surface roughness on femtosecond laser ablation of 4H-SiC substrates

Ablation threshold is an important concept in the study of femtosecond laser micro-and nano-machining.In this paper,the ablation experiments of three kinds of surface roughness 4H-Si C substrates irradiated by femtosecond laser were carried out.The feature thresholds were systematically measured for three surface roughness Si C substrates and found in the modification and annealing regions ranging from coincidence(R_(a)=0.5 nm)to a clear demarcation(R_(a)=5.5 nm),eventually being difficult to identify the presence of the former(R_(a)=89 nm).Under multi-pulse laser irradiation,oriented ripple structures were generated in the annealing region,where deep subwavelength ripples(about 110 nm,Λ≈0.2λ)can be generated above substrates with surface roughness higher than 5.5 nm.We investigated the effect of surface roughness on the ablation morphology,ablation threshold,and periodic structures of femtosecond laser ablation of 4H-Si C substrates,while the ablation threshold was tended to decrease and stabilize with the increase of pulse number N≥500.

普通混凝土抗压强度回弹法检测的思考

本文通过对回弹法检测普通混凝土强度相关参数的分析,讨论了回弹法检测中回弹值的检测现状及碳化深度值的影响规律。此外,对测区数少于10个时提出也按数理统计的方法进行统一计算分析,将其计算结果与文献[1]的计算方法进行比较,同时,结合工程实测数据,对不同测区数对计算结果影响规律进行了探讨。

CGE Simulation for Levying Carbon Tax in China and International Experience of Levying Carbon Tax

Levying carbon tax is conducive to reducing carbon dioxide emissions and protecting the environment.The author firstly reviewed some relevant empirical studies on carbon tax both home and abroad,and then established the CGE model and simulated levying carbon tax in China.The study found that levying carbon tax would have little impact on China's economy:in a short-term,China's GDP might decrease by 0.51%,while in a long-term it might decrease by 0.08%;however,the carbon dioxide emissions would be substantially reduced.Meanwhile,levying carbon tax has some negative impact on the output of each industry in the very economic structure;of this,the mineral extractive industries would be influenced the most.Then the author summarized experience of levying carbon tax in foreign countries.

Chemical and Biological Evaluation of Maturity of Pig Manure Compost at Different C/N Ratios

Aerobic static pile composting (mechanical turning every 3 days) of pig manure was prepared at & m3 windrow heaps. Sawdust was used as the bulking agent to provide additional carbon and to increase the porosity of the substrate. Two treatments at initial C/N ratios of 30 and 15, respectively, were designed in the study. Dissolved organic carbon (DOC), soluble NH+4-N, C/N ratios in solid and aqueous phases, E4/E6 ratios, and seed germination index (GI) were determined to evaluate the maturity of the co-composts. Seed germination index, a biological parameter, was suggested as one of the most reliable maturity indicators for organic compost. The results showed that the treatment at the initial C/N ratio of 30 reached maturity after 49 days of composting; however, the treatment at the initial C/N ratio of 15 should require composting time of longer than 63 days to obtain maturation. Chemical multi-indicator evaluation was necessary, and the GI measurement was the recommended approach for maturity evaluation in the study.

Effects of Organic Manure Applications on Methane and Nitrous Oxide Emissions in Paddy Fields

This study was carried out in paddy fields to explore how organic manure applications would affect greenhouse emissions in South China. The results showed that the seasonal emission of CH4 under the chemical fertilizer （CF） treatment was 271.47 kg/hm^2. In comparison, the seasonal emissions of CH4 under the treatment of pig manure （PM）, chicken manure （CM） and rice straw （RS） increased by 50.61,260.22 and 602.82 kg/hm^2, respectively. N2O emission under the CF treatment was 1.22 kg/hm^2, while the N20 seasonal emissions under tile PM, CM and RS treatment decreased by 23.6% （P〈0.05）, 31.7% （P〈0.05） and 30.9% （P〈0.05）, respectively. Meanwhile, the readily oxidized organic carbon （which was oxidized by 167 mmol/L potassium permanganate, ROC167） of manure, paddy soil Eh value and temperature could also affect the CH4 emissions. The average yield of the organic fertilizer treatments increased by 6.8% compared with that of the CF treatment. Among all the organic fertilizer treatments, the PM treatment offered the lowest global warming potential and greenhouse gas intensity, in which the PM was of no significant difference from NF （no fertilizing） and CF. Therefore, the pig manure is capable of coordinating the relationship between environment and yield, and it also has a low ROC167 content, so the PM is considered worthy of recommendation.