碱矿渣水泥基胶凝材料的碳化特征研究

抗碳化性能是混凝土耐久性的重要方面。以水玻璃与氢氧化钠(Na OH)为碱组分,粒化高炉矿渣为胶凝材料,研究了碱矿渣水泥的抗碳化性能,并分析了碱矿渣水泥易于发生碳化的主要原因。结果表明:与硅酸盐水泥相比,碱矿渣砂浆的碳化程度较大,碳化未引起碱矿渣水泥石干燥收缩的增加。碱矿渣水泥基胶凝材料硬化体碳化程度较大的主要原因是其水化产物不存在Ca(OH)2、硬化体孔溶液的高碱性及较大的干燥收缩。

合成超细CaCO_3的非稳态碳化反应特征和颗粒形态

在合成超微细CaCO3 的非稳态体系中 ,跟踪测定了Ca(OH) 2 悬浮液在有添加剂Na5P3 O10 存在时的碳化过程。研究表明 ,在Ca(OH) 2 悬浮液中加入 (0 .380 4～ 1.5 2 2 )× 10 -4 mol/LNa5P3 O10 就足以抑制Ca(OH) 2 碳化反应的进行。随着溶液中Na5P3 O10 浓度的增加 ,碳化反应速度减小。Ca(OH) 2 的碳化过程可分为两个阶段 ,即反应初期的恒速反应阶段和反应末期的变速反应阶段。

Analysis of the carbon dioxide mole fraction variation and its transmission characteristics in Taiyuan

Based on the concentrations of CO2,PM2.5 and PM1.0,and conventional meteorological observation data from 2016 to 2018 at Taiyuan station,which belongs to the Shanxi greenhouse gas observation network,the CO2 concentration monthly and daily distribution characteristics,the weekend effect,and the variation characteristics on haze days and non-haze days,are analyzed.By using the Hybrid Single-Particle Lagrangian Integrated Trajectorymodel(backward trajectory model)and surface wind data,the transmission characteristics of atmospheric CO2 in Taiyuan are studied in various seasons.The results show that,in Taiyuan,the CO2 mole fraction in autumn and winter is higher than that in spring and summer,and on haze days is higher than that on non-haze days.The diurnal variation characteristic of CO2mole fraction in each season is‘single peak and single valley’with the peak value around 0700(hereafter refers to Beijing Time)and the valley value around 1600.The CO2 mole fraction on workdays is slightly higher than that on non-workdays and obviously different around 0800 of the early peak.Horizontal diffusion can reduce the CO2 mole fraction,while breezy weather is not beneficial to CO2 diffusion.The wind direction and speed in the upper levels are different from those near the surface,and the close air masses in the southwest–west–northwest sector raise the CO2 concentration in Taiyuan obviously.This indicates that the CO2 in Taiyuan is mainly contributed by local sources.

Preparation of Glutaraldehyde Cross-Linked Chitosan Beads Under Microwave Irradiation and Properties of Urease Immobilized onto the Beads

The glutaraldehyde cross-linked chitosan beads were prepared under microwave irradiation and urease was immobilized onto the beads. The activity and the yield of enzyme activity of the immobilized urease were 10.83 U/g carrier and 47.700, respectively. The optimum conditions of immobilization were 100 of glutaraldehyde volume fraction, 10 mg/g of urease/beads weight ratio, 24 h of the processing time and pH 6.5 of the reaction medium for immobilization. The properties of the immobilized urease were investigated and compared with those of the free enzyme. The optimum pH values were 6.5 and 7.0 for the immobilized and free urease, respectively. The optimum temperature was 60 ℃ for the free urease, while it shifted to 65 ℃ for the immobilized enzyme. The Michaelis constant Km was 9.1 mmol/L for the immobilized and 12.5 mmol/L for the free urease. The immobilized urease retained 4000 of its initial enzyme activity even after 10 repeated uses. The immobilized urease stored at 4 ℃ retained 4600 of its initial activity even after 35 d.

Relationship of hydrocarbon and source-rock in Nos.3-5 tectonic belts of the Lenghu area,northern Qaidam Basin

Based on analyses of the components of crude oil hydrocarbons and carbon isotopes,the content of normal alkane decreased from 49.00% to 20.10% when moving from the No.3 to No.5 tectonic belt of the Lenghu area of the Qaidam Basin,while cycloalkanes increased from 30.00% to 52.20% and aromatic and branch chain alkanes increased gradually as well. The maturity of sterane in crude oil is higher than that of its source-rock,which shows that the hydrocarbons were generated from a deep source-rock of high maturity around the tectonic belts of the Lenghu area. The analysis of the characteristics of carbon isotopes also shows that these isotopes of hydrocarbon compounds in the No.4 and No.5 tectonic belt are apparently heavier than those in the No.3 belt. The results of our research show that the hydrocarbons in the No.3 tectonic belt are mainly from a relatively rich sapropelic substance,while the hydrocarbons in the No.4 and No.5 tectonic belt originated mainly from organic matter of a relatively rich humic type substance.

Petroleum systems in the Damintun Depression, Liaohe Oilfield

There are two different types of oils—high-wax oil and normal oil—found in the Damintun Depression of Liaohe Oilfield after several years of exploration and development, but their distributions and origins had confused the explorers in the oilfield. The introduction of petroleum-system concept shifts the view of geoscientists from geology and geophysics to oil, gas and their related source rocks. After detailed study, two petroleum systems have been identified in the Damintun Depression: (1) the ES42-Ar buried hill petroleum system (called the high-wax oil petroleum system) and (2) the ES41+ES34-ES4 and ES3 petroleum system (called the normal oil petroleum system). Based on the detailed analysis of the basic components, and all the geological processes required to create these elements of the two petroleum systems, it is put forward that targets for future exploration should include the area near Dongshenpu-Xinglongpu and the area near the Anfutun Sag. This provides scientific basis and has theoretical and practical meaning for the exploration and development.

Permeability variation characteristics of coal after injecting carbon dioxide into a coal seam

A theoretical basis for the optimization of carbon dioxide injection parameters and the development of the drainage system can be provided by identifying the permeability change characteristic of coal and rock after injection of carbon dioxide into the coal seam. Sihe, Yuwu, and Changcun mines were used as research sites. Scanning electron microscopy and permeability instruments were used to measure coal properties such as permeability and surface structure of the coal samples at different pH values of carbon dioxide solution and over different timescales. The results show that the reaction between minerals in coal and carbonate solution exhibit positive and negative aspects of permeability-the dissolution reaction between carbonate minerals in coal and acid solution improves the conductivity of coal whilst, on the other hand, the clay minerals in the coal （mainly including montmorillonite, illite and kaolinite） exhibit expansion as a result of ion exchange with the H~ in acid solution, which has a negative effect on the per- meability of the coal. The permeability of coal samples increased at first and then decreased with immer- sion time, and when the soaking time is 2-3 months the permeability of the coal reached a maximum. In general, for coals with permeabilities less than 0.2 mD or greater than 2 roD, the effect on the permeabil- ity is low： when the permeability of the coal is in the range 0.2-2 mD, the effect on the permeability is highest. Research into permeability change characteristics can provide a theoretical basis for carbon diox- ide injection under different reservoir permeability conditions and subsequent drainage.

Variation Trend and Characteristics of Anthropogenic CO Column Content in the Atmosphere over Beijing and Moscow

The anthropogenic CO column content in the atmosphere is derived from measurements with infrared grating spectrometers in Beijing,China,and Moscow,Russia,during 1992–2012.Some specific variation characteristics and long-term variation trends of the CO column content in the atmosphere in these regions are discussed.An evident variation trend of anthropogenic CO in the atmosphere for the Beijing region is not observed during 1992–2012,while for the Moscow region,it decreases yearly by about 1.4% for the same period.High CO concentrations appear quite frequently in Beijing,but much less frequently in Moscow,except during the natural fire events in summer 2010.From back trajectory analysis,the high CO concentration observed in Beijing can be attributed to the intensive CO emission sources in its surrounding areas.

Dissolved Organic Carbon Dynamics and Controls of Planted Slash Pine Forest Soil in Subtropical Region in Southern China

Soil dissolved organic carbon （DOC） is an active fraction of the soil organic carbon （SOC） pool and links terrestrial and aquatic systems. The degradation of DOC can affect carbon cycling, nutrient dynamics and energy supply to microorganism, and consequently change biogeochemical processes. This study investigated the vertical and seasonal variability of soil DOC concentrations and its controls in a 23-year-old planted slash pine （Pinus elliottii） forest at Qianyanzhou Forest Experimental Station （QFES） in Southern China. Soil solutions were collected at bimonthly intervals at depths of 10, 20 and 30 cm by a mechanical-vacuum extractor from November 2007 to March 2009, and at monthly intervals at depths of 10, 30 and 50cm from April 2009 to October 2010. The DOC concentrations were determined with a total organic carbon （TOC） analyzer. Mean （±standard deviation） DOC concentrations at depths of 10cm, 20cm, 30cm and 50cm were 12.4±4.4, 10.6±6.3, 8.7±2.6, and 8.0±5.9 mg L^-1, respectively. Both seasonal and spring means of DOC concentration showed a decreasing trend with increasing depth, while there was no clear trend for the summer, autumn, or winter seasons. DOC concentrations during spring, summer, autumn and winter ranged from 4.8 to 21.5, 4.9 to 26.2, 5.4 to 17.1, 4.9 to 14.6 mg L-1, respectively, their mean DOC concentrations were 10.2, 10.5, 10.8 and 8.3 mg L 1, respectively. No consistent pattern of seasonal variability of DOC concentrations at different depths was observed. No obvious relationship between organic carbon content of forest litter and DOC concentration was found. There was a positive linear relationship between SOC and DOC concentration （R2=0.19, p〈0.01）, which showed that SOC was one of the main controls of DOC. A positive exponential relationship existed between soil temperature at 5 cm and DOC concentrations at 10 cm depth in slash pine, masson pine （Pinus massoniana） and Chinese fir （Cunninghamia lanceolata） planted forests （R2=0.12, p〈0.01）. DOC concentrations showed a negative linear relationship with soil moisture at all depths in slash pine forest （R2=0.15, p〈0.001）, and DOC concentrations at depth of 10 cm demonstrated a negative exponential relationship with soil moisture at 5 cm depth in three planted forests （R2=0.13,/）〈0.001）. Precipitation in sampling months and mean seasonal DOC concentration were not correlated. However, a more detailed analysis of precipitation events at different times before sampling and seasonal DOC concentration showed that the timing of precipitation events prior to sampling had different effects on seasonal DOC concentrations at different depths. Our study highlights the importance of DOC dynamics for the carbon cycle in planted slash pine forest and it provides evidence for evaluating the effects of ecological restoration in subtropical red soil region.

The Characteristic Differences between Ecological Culture and Low-carbon Tourism Cognition under the Vision of Carbon Neutrality

Ecological culture has a low-carbon attribute,which coincides with the concepts of energy conservation and emission reduction in low-carbon tourism.Analyzing the differences in the public perception of the two is of great significance for achieving the carbon neutral goal of tourism.Firstly,the views of nature,equality and ecology in ecological culture,as well as the cognition and participation willingness for low-carbon tourism were identified by using the principal component analysis method.Secondly,all samples were divided into four types of ecological culture cognition:sufficient,relatively sufficient,general and poorer,by the K-means clustering method.Thirdly,significant differences in the low-carbon tourism cognition among different types were revealed by using the ANOVA method.Finally,the influences of the main demographic characteristics on the low-carbon tourism cognition were analyzed.This analysis showed that gender,age,education level and income level had significant differences in some aspects of low-carbon tourism cognition and participation willingness,especially education level.On this basis,several corresponding strategies were put forward for managing the cognitive differences of the different types,which could contribute to the realization of the carbon neutral vision of tourism.

Characteristics of carbonate cementation in clastic rocks from the Chang 6 sandbody of Yanchang Formation, southern Ordos Basin

Densification of reservoir is an important factor that restricts oil and gas exploration from low porosity and extra-low permeability reservoirs. Carbonate cementation was heavily developed in Chang 6 sandbody, a facies of underwater distributary channel in delta front, of Upper Triassic Yanchang Formation in Fuxian area, southern Ordos Basin, and the cementation is one of the major factors that affect quality of reservoir. Based on the macro-microcosmic petrology and geochemistry features, the genesis of densification of carbonate-cemented reservoir was systematically discussed. The carbonate cementation can be classified into endogenous and exogenous, and the essential differences between them are that they were formed in different fluids and in different diagenesis periods. With the aid of identification of thin sections, analyses on electron probe, trace and rare-earth elements, carbon and oxygen isotope, we propose that the endogenous fluid for cementation came from the rock itself during early diagenetic stage. The minerals related to endogenous fluid had good shapes. The reservoir property was enhanced with porosity increasing by 3%-8% because of later dissolution by endogenous fluid. The exogenous fluid might be water combining with CO 2 , likely released from organic matter-rich mudstone. Calcite cement, in form of substrate cementation, was precipitated from the fluid and filled in the remaining pores of sandstones in late diagenetic stage as variations of physical and chemical conditions. The exogenous cement reduced rock porosity, damaged reservoir property, affected some oil enrichment, and seriously caused Chang 6 reservoir densification. Some of the dense layers that formed on top of sandbody could have served as diagenetic traps, and thus the exogenous cementation area could be favorable for oil exploration.