Absorption rate of CO2 into aqueous solution of N-methyldiethanolamine (MDEA) blended with diethanolamine (DEA) and piperazine (PZ) was studied and a kinetic model was established. It is shown that homogeneous activat...Absorption rate of CO2 into aqueous solution of N-methyldiethanolamine (MDEA) blended with diethanolamine (DEA) and piperazine (PZ) was studied and a kinetic model was established. It is shown that homogeneous activation mechanism could explain this absorption process. The absorption rate coefficients of carbon dioxide into MDEA aqueous solution blended with DEA, PZ or DEA+PZ were compared with each other. The results demonstrated that the different activation effect of DEA, PZ and DEA+PZ on the carbon dioxide absorption comes from the difference in CO2 combination rate, transport of PZ and DEA to MDEA and the regeneration rate of PZ and DEA.展开更多
The effects of the molding pressure of a KO2 oxygen plate and the initial concentration of CO2 on the oxygen generation rate, the oxygen generation efficiency, and the carbon dioxide absorption rate were studied using...The effects of the molding pressure of a KO2 oxygen plate and the initial concentration of CO2 on the oxygen generation rate, the oxygen generation efficiency, and the carbon dioxide absorption rate were studied using a YES-300 hydraulic press to alter the pressure when forming the oxygen plate used in a coal mine refuge chamber. In addition, changes in the initial concentration of CO2 used in the closed- box model were made by adjusting the CO2 supply system, and a CD-7 multi-function parameter instrument was employed to monitor and record the changes of O2 and CO2 concentration in the closed-box model. Results indicate that the oxygen generation rate of KO2 oxygen plates, the oxygen generation efficiency, and the carbon dioxide absorption rate decrease when there is an increase in the pressure used to mold the oxygen plates, but those values increase when the initial CO2 concentration increases. When the initial concentration of CO2 in the dosed-box model is 3.5% and the forming pressure is 10 kN, the average oxygen generation rate of 15 g KO2 oxygen plate is 11.88 ×10^-3 L/min, the oxygen generation efficiency is 80.3%, and the average CO2 absorption rate is 11.0 × 10^-3 L/min. Compared with the condition where the initial CO2 concentration is 1.5%, the results show that average oxygen genera- tion rate of oxygen plates increases by 88,9%, the oxygen generation efficiency increases by 88.9%, and the CO2 absorption rate increases by 100%.展开更多
The flotation of pure and natural carbonaceous iron ore samples in the oleate flotation system was investigated.Starch can depress hematite effectively in a wide pH range,but cannot depress siderite efficiently in neu...The flotation of pure and natural carbonaceous iron ore samples in the oleate flotation system was investigated.Starch can depress hematite effectively in a wide pH range,but cannot depress siderite efficiently in neutral conditions.The flotation recovery of pure hematite,siderite,and quartz in the oleate-starch-CaCl2 system is significantly different when the slurry pH varies from 4 to 12.A novel two-step flotation process was developed for the separation of iron concentrate from Donganshan carbonaceous iron ore through which the siderite concentrate is first recovered and the high quality hematite concentrates with relative high iron recovery can be obtained in the second step flotation.The siderite concentrate may be utilized directly or undergo further concentration steps to increase iron grade.展开更多
Oxy fuel combustion and conventional cycle(currently working cycle) in Kazeroon plant are modeled using commercial thermodynamic modeling software. Economic evaluation of the two models regarding the resources of tran...Oxy fuel combustion and conventional cycle(currently working cycle) in Kazeroon plant are modeled using commercial thermodynamic modeling software. Economic evaluation of the two models regarding the resources of transport and injection of carbon dioxide into oil fields at Gachsaran for enhanced oil recovery in the various oil price indices is conducted and indices net present value(NPV) and internal rate of return on investment(IRR) are calculated. The results of the two models reveal that gross efficiency of the oxy fuel cycle is more than reference cycle(62% compared to 49.03%), but the net efficiency is less(41.85% compared to 47.92%) because of the high-energy consumption of the components, particularly air separation unit(ASU) in the oxy fuel cycle. In this model, pure carbon dioxide with pressure of 20×105 Pa and purity of 96.84% was captured. NOX emissions also decrease by 4289.7 tons per year due to separation of nitrogen in ASU. In this model, none of the components of oxy fuel cycle is a major engineering challenge. With increasing oil price, economic justification of oxy fuel combustion model increases. With the price of oil at $ 80 per barrel in mind and $ 31 per ton fines for emissions of carbon dioxide in the atmosphere, IRR is the same for both models.展开更多
Enhanced oil recovery (EOR) via carbon dioxide (CO2) flooding has received a considerable amount of attention as an economically feasible method for carbon sequestration, with many recent studies focus- ing on dev...Enhanced oil recovery (EOR) via carbon dioxide (CO2) flooding has received a considerable amount of attention as an economically feasible method for carbon sequestration, with many recent studies focus- ing on developing enhanced CO2 foaming additives, However, the potential long-term environmental effects of these additives in the event of leakage are poorly understood and, given the amount of additives injected in a typical CO2 EOR operation, could he far-reaching, This paper presents a summary of recent developments in surfactant and surfactant/nanoparticle-hased CO2 foaming systems, with an emphasis on the possible environmental impacts of CO2 foam leakage, Most of the surfactants studied are unlikely to degrade under reservoir conditions, and their release can cause major negative impacts on wildlife, With recent advances in the use of additives (e,g,, nonionic surfactants, nanoparticles, and other chemicals) the use of harsh anionic surfactants may no longer he warranted, This paper discusses recent advances in producing foaming systems, and highlights possible strategies to develop environmentally friendly CO2 EOR methods,展开更多
CO2 flooding is a process whereby carbon dioxide is injected into an oil reservoir in order to increase output when extracting oil. Since 1952, Wharton obtained the patent concern CO2 flooding, CO2-EOR (CO2 flooding ...CO2 flooding is a process whereby carbon dioxide is injected into an oil reservoir in order to increase output when extracting oil. Since 1952, Wharton obtained the patent concern CO2 flooding, CO2-EOR (CO2 flooding enhance oil recovery) has been one of research hot-spot around the world. According to the statistical data of 2006, there are total of 94 global CO2-EOR projects, including 65 low permeability oilfield projects (79% of the total). Daqing Oilfield is the largest one of China, after more than 50 years of continuous development, oilfield comprehensive water cut has reached over 90%, and the difficulty of oilfield development has been gradually increasing. In recent years, low and ultra-low permeability reservoirs development have played a more and more important role accompany with low permeability reserves in proportion of the total reserves have been increasing year by year. But water-flooding recovery of low permeability reservoir is very low under the influence of reservoir poor properties and heterogeneity. As a kind of greenhouse gas, CO2 flooding can obtain good results for the low permeability reservoir in which the water flooding has proven ineffective. CO2 flooding Pilot Test was conducted under such background since Dec. 2002, over 10 years of practice has proved that CO2 flooding is an effective method to improve the development effect of low permeability reservoir, all experience during the mechanism study and field test should present important references for further larger-scale CO2 flooding projects.展开更多
基金supported by the National Key Research and Development Program of China(2020YFB0606404)National Natural Science Foundation of China(21991092,22272195,U2003123,U1910203).
文摘Absorption rate of CO2 into aqueous solution of N-methyldiethanolamine (MDEA) blended with diethanolamine (DEA) and piperazine (PZ) was studied and a kinetic model was established. It is shown that homogeneous activation mechanism could explain this absorption process. The absorption rate coefficients of carbon dioxide into MDEA aqueous solution blended with DEA, PZ or DEA+PZ were compared with each other. The results demonstrated that the different activation effect of DEA, PZ and DEA+PZ on the carbon dioxide absorption comes from the difference in CO2 combination rate, transport of PZ and DEA to MDEA and the regeneration rate of PZ and DEA.
基金financially supported by the Research Fund for the Doctoral Program of Higher Education of China (No. 20130006120020)the China Postdoctoral Science Foundation (No. 2013M540866)+1 种基金the China Postdoctoral Science Foundation (No. 2014T70039)the Fundamental Research Funds for the Central Universities (No. FRF-TP-14-083A2)
文摘The effects of the molding pressure of a KO2 oxygen plate and the initial concentration of CO2 on the oxygen generation rate, the oxygen generation efficiency, and the carbon dioxide absorption rate were studied using a YES-300 hydraulic press to alter the pressure when forming the oxygen plate used in a coal mine refuge chamber. In addition, changes in the initial concentration of CO2 used in the closed- box model were made by adjusting the CO2 supply system, and a CD-7 multi-function parameter instrument was employed to monitor and record the changes of O2 and CO2 concentration in the closed-box model. Results indicate that the oxygen generation rate of KO2 oxygen plates, the oxygen generation efficiency, and the carbon dioxide absorption rate decrease when there is an increase in the pressure used to mold the oxygen plates, but those values increase when the initial CO2 concentration increases. When the initial concentration of CO2 in the dosed-box model is 3.5% and the forming pressure is 10 kN, the average oxygen generation rate of 15 g KO2 oxygen plate is 11.88 ×10^-3 L/min, the oxygen generation efficiency is 80.3%, and the average CO2 absorption rate is 11.0 × 10^-3 L/min. Compared with the condition where the initial CO2 concentration is 1.5%, the results show that average oxygen genera- tion rate of oxygen plates increases by 88,9%, the oxygen generation efficiency increases by 88.9%, and the CO2 absorption rate increases by 100%.
基金Project(2006DFB72570) supported by the Grand Project of International Cooperation of Ministry of Science and Technology of China
文摘The flotation of pure and natural carbonaceous iron ore samples in the oleate flotation system was investigated.Starch can depress hematite effectively in a wide pH range,but cannot depress siderite efficiently in neutral conditions.The flotation recovery of pure hematite,siderite,and quartz in the oleate-starch-CaCl2 system is significantly different when the slurry pH varies from 4 to 12.A novel two-step flotation process was developed for the separation of iron concentrate from Donganshan carbonaceous iron ore through which the siderite concentrate is first recovered and the high quality hematite concentrates with relative high iron recovery can be obtained in the second step flotation.The siderite concentrate may be utilized directly or undergo further concentration steps to increase iron grade.
文摘Oxy fuel combustion and conventional cycle(currently working cycle) in Kazeroon plant are modeled using commercial thermodynamic modeling software. Economic evaluation of the two models regarding the resources of transport and injection of carbon dioxide into oil fields at Gachsaran for enhanced oil recovery in the various oil price indices is conducted and indices net present value(NPV) and internal rate of return on investment(IRR) are calculated. The results of the two models reveal that gross efficiency of the oxy fuel cycle is more than reference cycle(62% compared to 49.03%), but the net efficiency is less(41.85% compared to 47.92%) because of the high-energy consumption of the components, particularly air separation unit(ASU) in the oxy fuel cycle. In this model, pure carbon dioxide with pressure of 20×105 Pa and purity of 96.84% was captured. NOX emissions also decrease by 4289.7 tons per year due to separation of nitrogen in ASU. In this model, none of the components of oxy fuel cycle is a major engineering challenge. With increasing oil price, economic justification of oxy fuel combustion model increases. With the price of oil at $ 80 per barrel in mind and $ 31 per ton fines for emissions of carbon dioxide in the atmosphere, IRR is the same for both models.
基金support from the American Chemical Society Petroleum Research Fund (ACS-PRF) (55801-DNI6)
文摘Enhanced oil recovery (EOR) via carbon dioxide (CO2) flooding has received a considerable amount of attention as an economically feasible method for carbon sequestration, with many recent studies focus- ing on developing enhanced CO2 foaming additives, However, the potential long-term environmental effects of these additives in the event of leakage are poorly understood and, given the amount of additives injected in a typical CO2 EOR operation, could he far-reaching, This paper presents a summary of recent developments in surfactant and surfactant/nanoparticle-hased CO2 foaming systems, with an emphasis on the possible environmental impacts of CO2 foam leakage, Most of the surfactants studied are unlikely to degrade under reservoir conditions, and their release can cause major negative impacts on wildlife, With recent advances in the use of additives (e,g,, nonionic surfactants, nanoparticles, and other chemicals) the use of harsh anionic surfactants may no longer he warranted, This paper discusses recent advances in producing foaming systems, and highlights possible strategies to develop environmentally friendly CO2 EOR methods,
文摘CO2 flooding is a process whereby carbon dioxide is injected into an oil reservoir in order to increase output when extracting oil. Since 1952, Wharton obtained the patent concern CO2 flooding, CO2-EOR (CO2 flooding enhance oil recovery) has been one of research hot-spot around the world. According to the statistical data of 2006, there are total of 94 global CO2-EOR projects, including 65 low permeability oilfield projects (79% of the total). Daqing Oilfield is the largest one of China, after more than 50 years of continuous development, oilfield comprehensive water cut has reached over 90%, and the difficulty of oilfield development has been gradually increasing. In recent years, low and ultra-low permeability reservoirs development have played a more and more important role accompany with low permeability reserves in proportion of the total reserves have been increasing year by year. But water-flooding recovery of low permeability reservoir is very low under the influence of reservoir poor properties and heterogeneity. As a kind of greenhouse gas, CO2 flooding can obtain good results for the low permeability reservoir in which the water flooding has proven ineffective. CO2 flooding Pilot Test was conducted under such background since Dec. 2002, over 10 years of practice has proved that CO2 flooding is an effective method to improve the development effect of low permeability reservoir, all experience during the mechanism study and field test should present important references for further larger-scale CO2 flooding projects.