侵润性及含水饱和度对碳氢岩介电常数的影响

在10Hz－100MHz频率范围内，对砂岩样品及火山灰粘土－砂包容形成的样品进行复阻抗测量，并使用了考虑了双层电离扩散的MAXWELL－WANGER理论。从实践及理论上，对空隙性岩石的侵润性及含水饱和度对介电常数的影响做了研究。测量结果清楚地表明：当含水饱和度大于50％时，介电常数随含水饱和度呈线性变化，介电常数随含水饱和度的变化率是频率的函数。当频率增加时，变化率减少，介常数与含水饱和度的变化频率减少小感觉不明显，但是现在可以从理论上证实这一点。在含水完全饱和的情况下，亲水岩样比亲油岩样的介电常数高很多。侵润的变化可以通过改变岩石表面的离子电荷的数量来模拟。模拟的结果表明：亲润性对介电常数的影响是十分有效的，这些结论与我们的实验结果是一致的。

Study on source rock potential and source rocks spatial distribution in the Manghan Faulted Sag, Kailu Basin

Manghan Faulted Sag is an exploratory target area in Kailu Basin. In order to determine its exploration prospect, the effectiveness of its source rocks is evaluated by organic geochemical behavior analysis of the samples, and their distributions are predicted using trace integration seismic inversion technology. Studies on their organic matter abundance, type and maturity indicate that the source rocks in the Sag have great generating potentials. Furthermore, it is found that, based on the spatial distribution predication, the source rocks in the Sag are well developed. Therefore, the Sag has a promising prospect for exploration.

Oil shale resources in China and their utilization

The unconventional oil and gas resources presented in oil shales have meant these potential sources of hydrocarbons, which has become a research focus. China contains abundant oil shale resources, ranking fourth in the world, with ca. 7 254.48 x 108 t within 24 provinces, including 48 basins and 81 oil shale deposits. A- bout 48% of the total oil shale resources are concentrated in the eastern resource region, with a further 22% in the central resource region. 65 % of the total quantity of oil shale resources is present at depths of 0-500 m, with 17% of the total resources being defined as high-quality oil shales yielding more than 10% oil by weight. Chinese oil shale resources are generally hosted by Mesozoic sediments that account for 78% of the total re- sources. In terms of the geographical distribution of these resources, some 45% are located in plain regions, and different oil shale basins have various characteristics. The oil shale resources in China represent a highly prospective future source of hydrocarbons. These resources having potential use not only in power generation and oil refining but also in agriculture, metal and chemical productions, and environmental protection.

Relationship of hydrocarbon and source-rock in Nos.3-5 tectonic belts of the Lenghu area,northern Qaidam Basin

Based on analyses of the components of crude oil hydrocarbons and carbon isotopes,the content of normal alkane decreased from 49.00% to 20.10% when moving from the No.3 to No.5 tectonic belt of the Lenghu area of the Qaidam Basin,while cycloalkanes increased from 30.00% to 52.20% and aromatic and branch chain alkanes increased gradually as well. The maturity of sterane in crude oil is higher than that of its source-rock,which shows that the hydrocarbons were generated from a deep source-rock of high maturity around the tectonic belts of the Lenghu area. The analysis of the characteristics of carbon isotopes also shows that these isotopes of hydrocarbon compounds in the No.4 and No.5 tectonic belt are apparently heavier than those in the No.3 belt. The results of our research show that the hydrocarbons in the No.3 tectonic belt are mainly from a relatively rich sapropelic substance,while the hydrocarbons in the No.4 and No.5 tectonic belt originated mainly from organic matter of a relatively rich humic type substance.

Pedogenic Carbonate and Soil Dehydrogenase Activity in Response to Soil Organic Matter in Artemisia ordosica Community

Little attention has been paid to the role of soil organic matter （OM） in the formation of pedogenic carbonate in desert soils. The relationships among soil OM, soil dehydrogenase activity （DHA）, and soil CaCO3 in a plant community dominated by Artemisia ordosica, located on the eastern boundary of Tcngger Desert in the Alxa League, Inner Mongolia, China, were studied to understand whether OM was directly involved in the formation of pedogenic carbonate. The results showed that DHA and CuCO3 positively correlated with OM content, and DHA, OM, and CaCO3 were correlated with each other in their spatial distribution, indicating that abundant OM content contributed to the formation of CaCO3. Therefore, the formation of pedogenic CaCO3 was a biotic process in the plant community dominated by A. ordosica.

Petroleum systems in the Damintun Depression, Liaohe Oilfield

There are two different types of oils—high-wax oil and normal oil—found in the Damintun Depression of Liaohe Oilfield after several years of exploration and development, but their distributions and origins had confused the explorers in the oilfield. The introduction of petroleum-system concept shifts the view of geoscientists from geology and geophysics to oil, gas and their related source rocks. After detailed study, two petroleum systems have been identified in the Damintun Depression: (1) the ES42-Ar buried hill petroleum system (called the high-wax oil petroleum system) and (2) the ES41+ES34-ES4 and ES3 petroleum system (called the normal oil petroleum system). Based on the detailed analysis of the basic components, and all the geological processes required to create these elements of the two petroleum systems, it is put forward that targets for future exploration should include the area near Dongshenpu-Xinglongpu and the area near the Anfutun Sag. This provides scientific basis and has theoretical and practical meaning for the exploration and development.

Geochemistry and possible origin of the hydrocarbons from Wells Zhongshen1 and Zhongshen1C, Tazhong Uplift

In 2013, a great breakthrough of deep petroleum exploration was achieved in the Cambrian pre-salt intervals of Wells Zhongshen1(ZS1) and Zhongshen1C(ZS1C), Tazhong Uplift. However, the hydrocarbon discovery in the Cambrian pre-salt intervals has triggered extensive controversy regarding the source of marine oils in the Tarim Basin. The geochemistry and origin of the Cambrian pre-salt hydrocarbons in Wells ZS1 and ZS1 C were investigated using GC, GC-MS and stable carbon isotope technique. These hydrocarbons can be easily distinguished into two genetic families based on their geochemical and carbon isotopic compositions. The oil and natural gases from the Awatage Formation of Well ZS1 are derived from Middle-Upper Ordovician source rocks. In contrast, the condensate and gases from the Xiaoerbulake Formation of Wells ZS1 and ZS1 C probably originate from Cambrian source rocks. The recent discovery of these hydrocarbons with two different sources in Wells ZS1 and ZS1 C suggests that both Middle-Upper Ordovician-sourced hydrocarbons and Cambrian-sourced petroleums are accumulated in the Tazhong Uplift, presenting a great exploration potential.

Hydrocarbon charging of the Ordovician reservoirs in Tahe-Lunnan area, China

The Tahe-Lunnan hydrocarbon province is China's largest region with oil-and-gas-producing marine carbonate rocks. However, in terms of multi-source hydrocarbon generation, multi-episode reservoir adjustment and reconstruction, it remains unsettled how to determine the geological period of primary hydrocarbon filling of the Ordovician reservoir in this region. Based on the analysis of distribution and properties of reservoir, hydrocarbon filling of the Cambrian source rocks in the Late Caledon stage has largely been destroyed. However, hydrocarbon filling of the Middle Ordovician source rocks in the Early Carboniferous resulted in the major body of crude oil. During the charging process, the hydrocarbons were oxidatively degraded to heavy oil due to the poor closure conditions, which is corroborated by homogenization temperature of inclusions. Moreover, the capturing of hydrocarbon inclusions with high-temperature does not represent the filling of mature petroleum in the later period, but represents the result of the natural gas containing light fraction. Therefore, the Tahe-Lunnan area underwent two hydrocarbon filling processes, and the invasion of excessive dry gas led to a gas-washing fractionation upon the original Ordovician reservoirs.

Olivine versus peridotite during serpentinization:Gas formation

The dependence of starting materials and their initial grain sizes on the formation of gases （H2, CH4, C2H6 and C3Hs） during serpentinization was investigated by conducting hydrothermal experiments at 311℃ and 3 kbar on olivine and peridotite with initial grain sizes ranging from 〈30 to 177 μm. Hydrocarbons （CH4, C2H6 and C3H8） were produced from reaction between dissolved CO2 in the starting fluids and HE formed during serpentinization, which were analyzed by Gas Chromatography. It was found that olivine serpentinization produced much less H2 and CH4 compared with those after peridotite alteration, while their C2H6 and C3H8 were identical. For example, for olivine with initial grain sizes of 〈30 μm, the amounts of HE and CH4 were 79.6 mmol/kg and 460 μmol/kg after 27 days, respectively. By contrast, the quantities of H2 and CH4 produced in experiment on peridotite with the same run duration were much larger, 119 mmol/kg and 1300 μmol/kg, respectively. This indicates that spinel and pyroxene in peridotite may increase the amounts of HE and hydrocarbons, possibly due to the catalytic effect of aluminum released by spinel and pyroxene during serpentinization. Moreover, the production of H2 and hydrocarbons is negatively correlated with initial grain sizes of the starting material, with smaller amounts of HE and hydrocarbons for larger initial grain sizes, indicating that the kinetics of serpentinization influences the formation of HE and hydrocarbons, possibly because of the lack of catalytic minerals for the starting material with larger grain sizes. This study suggests that olivine cannot completely represent peridotite during serpentinization, and that H2 and hydrocarbons in hydrothermal fields near the mid-ocean ridge may be produced in a very long period of serpentinization or the presence of catalytic minerals due to large grain sizes of ultramafic rocks.