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碳氢火焰中碳黑检测方法评述 被引量:7
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作者 娄春 陈辰 +1 位作者 孙亦鹏 周怀春 《中国科学:技术科学》 EI CSCD 北大核心 2010年第8期946-958,共13页
碳氢燃料不完全燃烧所产生的碳黑是一种仅次于二氧化碳的温室物质,开展碳氢火焰中碳黑的检测研究对于充分理解碳黑生成机理、控制碳黑排放有着重要的作用.本文综述了碳氢火焰中碳黑检测的常用方法,包括:热泳探针取样及电镜分析、热电偶... 碳氢燃料不完全燃烧所产生的碳黑是一种仅次于二氧化碳的温室物质,开展碳氢火焰中碳黑的检测研究对于充分理解碳黑生成机理、控制碳黑排放有着重要的作用.本文综述了碳氢火焰中碳黑检测的常用方法,包括:热泳探针取样及电镜分析、热电偶颗粒密度法、消光法、激光诱导炽光法、双色法、发射CT法,并详细介绍了各种检测方法的基本原理及应用状况.碳黑检测的发展趋势是要实现对碳氢火焰中温度、碳黑浓度、碳黑尺寸等多参数的多维分布的在线检测;不仅要面向实验室小型燃烧火焰,还要面向工业应用中大尺度火焰;而且对于高压、零重力、微重力等燃烧火焰也要提供合适的检测手段. 展开更多
关键词 碳氢火焰 燃烧检测 激光诱导炽光法 发射CT法
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碳氢火焰辐射特性快速判定方法研究
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作者 姜志伟 张安琪 +1 位作者 易正明 吕伟 《热科学与技术》 CAS CSCD 北大核心 2022年第3期283-289,共7页
针对比色法计算碳氢火焰温度时要判定其是否为灰体,提出了一种基于图像处理的辐射特性判定方法。该方法用黑体炉标定CCD相机,拟合得到三基色值与单色辐射强度的函数关系,再根据普朗克定律和比色法测温原理计算蜡烛火焰的温度以及三基色... 针对比色法计算碳氢火焰温度时要判定其是否为灰体,提出了一种基于图像处理的辐射特性判定方法。该方法用黑体炉标定CCD相机,拟合得到三基色值与单色辐射强度的函数关系,再根据普朗克定律和比色法测温原理计算蜡烛火焰的温度以及三基色值下的辐射率,计算三个辐射率的均方差并进行辐射特性判定。实验结果表明:三个快门速度下,计算温度的相对误差均小于0.500%,计算辐射率的相对误差均小于5.000%,说明标定实验的有效性;以蜡烛火焰为研究对象,其辐射率的均方差均大于0.024,可判定蜡烛火焰为非灰体。 展开更多
关键词 图像处理 碳氢火焰 比色法 辐射特性 温度
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不含硼酸盐的环氧防火涂料制备及应用 被引量:2
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作者 张武军 徐丹 《涂料工业》 CAS CSCD 北大核心 2017年第5期75-78,共4页
研究了防火涂料的火焰传播指数、发烟指数、漆膜溶解失质量率、耐碳氢火焰能力及环境耐久性。研究表明:不含硼酸盐的环氧防火涂的漆膜溶解失质量率低于相应的含硼酸盐防火涂料,对环境水质干扰小;依据GA/T 714—2007测试其耐碳氢火焰防... 研究了防火涂料的火焰传播指数、发烟指数、漆膜溶解失质量率、耐碳氢火焰能力及环境耐久性。研究表明:不含硼酸盐的环氧防火涂的漆膜溶解失质量率低于相应的含硼酸盐防火涂料,对环境水质干扰小;依据GA/T 714—2007测试其耐碳氢火焰防火性能,膜厚10 mm时,耐火时为160 min;依据GB 14907—2002和ANSI/UL 1709—2007测试其在各种环境下的耐久抗衰减能力<15%,证明了其能应用于高层建筑、化工厂和海洋采油平台钢结构上。 展开更多
关键词 不含硼酸盐 防火涂料 碳氢火焰 环境耐久性
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Modeling Study of Hydrogen/Oxygen and n-alkane/Oxygen Counterflow Diffusion Flames
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作者 汪小卫 蔡国飙 Vigor Yang 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2011年第2期231-238,I0004,共9页
A comprehensive analysis of hydrogen/oxygen and hydrocarbon/oxygen counterflow diffusion flames has been conducted using corresponding detailed reaction mechanisms. The hydrocarbon fuels contain n-alkanes from CH4 to ... A comprehensive analysis of hydrogen/oxygen and hydrocarbon/oxygen counterflow diffusion flames has been conducted using corresponding detailed reaction mechanisms. The hydrocarbon fuels contain n-alkanes from CH4 to C16H34. The basic diffusion flame structures are demonstrated, analyzed, and compared. The effects of pressure, and strain rate on the flame behavior and energy-release rate for each fuel are examined systematically. The detailed chemical kinetic reaction mechanisms from Lawrence Livermore National Laboratory (LLNL) are employed, and the largest one of them contains 2115 species and 8157 reversible reactions. The results indicate for all of the fuels the flame thickness and heat release rate correlate well with the square root of the pressure multiplied by the strain rate. Under the condition of any strain rate and pressure, H2 has thicker flame than hydrocarbons, while the hydrocarbons have the similar temperature and main products distributions and almost have the same flame thickness and heat release rate. The result indicates that the fuels composed with these hydrocarbons will still have the same flame properties as any pure n-alkane fuel. 展开更多
关键词 COUNTERFLOW Combustion HYDROGEN HYDROCARBON FLAME
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Free Radical Imaging Techniques Applied to Hydrocarbon Flames Diagnosis 被引量:2
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作者 A. Caldeira-Pires Instituto Nacional de Pesquisas Espaciais, INPE-LCP, Rod. Pres. Dutra, km 40 -12630-000 SP Brazil 《Journal of Thermal Science》 SCIE EI CAS CSCD 2001年第2期182-187,192,共7页
This paper evaluates the utilization of the radical chemiluminesecnce imaging and tomographic reconstruction techniques to assess advanced information on reacting flows. Two different laboratory flow configurations we... This paper evaluates the utilization of the radical chemiluminesecnce imaging and tomographic reconstruction techniques to assess advanced information on reacting flows. Two different laboratory flow configurations were analyzed, including unconfined non-premixed jet flame measurements to evaluate name fuel/air mixing patterns at the burner-port of a typical glass-furnace burner. The second case characterized the reaction zone of premixed flames within gas turbine combustion chambers, based on a laboratory scale model of a lean prevaporized premixed (LPP) combustion chamber. The analysis shows that advanced imaging diagnosis can provide new information on the characterization of flame mixing and reacting phenomena. The utilization of local C2 and CH chemiluminescence can assess useful information on the quality of the combustion process, which can be used to improve the design of practical combustors. 展开更多
关键词 free radical imaging TOMOGRAPHY gas turbine glass furnace.
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Asymptotic Analysis of Transport Properties and Burning Velocities for Premixed Hydrocarbon Flames
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作者 J.Y.Law H.K.Ma 《Journal of Thermal Science》 SCIE EI CAS CSCD 2001年第2期170-175,共6页
Based on premixed flame, the theoretical model of transport properties with temperature variation was established inside a preheated zone. Lewis number of the deficient-to- stoichiometric hydrocarbon/air mixture has b... Based on premixed flame, the theoretical model of transport properties with temperature variation was established inside a preheated zone. Lewis number of the deficient-to- stoichiometric hydrocarbon/air mixture has been theoretically predicted over a wide range of preheated temperature. These predictions are compared with the experimental data on disport properties that exist in the literature. The response of the burning velocity to flame stretch can be parameterized by the laminar flame speed and Markstein length. Therefore, if the laminar flame speed and Markstein number could be accurately simulated by using an analytic expression of characterized temperature, equivalence ratio, and Lewis number, the results are applicable to the prediction of methane, acetylene, ethylene, ethane, and propane flames. Expanding previous studies on the extinction of premixed flames under the influence of stretch and incomplete reaction, the results were further classified and rescaled. Finally, it could be inferred that parameter Pq, the rescaled extinction Karlovitz number could be used to explain the degree or flame quench. 展开更多
关键词 Lewis number laminar flame speed burning velocity Markstein number Karlovitz number.
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