一段炉汽碳比控制系统

介绍中国石化安庆分公司化肥厂用炼厂气部分顶替石脑油的改造项目中 ,采用的一段炉汽碳比控制系统 ,分析了控制过程 。

小型汽轮机碳精汽封的国产化

介绍了碳精汽封的工作原理和特点，分析了其泄漏的原因，并针对一台引进汽轮机的汽封结构进行了理论计算，从而确定了该汽轮机碳精汽封的结构参数和材料，实现了该汽轮机碳精汽封的国产化。

增压直喷发动机积碳形成机理及对策

为研究直喷发动机积碳的形成机理并提出解决措施,通过热重、红外光谱、电子能谱、扫描电镜等方法分析了直喷发动机积碳的成分和形貌,发现积碳的成分主要是汽油和润滑油组分、碳烟颗粒、无机灰分,且燃油清洁度、润滑油、燃烧温度是影响积碳形成的重要因素。通过内窥镜对比了使用不同型号、不同剂量汽油清净剂对改善积碳的效果。

两段式空气气化炉的模拟与研究

二段式空气气化炉由于可以节省空分装置,减少初期投资和降低消耗功率,因而受到了广泛关注。文章建立了两段式空气气化炉的计算模型,研究了入口氧碳比、汽煤比、气化压力对出口粗煤气成分的影响,分析了两段式空气气化炉的特点,对该种气化炉的操作参数进行了优化。

客车采暖装置防腐蚀研究

介绍了碳钢水冷汽防腐涂料的各项有关性能及装车试验和运用情况

Research and Development of Heat-Resistant Materials for Advanced USC Power Plants with Steam Temperatures of 700℃ and Above

Materials-development projects for advanced ultra-supercritical(A-USC) power plants with steam temperatures of 700℃ and above have been performed in order to achieve high efficiency and low CO_2 emissions in Europe, the US, Japan, and recently in China and India as well. These projects involve the replacement of martensitic 9%–12% Cr steels with nickel(Ni)-base alloys for the highest temperature boiler and turbine components in order to provide sufficient creep strength at 700℃ and above. To minimize the requirement for expensive Ni-base alloys, martensitic 9%–12% Cr steels can be applied to the next highest temperature components of an A-USC power plant, up to a maximum of 650℃. This paper comprehensively describes the research and development of Ni-base alloys and martensitic 9%–12% Cr steels for thick section boiler and turbine components of A-USC power plants, mainly focusing on the long-term creep-rupture strength of base metal and welded joints, strength loss in welded joints, creep-fatigue properties, and microstructure evolution during exposure at elevated temperatures.

Multi-Physics Modeling Assisted Design of Non-Coking Anode for Planar Solid Oxide Fuel Cell Fueled by Low Steam Methane

Internal reformation of low steam methane fuel is highly beneficial for improving the energy efficiency and reducing the system complexity and cost of solid oxide fuel cells(SOFCs).However,anode coking for the Ni-based anode should be prevented before the technology becomes a reality.A multi-physics fully coupled model is employed to simulate the operations of SOFCs fueled by low steam methane.The multi-physics model produces I-V relations that are in excellent agreement with the experimental results.The multi-physics model and the experimental non-coking current density deduced kinetic carbon activity criterion are used to examine the effect of operating parameters and the anode diffusion barrier layer on the propensity of carbon deposition.The interplays among the fuel utilization ratio,current generation,thickness of the barrier layer and the cell operating voltage are revealed.It is demonstrated that a barrier layer of 400μm thickness is an optimal and safe anode design to achieve high power density and non-coking operations.The anode structure design can be very useful for the development of high efficiency and low cost SOFC technology.

One of the Scenarios for Reduction the Emission of Pollutants from Motor Vehicle in the Territory of the Republic of Kosovo

Together with development of the industry, there is present a continuous increase number of motor vehicles that contributes to the growth of the emission of pollutants. This is the main reason that during eighties of the last century, a special attention has started to be paid on pollution emissions from vehicles. It is important to note that most of the current emissions are formed directly and are present in urban areas. The aim of this research was to determine the emission of pollutants in the territory of the Republic of Kosovo, when circulates more than 380,000 motor vehicles. Taking into consideration the daily traffic jam, and the fact that gasoline engines are responsible for most emissions of CO, while diesel engines for NOx emission, the conclusion arises that there is necessary a special dedication to the emission of pollutants and to the definition of the measures to reduce or control them. Based on the performed tests and realistic assessment of the overall situation in the Republic of Kosovo, the current situation on the amount of pollution was compared with development countries in the region as a matter in the research. The results obtained, suggest to the most important causes that increase pollutant emission from motor vehicles and offer actions to keep the same level or to reduce them.

In situ FT-IR spectroscopy investigations of carbon nanotubes supported Co-Mo catalysts for selective hydrodesulfurization of FCC gasoline

To better understand the nature of carbon nanotubes supported Co-Mo catalysts （Co-Mo/CNTs） for selective hydrodesulfurization （HDS） of fluid catalytic cracking （FCC） gasoline, studies are carried out using in situ Fourier transform infrared spectroscopy （FT-IR）. The catalytic performances of Co-Mo/CNTs catalysts were evaluated with a mixture of cyclohexane, diisobutylene, cyclohexene, 1-octene （60 ： 30 ： 5 ： 5, volume ratio） and thiophene （0.5%, ratio of total weight） as model compounds to simulate FCC gasoline. The HDS experimental results suggested that the HDS activity and selectivity of Co-Mo/CNTs catalysts were affected by Co/Mo ratio; the optimal Co/Mo atomic ratio is about 0.4, and the optimum reaction temperature is 260 ℃. The in situ FT-IR studies revealed that 1-octene can be completely saturated at 200 ℃. In the FT-IR spectra of diisobutylene, the characteristic absorption peak around 3081 cm^-1 for the stretching vibration peak of =C-H bond was still clear at 320 ℃ indicating that diisobutylene is difficult to be hydrogenated. As for the thiophene, no characteristic absorption peak could be found around 3092 cm^-1 and 835 cm^-1 when the reaction temperature was raised to 280 ℃, indicating that thiophene had been completely hydrodesulfurized. On the basis of FT-IR results, it can be deduced that thiophene HDS reaction occurred mainly through direct hydrogenolysis route, whereas thiophene HDS and diisobutylene hydrogenation reaction over Co-Mo/CNTs catalysts might occur on two different kinds of active sites.

Probing the catalytic behavior of ZnO nanowire supported Pd_1 single-atom catalyst for selected reactions

We have dispersed individual Pd atoms onto ZnO nanowires(NWs)as single‐atom catalysts(SACs)and evaluated their catalytic performance for several selected catalytic reactions.The Pd1/ZnO SAC is highly active,stable,and selective towards CO2for steam reforming of methanol to produce hydrogen.This catalyst system is active for oxidation of CO and H2but performs poorly for preferential oxidation of CO in hydrogen‐rich stream primarily due to the strong competitive oxidation of H2on ZnO supported Pd1atoms.At ambient pressure,reverse water‐gas‐shift reaction occurs on the Pd1/ZnO SAC.This series of tests of catalytic reactions clearly demonstrate the importance of selecting the appropriate metal and support to develop SACs for catalytic transformation of molecules.

Coupling Heat and Electricity Sources to Intermediate Temperature Steam Electrolysis

The use of CO2-free energy sources for running SOEC （solid-oxide electrolysis cell） technologies has a great potential to reduce the carbon dioxide emissions compared to fossil fuel based technologies for hydrogen production. The operation of the electrolysis cell at higher temperature offers the benefit of increasing the efficiency of the process. The range of the operating temperature of the SOEC is typically between 800 ~C and 1,000 ~C. Main sources of degradation that affect the SOEC stack lifetime is related to the high operating temperature. To increase the electrolyser durability, one possible solution is to decrease the operating temperature down to 650 ~C, which represents the typical operating range of the ITSE （intermediate temperature steam electrolysis）. This paper is related to the work of the JU-FCH project ADEL, which investigates different carbon-free energy sources with respect to potential coupling schemes to ITSE. A predominant focus of the analysis is put on solar concentrating energy systems （solar tower） and nuclear energy as energy sources to provide the required electricity and heat for the ITSE. This study will present an overview of the main considerations, the boundary conditions and the results concerning the development of coupling schemes of the energy conversion technologies to the electrolyser.

Synthesis of TiO2 supported on activated carbon by MOCVD： operation parameters study

A novel metallo-organic chemical vapor deposition (MOCVD) technique has been applied to the preparation of the photocatalytic titanium dioxide supported on activated carbon. The effects of various condition parameters such as carrier gas flow rate, source temperature and deposition temperature on the deposition rate were investigated. The maximum deposition rate of 8.2 mg/(g.h) was obtained under conditions of carrier gas flow rate of 400 ml/min, source temperature of 423 K and deposition temperature of 913 K. The deposition rate followed Arrhenius behavior at temperature of 753 K to 913 K, corresponding to activation energy Ea of 51.09 kJ/mol. TiO2 existed only in anatase phase when the deposition temperature was 773 K to 973 K. With increase of deposition temperature from 1073 K to 1273 K, the rutile content sharply increased from 7% to 70%. It was found that a deposition temperature of 773 K and a higher source temperature of 448 K resulted in finely dispersed TiO2 particles, which were mainly in the range of 10-20 nm.

The Status Quo and Development Trend of Low-carbon Vehicle Technologies in China

Three types of low-carbon vehicle technologies in China are reviewed. Potential effects are listed for those integrated energy-saving technologies for conventional vehicles. Low carbon transitions, including alternative vehicle power train systems and fuels, are discussed on their development status and trends, including life cycle primary fossil energy use and greenhouse gas emissions of each pathway. To further support the low-carbon vehicle technologies development, integrated policies should seek to： （1） employ those integrated energy-saving technologies, （2） apply hybrid electric technology, （3） commercialize electric vehicles through battery technology innovation, （4） support fuel cell vehicles and hydrogen technology R＆D for future potential applications, （5） boost the R＆D of second generation biofuel technology, and （6） conduct further research on applying low-carbon technologies including CO2 capture and storage technology to coal-based transportation solutions.

Small Scale Refrigerators and Freezers： Thermal Improvements in the Envelope

Like in other sectors of activity, the sustainability in refrigeration systems is a mandatory goal to achieve, namely at house holdings, bars and restaurants, where small-scale refrigerators and freezers are widely used. The aim of this work is to demonstrate experimentally, trough measurements carried out in these equipments, the improvement that can be achieved if several modifications are implemented in traditional household refrigeration systems. In addition, it was also simulated and analysed experimentally a slightly different equipment, a refrigeration system used for draught beverages. Both systems work on a single vapour compression refrigeration with R-134a as working fluid. In the end, by implemented the modifications tested in the virtual model, it was possible to improve their thermal behaviour, a decrease in electrical energy consumption, as well as, the associated CO2 emissions reduction can be attained. In this project, the CFD （Computational Fluid Dynamics） soffware--ANSYS Fluent was used to simulate the ambient temperature and velocity fields inside the refrigerator and in that way to validate the measured results.

Comparative Analysis of Gas Emissions from a Vehicle Running on Ethanol and Natural Gas Fuel

It is known that the transport sector has a fundamental importance in the modem society, as the economic development is directly linked to mobility. Over the years, the transport became linked to different environmental problems, which can be detached greenhouse gases emissions in the atmosphere, where in recent decades can be perceived the intensification and targeting of efforts in research and development of new technologies to reduce the levels of greenhouse gases emissions in the atmosphere. In this context, it can be highlighted the modem systems of electronic engine management, new automotive catalysts and the use of renewable fuels which contribute to reducing the environmental impact. This research had, as its purpose, the analysis of fuels characteristics used for testing, comparative analysis of gas emissions from a motor vehicle running on ethanol or natural gas fuels according to NBR 6601 and conducting tests to estimate the maximum catalytic efficiency. For the implementation of trial, a flex vehicle was installed in a chassis dynamometer equipped with a gas analyzer, in order that before the completion of the urban driving cycle, were determined the content of hydrocarbons corrected, carbon monoxide corrected, carbon dioxide and oxygen present in gas emissions from the engine. The research concluded that： the performance analysis for characterization of fuel showed consistent with ANP specifications; after tests performances, it can be stated that natural gas fuel was the fuel which had the highest content of hydrocarbons and carbon monoxide corrected, while ethanol had the highest amount of carbon dioxide and oxygen residue present in gas emissions; before a comparative analysis, the vehicle catalyst showed the best performance for reducing the content of hydrocarbon corrected present in exhaustion gases when it worked with natural gas fuel and showed maximum efficiency of 100% to reduce the content of carbon monoxide corrected for both fuels. Before this, it can be stated that the vehicle catalyst showed satisfactory performance, achieving good reduction levels of greenhouse gases emissions.

国外低能耗合成氨技术的新发展

一、概况(一)世界合成氨的生产能力世界合成氨的生产能力仍在迅速提高,1978年年中法国对世界各国1978年5月以前投产的,以及正在计划和建设中装置的生产能力分别统计如下表:

Hydrogen production through CO_2 sorption-enhanced methane steam reforming:Comparison between different adsorbents

A two-dimensional transient model has been developed to describe the catalytic methane reforming （MSR） coupled with simultaneous CO2 removal by different absorbents under non-isothermal, non-isobaric and non-adiabatic operating conditions. The influences of temperature, pressure and steam/carbon （S/C） on enhancement were taken into account. The results showed that the hydrogen mole fraction （dry basis） higher than 94% could be achieved using Li4SiO4, CaO, and HTC as CO2 acceptors at the operating conditions of 550~C and 0.1 MPa. When the reaction temperature varied from 500℃ to 600℃, the initial CO2 capture rates were HTC〉CaO〉Li4SiO4〉LizZrO3, and the saturation rates HTC〉CaO〉Li4SiOg〉Li2ZrO3. Increasing the reaction temperature would improve the CO2 capture rate and available CO2 capacity. For Li4SiO4, although the adsorbing rate increased as the operating temperature increased, the capacity almost did not change. At 550℃, increasing the working pressure could promote the enhancing factors of Li4SiO4,Li2ZrO3 and HTC. There was an optimal steam/carbon ratio between 2-4.5 such that all CaO, Li4SiO4, HTC and Li2ZrO3 would obtain the biggest enhancement for H2 production at the pre-breakthrough stage.

Carbon nanocomposites with high photothermal conversion efficiency

Photothermal conversion for water vapor gen- eration is a novel strategy and an efficient way to utilize solar energy, which has great potential for water purification and desalination. In this review, the development of photothermal conversion and the classification of absorbers for solar vapor generation systems are presented, especially in recent devel- opment of carbon nanocomposites （carbon nanotubes and graphene） as solar vapor generation devices. Combined with recent progresses and achievements in this field, we discuss the challenges and opportunities for photothermal conversion based on carbon nanocomposites as well as their promising applications.