吸附法分步处理含油废水研究

提出用灯芯草吸收含油废水中的悬浮油,然后再用碳石纤维对乳化油和溶解油进行深度吸附,系统考察了两种吸油剂的性能以及吸附时间、pH、盐度等对吸油效果的影响。结果表明灯芯草可以快速吸收废水中的悬浮油,pH、盐度对吸油效果影响很小。碳石纤维对乳化油的吸附速度缓慢,废水酸碱度和盐度显著影响其饱和吸附量。

Catalytic graphitization of PAN-based carbon fibers with electrodeposited Ni-Fe alloy

Ni-Fe alloy was electrodeposited on the surface of polyacrylonitrile （PAN）-based carbon fibers, and catalytic graphitization effect of the heat-treated carbon fibers was investigated by X-ray diffractometry and Raman spectra. It is found that Ni-Fe alloy exhibits significant catalytic effect on the graphitization of the carbon fibers at low temperatures. The degree of graphitization of the carbon fibers coated with Ni-Fe alloy （57.91% Fe, mass fraction） reaches 69.0% through heat treatment at 1 250 °C. However, the degree of graphitization of the carbon fibers without Ni-Fe alloy is only 30.1% after being heat-treated at 2 800 °C. The catalytic effect of Ni-Fe alloy on graphitization of carbon fibers is better than that of Ni or Fe at the same temperature, indicating that Ni and Fe elements have synergic catalytic function. Furthermore, Fe content in the Ni-Fe alloy also influences catalytic effect. The catalytic graphitization of Ni-Fe alloy follows the dissolution-precipitation mechanism.

钢管聚丙烯纤维超高强石渣混凝土短柱的静力特性

以试件的直径、径厚比和混凝土强度等级为试验参数进行了19根试件的轴心抗压试验,考察了钢管聚丙烯纤维超高强石渣混凝土短柱轴心受压时的破坏形态,揭示了影响其力学性能的因素和规律.试验结果表明:钢管内填充低碳聚丙烯纤维超高强石渣混凝土可以解决由于自收缩偏大引起的钢管混凝土脱空问题;在试验参数范围内,影响试件静力特性的主要因素是套箍指标和核心混凝土强度;荷载-平均应变关系曲线可以分为4个阶段,即弹性阶段、弹塑性阶段、承载力下降阶段和承载力回升阶段;所有试件都呈剪切型的破坏特征,残余承载力达到极限荷载的80%以上,都有较好的延性性能,极限应变达到8.67%～24.9%;最后,推荐了经回归分析得到的钢管聚丙烯纤维超高强石渣混凝土短柱轴心受压极限承载力的计算公式,计算结果与试验数据比较吻合.

ADSORPTION CAPACITY OF ACTIVATED CARBON FIBER FABRIC IN CYANIDE LEACHING LIQUOR OF GOLD ORES

Adsorption capacity of ACFF in cyanide leaching liquor of gold ores was studied with cyanide leaching liquor of gold ores, containing various kinds of ions. The adsorbed leaching liquor was analyzed by atomic emission spectroscopy and colorimetric method. The contents of various kinds of ions in ACFF were determined with X-ray photoctron spectroscopy. ACFF not only adsorbed gold but also adsorbed arsenic, nickel, zinc, calcium, sulphur, bismuth, copper, iron, silver and cyanide anion. Atomic percentage of C and those of O, N, Zn, Fe increase and decrease respectively with the increase of the layer depth, while those of Ca, Au, Ag keep constant.

Preparation of three-dimensional braided carbon fiber reinforced mullite composites from a sol with high solid content

To prepare the three-dimensional braided carbon fiber reinforced mullite （3D C/mullite） composites, an Al2O3-SiO2 solwith a solid content of 20% （mass fraction） and an Al2O3/SiO2 mass ratio of 2：1 was selected as the raw material. Characteristics andmullitization of the sol were analyzed throughly. It is found that the formation of mullite is basically completed at 1300℃ and thegel powders exhibit favorable sintering shrinkage. The 3D C/mullite composites without interfacial coating were fabricated throughthe route of vacuum impregnation-drying-heat treatment. Satisfied mechanical properties with a flexural strength of 241.2 MPa anda fracture toughness of 10.9 MPa·m1/2are obtained although the total porosity reaches 26.0%. Oxidation resistances of the compositesat 1200, 1400 and 1600 ℃ were investigated. Due to the further densification of matrix, the 3D C/mullite composites show tiny massloss and their mechanical properties are well retained after oxidation at 1600 ℃ for 30 min.

Catalytic graphitization of polyacrylonitrile(PAN)-based carbon fibers with Fe-Cr_2O_3 composite coating

The process of electrodepositing Fe-Cr2O3 composite coating on polyacrylonitrile （PAN）-based carbon fibers and its catalytic graphitization were studied. Carbon fibers with and without electrodeposited Fe-Cr2O3 composite coating were heat treated at different temperatures and the structural changes were characterized by XRD, Raman spectroscopy and SEM. The results indicate that Fe-Cr2O3 composite coating exhibits a significant catalytic effect on graphitization of carbon fibers at low temperatures. When the Fe-Cr2O3-coated carbon fibers were heat treated at 1 300℃ the interlayer spacing （doo2） and ratio of relative peak area （AD/AG） reach 3.364/k and 0.34, respectively. Whereas, the extent of graphitization of pristine carbon fibers is comparatively low even after heat treatment at 2 800℃ and the values of doo2 and AD/AG are 3.414 A and 0.68, respectively. The extent of graphitization of carbon fibers increases not only with the increase of the catalyst gross but also the Cr2O3 content in Fe-Cr2O3 coating. The catalytic effect of Fe-Cr2O3 composite coating accords with the dissolution-precipitation mechanism.

Synthesis of carbon nanofibers by ethanol catalytic combustion technique

A general, simple and economic synthetic method for synthesizing carbon nanofibers was presented. In the method, ethanol was employed as carbon source; metal salts such as nickel nitrate, ferric nitrate and ferric chloride were used as catalyst precursor respectively; copper plate was employed as the support material. A lot of products were obtained by catalytic combustion deposition of ethanol vapor. Then the as-prepared carbon nanofibers were characterized by field-emission scanning electron microscopy, transmission electron microscopy, Raman spectroscopy, energy dispersion X-ray spectroscopy and selected-area electron diffractometry. By analyzing the results of characterization, the conclusions are as follows: 1) the large catalyst particles tend to form large-diameter CNFs, small catalyst particles are inclinable to form small-diameter CNFs; 2) the morphology of the catalyst can affect the final morphology of the CNFs. Moreover, the possible growth mechanisms were proposed and the degree of graphitization of samples was estimated by Raman spectroscopy characterization.

Catalytic graphitization of Mo-B-doped polyacrylonitrile(PAN)-based carbon fibers

A novel carbon fiber pretreatment was proposed.Polyacrylonitrile(PAN)-based carbon fibers were first anodized in H3PO4 electrolyte to achieve an active surface,and then coated with Mo-B catalysts by immersed the carbon fibers in a uniformly dispersed Mo-B sol.The as-treated carbon fibers were then graphitized at 2 400 ℃ for 2 h.The structural changes were characterized by X-ray diffractometry(XRD),Raman spectroscopy,scanning electron microscopy(SEM) and high-resolution transmission electronic microscopy(HRTEM).The results show that much better graphitization can be achieved in the presence of Mo-B,with an interlayer spacing(d002) of 0.335 8 nm and a crystalline size(Lc) of 28 nm.

Catalytic graphitization of polyacrylonitrile-based carbon fibers coated with Prussian blue

Prussian blue(PB) was used as catalyst to improve the extent of graphitization of polyacrylonitrile(PAN)-based carbon fibers.PB was deposited on carbon fibers by anodic electrodeposition and the thickness of PB coating(PB content) was controlled by adjusting the electrodeposition time.PAN-based carbon fibers with PB coating were heat-treated and the extent of graphitization was measured by X-ray diffractometry and Raman spectroscopy.The results indicate that the extent of graphitization of PAN-based carbon fibers is enhanced in the presence of the coating.When the PB-coated carbon fibers were heat-treated at 1 900 ℃,interlayer spacing(d002) and crystallite size(Lc) reach 0.336 8 and 21.2 nm respectively.Contrarily,the values of d002 and Lc are 0.341 4 and 7.4 nm respectively when the bare carbon fibers were heat-treated at 2 800 ℃.Compared with the bare carbon fibers,PB can make the heat treatment temperature(HTT) drop more than 500 ℃ in order to reach the same extent of graphitization.Furthermore,the research results show that PB content also has a certain influence on the extent of graphitization at the same HTT.

Cutting Characteristics of CFRP Boards Using Electroplated Diamond Wire Tools

CFRP （carbon fiber reinforced plastic）, which is composed of carbon fibers in a resin matrix, is an extremely strong and light composite material that has found use in the aerospace and automotive industries. CFRP boards are very difficult to machine using common machining processes. Various machining artifacts, such as burrs and delamination, occur frequently when machining CFRP. Adequate techniques for machining CFRP have not yet been established. Recently, electroplated diamond wire machining technology has found use in cutting hard, brittle materials such as silicon and sapphire. In this study, we used an electroplated diamond wire saw to cut a CFRP workpiece. We quantified the cutting forces imposed on the workpiece and observed the surface state of the workpiece after cutting. We demonstrated that an electroplated diamond wire tool is suitable for the high-quality machining of CFRP boards.

Nitrogen Plasma Treatment Effect on Graphene Sheeted Vertically Aligned Carbon Nanofibers

Nitrogen plasma treatment effect on GS-CNFs （graphene seeted vertically aligned carbon nanofibers） has been studied. GS-CNFs were grown on nickel coated cupper substrates by DC-plasma CVD （chemical vapor deposition） at relatively low temperature. GS-CNFs were studied by SEM （scanning electron microscopy）, HR-TEM （high-resolution transmission electron microscopy）, XPS and Raman measurements. GS-CNFs are composed of cylindrical shaped having pure graphite sheets with about 5 μm length and nanometer size tips and roots diameter. Nitrogen plasma treatment causes nitrogen chemical etching on the graphene seeted carbon nanofibers were disordered its fine shape and increase the graphetization due to nitrogen incorporation.

Selective suspension of single layer graphene mechanochemically exfoliated from carbon nanofibres

This paper presents the first report of the successful ball-milling exfoliation of graphitic filaments （GANF~ carbon nanofibres） into single layer graphene. The addition of small amounts of solvent during the milling process makes it possible to enhance the intercalation of the exfoliating agent （melamine） between the graphene layers, thus promoting exceptional exfoliation. Advantage has also been taken of the fact that the Hansen solubility parameters of graphene are different from those of carbon fibres, which allows single and few-layer graphene to be suspended in a particular solvent, thus discriminating them from poorly exfoliated carbon nanofibres.

Probing the Young＇s modulus and Poisson＇s ratio in graphene/metal interfaces and graphite： A comparative study

By analyzing phonon dispersion, we have evaluated the average Young＇s modulus and Poisson＇s ratio in graphite and in graphene grown on Ru（0001）, Pt（111）, Ir（111）, Ni（111）, and BC3/NbB2（0001）. In both flat and corrugated graphene sheets and in graphite, we find a Poisson＇s ratio of 0.19 and a Young＇s modulus of 342 N/m. The unique exception is graphene/Ni（111）, for which we find different values because of the stretching of C-C bonds occurring in the commensurate overstructure （0.36 and 310 N/m for the Poisson＇s ratio and Young＇s modulus, respectively）. Such findings are in excellent agreement with calculations performed for a free-standing graphene membrane. The high crystalline quality of graphene grown on metal substrates leads to macroscopic samples with high tensile strength and bending flexibility for use in technological applications such as electromechanical devices and carbon-fiber reinforcements.