Calcium carbonate,which is widely employed as a filler added into the polymer matrix,has large numbers of applications owing to the excellent properties such as low cost,non-toxicity,high natural reserves and biocompa...Calcium carbonate,which is widely employed as a filler added into the polymer matrix,has large numbers of applications owing to the excellent properties such as low cost,non-toxicity,high natural reserves and biocompatibility.Nevertheless,in order to obtain the good filling effect,calcium carbonate needs to be surface modified by organic molecules so as to enhance the dispersion and compatibility within the composites.This review paper systematically introduces the theory,methods,and applications progress of calcium carbonate with surface modification.Additionally,the key factors that affect the properties of the composites as well as the current difficulties and challenges are highlighted.The current research progress and potential application prospects of calcium carbonate in the fields of plastics,rubber,paper,medicine and environmental protection are discussed as well.Generally,this review can provide valuable reference for the modification and comprehensive utilization of calcium carbonate.展开更多
This paper concerns the bond strength of FRP bars in AAC by the concentric pullout test. Specimens were subjected to compare with mild steel bars. The bond performance including the mode of failure and bond strength w...This paper concerns the bond strength of FRP bars in AAC by the concentric pullout test. Specimens were subjected to compare with mild steel bars. The bond performance including the mode of failure and bond strength was investigated with varying embedment length and surface treatment. Regarding the bond performance, embedment depth has influenced on bond strength as well as the sanded surface. Carbon fiber reinforced polymer （CFRP） pronounced the most promising results with the highest bond strength attained.展开更多
Carbon fiber composites have high strength, high stiffness and light weight characteristics to apply to many fields, such as leisure, energy and transportation industries. The CFRP （carbon fiber reinforced polymers/p...Carbon fiber composites have high strength, high stiffness and light weight characteristics to apply to many fields, such as leisure, energy and transportation industries. The CFRP （carbon fiber reinforced polymers/plastics） composites made of carbon fibers as reinforcement and epoxy resins as matrix were prepared by drum winding process. Various parameters such as molding temperature, molding pressure and pressing time were selected as the pre-pregs were laminated to be the CFRP. The effects of fabricating parameters which affected the mechanical properties of CFRPs were analyzed by Taguchi method in this study. The results showed that molding temperature was the main factor to influence the mechanical properties of composites.展开更多
In this paper, the strengthening of thin-walled metallic shells with the application of CFRP （carbon fibre reinforced polymer） has been investigated. To lower down the downside of the lower stiffness exhibited by CF...In this paper, the strengthening of thin-walled metallic shells with the application of CFRP （carbon fibre reinforced polymer） has been investigated. To lower down the downside of the lower stiffness exhibited by CFRP shells and to diminish the major problem associated with steel shells, a new composite sandwich structure has been introduced in this paper and effect of CFRP reinforcements under axial compression has been studied through three kinds of analytical procedures; the linear Eigen value problem, the modified RS （reduced stiffness） analysis and the fully nonlinear numerical experiment. With these multiple treatments it has been suggested that recently developed modified RS analysis which effectively compute the lower bounds provides the significant information to evaluate the buckling capacity of reinforced shells that display the unstable behaviour and imperfection-sensitivity than the general RS Analysis. This paper also illustrates the application of the methodology to cases of axial loaded shells with the varying thickness of veneers of CFRP.展开更多
In this work, we demonstrate a new kind of Pt-free counter electrode for dye-sensitized solar cells(DSCs). Polypyrrole-cobalt-carbon(PPY-Co-C) nanocomposites, with the advantages of low cost and simple preparation, sh...In this work, we demonstrate a new kind of Pt-free counter electrode for dye-sensitized solar cells(DSCs). Polypyrrole-cobalt-carbon(PPY-Co-C) nanocomposites, with the advantages of low cost and simple preparation, show favorable catalytic activity in promoting tri-iodide reduction. The DSC composed of the PPY-Co-C nanocomposite electrode exhibits an acceptable energy conversion efficiency of 6.01%, a considerable short-circuit photocurrent of 15.33 mA cm-2, and a low charge-transfer resistance of 1.5 Ω cm2. The overall performance of PPY-Co-C is superior to the carbon counterparts and comparable with the platinum reference, rendering them efficient and promising counter electrode materials for DSCs.展开更多
Carbon fiber reinforced polymer(CFRP)has many remarkable merits.It is lightweight and has great rigidity and high intensity. High-durability cable produced from CFRP as reinforcement material is widely used in bridge ...Carbon fiber reinforced polymer(CFRP)has many remarkable merits.It is lightweight and has great rigidity and high intensity. High-durability cable produced from CFRP as reinforcement material is widely used in bridge construction projects.However, there is a dearth of studies regarding damage types and mechanism under fatigue load of CFRP bridge cables.In this paper,we adopt acoustic emission(AE)technology to monitor fatigue damage and failure of the CFRP bridge cables,specifically by monitoring the bridge cable’s fatigue test process and using wavelet transformation to analyze data.Results show that damage on the CFRP cable is divided into three stages.Based on wavelet singularity theory,in each stage of AE,the burst signal is obtained and its time-frequency distribution is achieved through wavelet analysis.According to the analysis results,failure modes in each phase and type of acoustic emission source are easy to determine.The characteristics of waveform,types of damages, and frequency distribution of CFRP bridge cable in different damage phases are collected.Research shows that the method used to determine the types of fatigue damage on the CFRP cable is feasible according to the range of distribution characteristic parameters for acoustic emission signal and type of waveform.展开更多
Nitrogen-doped carbon nanotubes (N-CNTs)/polyaniline (PANI) composites are developed as an electrode material for biosensors. The morphology, composition, and optical properties of the resulting products were characte...Nitrogen-doped carbon nanotubes (N-CNTs)/polyaniline (PANI) composites are developed as an electrode material for biosensors. The morphology, composition, and optical properties of the resulting products were characterized by transmission electron microscopy (TEM), thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FT-IR), and ultraviolet-visible absorption spectra (UV-vis). Furthermore, N-CNTs/PANI composite was immobilized on the surface of a glassy carbon electrode (GCE) and applied to construct a sensor. The obtained N-CNTs/PANI-modified GCE showed one pair of redox peaks and high catalytic activity for the oxidation of dopamine (DA) in a neutral environment. Differential pulse voltam-mograms results illustrate that the fabricated DA biosensor has high anti-interference ability towards ascorbic acid (AA). In addition, the fabricated biosensor showed superior performances with two wide linear ranges from 1 to 80 μM and from 1.5 to 3.5 mM and a low detection limit of 0.01 μM.展开更多
基金Project(AA18242008)supported by the Guangxi Science&Technology Major Project,ChinaProject(HZXYKFKT201904)supported by the Opening Project of Guangxi Key Laboratory of Calcium Carbonate Resources Comprehensive Utilization,China。
文摘Calcium carbonate,which is widely employed as a filler added into the polymer matrix,has large numbers of applications owing to the excellent properties such as low cost,non-toxicity,high natural reserves and biocompatibility.Nevertheless,in order to obtain the good filling effect,calcium carbonate needs to be surface modified by organic molecules so as to enhance the dispersion and compatibility within the composites.This review paper systematically introduces the theory,methods,and applications progress of calcium carbonate with surface modification.Additionally,the key factors that affect the properties of the composites as well as the current difficulties and challenges are highlighted.The current research progress and potential application prospects of calcium carbonate in the fields of plastics,rubber,paper,medicine and environmental protection are discussed as well.Generally,this review can provide valuable reference for the modification and comprehensive utilization of calcium carbonate.
文摘This paper concerns the bond strength of FRP bars in AAC by the concentric pullout test. Specimens were subjected to compare with mild steel bars. The bond performance including the mode of failure and bond strength was investigated with varying embedment length and surface treatment. Regarding the bond performance, embedment depth has influenced on bond strength as well as the sanded surface. Carbon fiber reinforced polymer （CFRP） pronounced the most promising results with the highest bond strength attained.
文摘Carbon fiber composites have high strength, high stiffness and light weight characteristics to apply to many fields, such as leisure, energy and transportation industries. The CFRP （carbon fiber reinforced polymers/plastics） composites made of carbon fibers as reinforcement and epoxy resins as matrix were prepared by drum winding process. Various parameters such as molding temperature, molding pressure and pressing time were selected as the pre-pregs were laminated to be the CFRP. The effects of fabricating parameters which affected the mechanical properties of CFRPs were analyzed by Taguchi method in this study. The results showed that molding temperature was the main factor to influence the mechanical properties of composites.
文摘In this paper, the strengthening of thin-walled metallic shells with the application of CFRP （carbon fibre reinforced polymer） has been investigated. To lower down the downside of the lower stiffness exhibited by CFRP shells and to diminish the major problem associated with steel shells, a new composite sandwich structure has been introduced in this paper and effect of CFRP reinforcements under axial compression has been studied through three kinds of analytical procedures; the linear Eigen value problem, the modified RS （reduced stiffness） analysis and the fully nonlinear numerical experiment. With these multiple treatments it has been suggested that recently developed modified RS analysis which effectively compute the lower bounds provides the significant information to evaluate the buckling capacity of reinforced shells that display the unstable behaviour and imperfection-sensitivity than the general RS Analysis. This paper also illustrates the application of the methodology to cases of axial loaded shells with the varying thickness of veneers of CFRP.
基金supported by the National Basic Research Program of China(2011CBA00702)the National Natural Science Foundation of China(21322101)+1 种基金Ministry of Education(B12015,113016A,ACET-13-0296)the Fundamental Research Funds for the Central Universities
文摘In this work, we demonstrate a new kind of Pt-free counter electrode for dye-sensitized solar cells(DSCs). Polypyrrole-cobalt-carbon(PPY-Co-C) nanocomposites, with the advantages of low cost and simple preparation, show favorable catalytic activity in promoting tri-iodide reduction. The DSC composed of the PPY-Co-C nanocomposite electrode exhibits an acceptable energy conversion efficiency of 6.01%, a considerable short-circuit photocurrent of 15.33 mA cm-2, and a low charge-transfer resistance of 1.5 Ω cm2. The overall performance of PPY-Co-C is superior to the carbon counterparts and comparable with the platinum reference, rendering them efficient and promising counter electrode materials for DSCs.
基金supported by the National Natural Science Foundation of China(Grant No.50808030)the Doctoral Fund of Ministry of Education of China(Grant No.200801411102)
文摘Carbon fiber reinforced polymer(CFRP)has many remarkable merits.It is lightweight and has great rigidity and high intensity. High-durability cable produced from CFRP as reinforcement material is widely used in bridge construction projects.However, there is a dearth of studies regarding damage types and mechanism under fatigue load of CFRP bridge cables.In this paper,we adopt acoustic emission(AE)technology to monitor fatigue damage and failure of the CFRP bridge cables,specifically by monitoring the bridge cable’s fatigue test process and using wavelet transformation to analyze data.Results show that damage on the CFRP cable is divided into three stages.Based on wavelet singularity theory,in each stage of AE,the burst signal is obtained and its time-frequency distribution is achieved through wavelet analysis.According to the analysis results,failure modes in each phase and type of acoustic emission source are easy to determine.The characteristics of waveform,types of damages, and frequency distribution of CFRP bridge cable in different damage phases are collected.Research shows that the method used to determine the types of fatigue damage on the CFRP cable is feasible according to the range of distribution characteristic parameters for acoustic emission signal and type of waveform.
基金supported by the National Natural Science Foundation of China (20905038, 20903057, 20974046, 50803027, 20874048 & 20804020)the National Basic Research Program of China (2009CB930600)+1 种基金the Natural Science Foundation of Jiangsu Province (08KJB150011 & 09KJB150007)the Fok Ying-Tong Education Foundation under Grant 111051
文摘Nitrogen-doped carbon nanotubes (N-CNTs)/polyaniline (PANI) composites are developed as an electrode material for biosensors. The morphology, composition, and optical properties of the resulting products were characterized by transmission electron microscopy (TEM), thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FT-IR), and ultraviolet-visible absorption spectra (UV-vis). Furthermore, N-CNTs/PANI composite was immobilized on the surface of a glassy carbon electrode (GCE) and applied to construct a sensor. The obtained N-CNTs/PANI-modified GCE showed one pair of redox peaks and high catalytic activity for the oxidation of dopamine (DA) in a neutral environment. Differential pulse voltam-mograms results illustrate that the fabricated DA biosensor has high anti-interference ability towards ascorbic acid (AA). In addition, the fabricated biosensor showed superior performances with two wide linear ranges from 1 to 80 μM and from 1.5 to 3.5 mM and a low detection limit of 0.01 μM.
