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数字石化化工与碳安全
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作者 徐晨光 张燕 +1 位作者 杨彦 纪红兵 《化工进展》 EI CAS CSCD 北大核心 2024年第10期5339-5352,F0004,共15页
第二十八届联合国气候变化大会(COP28)要求本十年结束前加大气候行动力度,实现将全球气温升幅限制在1.5℃以内的总体目标。石化化工行业作为重要碳排放来源,数字化转型被认为提供了降低碳排放、提升碳效率的新途径。数字化技术的应用已... 第二十八届联合国气候变化大会(COP28)要求本十年结束前加大气候行动力度,实现将全球气温升幅限制在1.5℃以内的总体目标。石化化工行业作为重要碳排放来源,数字化转型被认为提供了降低碳排放、提升碳效率的新途径。数字化技术的应用已经在石化化工行业中逐步展开,数字化与双碳的紧密结合促进了石化化工的绿色高效发展。本文从数字化与碳安全两方面入手,首先通过数字化技术在石化化工的应用实例分析了数字化技术结合低碳发展的优势与问题,率先提出石化化工碳链理论,即数字化与双碳目标的有机结合,认为工业碳链中碳工程给出了石化化工低碳发展的路径,是践行新质生产力重要举措。从政策要求、能源挑战和产品出口等3个维度进行了分析石化化工的碳安全。 展开更多
关键词 石化化工 数字化转型 化工产业链核算 碳负荷 工业链理论
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考虑电能使用行为的用户碳画像研究
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作者 郑杨 王雨薇 +3 位作者 徐丁吉 邓士伟 李莹莹 陈星瑞 《电力需求侧管理》 2024年第2期100-106,共7页
随着我国提出“碳达峰、碳中和”的双碳建设目标,节能减碳成为当下的热点问题。用户碳画像对电力公司分析居民用户的电能使用行为,制定合理的电能减碳调控措施具有重要意义。为此,对基于电能使用行为的用户碳画像标签体系和画像方法进... 随着我国提出“碳达峰、碳中和”的双碳建设目标,节能减碳成为当下的热点问题。用户碳画像对电力公司分析居民用户的电能使用行为,制定合理的电能减碳调控措施具有重要意义。为此,对基于电能使用行为的用户碳画像标签体系和画像方法进行研究。首先对用户多维用能数据进行搜集和筛选;然后根据筛选后的用户电能使用行为数据,结合画像目的,从用户减碳负荷特性、用户低碳用电特性、用户电能产消碳特性3个维度设计用户碳画像的标签体系;再将子标签进行数据处理并对各类综合指标分析得到各维标签数据。最后通过使用k-means聚类算法判断并确定用户的所属簇别,以三维散点图进行展示;再根据标签体系计算获得用户的减碳综合指数并以柱状图进行展示,实现了用户碳画像的可视化呈现,反映了用户电能减碳的综合能力;通过选取典型用户对比实施减碳措施前后的碳排放量,验证了所提方法的有效性。 展开更多
关键词 画像 碳负荷特性 用电特性 电能产消特性 K-MEANS聚类算法
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不同碳负荷梯度下稻田土壤有机碳矿化特征 被引量:1
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作者 童瑶瑶 王季斐 +5 位作者 祝贞科 邓扬悟 陈珊 葛体达 袁红朝 吴金水 《环境科学》 EI CAS CSCD 北大核心 2019年第3期1483-1490,共8页
易利用态有机碳是土壤微生物的重要碳源,影响土壤有机碳的矿化和累积过程,而易利用态碳源的输入量尤其是相对于土壤微生物生物量碳的不同输入负荷,对土壤有机碳的矿化影响机制尚不明确.因此,本研究采取室内模拟培养实验,选择不同浓度梯... 易利用态有机碳是土壤微生物的重要碳源,影响土壤有机碳的矿化和累积过程,而易利用态碳源的输入量尤其是相对于土壤微生物生物量碳的不同输入负荷,对土壤有机碳的矿化影响机制尚不明确.因此,本研究采取室内模拟培养实验,选择不同浓度梯度添加[0. 5、1、3、5倍微生物量碳(MBC)]^(13)C-葡萄糖,分析葡萄糖-C的矿化特征及其激发效应.结果表明,葡萄糖-C矿化率随着外源碳添加量的增加而显著增加;葡萄糖-C向快库、慢库分配的比例也分别与碳添加量呈指数关系(R^2=0. 99,P <0. 05和R^2=0. 99,P <0. 05).在高添加量处理(3×MBC、5×MBC)中,葡萄糖的添加抑制土壤原有有机碳的矿化,即表现出负激发效应;而在低添加量处理(0. 5×MBC、1×MBC)中,表现为正激发效应,60 d培养结束后累积激发效应分别为160. 0 mg·kg^(-1)和325. 1 mg·kg^(-1).相关性分析结果表明在培养实验前期,累积激发效应主要受MBC、MBN和DOC的影响,而在后期主要β-葡糖苷酶、几丁质酶和铵态氮的影响.因此,稻田土壤有机碳矿化和激发效应与易利用态有机碳添加的碳负荷密切相关,并通过微生物量和酶活性调控土壤碳的矿化过程.本研究对于揭示稻田有机碳累积行为与推动农业可持续发展具有重要的科学意义. 展开更多
关键词 水稻土 固持 易利用态 碳负荷 13C同位素示标记 激发效应
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双碳目标下含P2G与需求响应的综合能源系统双层优化 被引量:20
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作者 黄文轩 刘道兵 +3 位作者 李世春 李伟锋 鲍志阳 袁野 《电测与仪表》 北大核心 2022年第11期8-17,共10页
在“双碳”目标背景下,对能源系统节能与减排提出了更高的要求。综合能源系统(IES)作为能源系统节能减排的主要载体,为深度发挥IES中用户侧与社区运营商的减排能力,文中提出将用户侧参与需求响应的负荷分为刚性负荷、价格型敏感负荷与... 在“双碳”目标背景下,对能源系统节能与减排提出了更高的要求。综合能源系统(IES)作为能源系统节能减排的主要载体,为深度发挥IES中用户侧与社区运营商的减排能力,文中提出将用户侧参与需求响应的负荷分为刚性负荷、价格型敏感负荷与碳价型敏感负荷,并在社区运营商中增设P2G设备。在此基础上,建立了用户与IES运营商参与的双主体阶梯碳交易机制,并建立双层优化模型。上层模型为IES运营商运营收益最大,下层模型为用户侧受到园区内碳价与分时能源价格下的用能费用最小。与传统优化模型相比,用户侧行为不仅受到能源价格影响,还受到碳交易价格的影响。此外分析敏感型负荷对需求响应的影响,需求响应及P2G联合优化在IES上的节能减排优势。最后通过4种情境下的仿真,验证了所提模型的有效性。 展开更多
关键词 价格型敏感负荷 价型敏感负荷 P2G 需求响应 双层优化
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Behavior of preloaded RC beams strengthened with CFRP laminates 被引量:1
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作者 张爱晖 金伟良 李贵炳 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2006年第3期436-444,共9页
Eighteen reinforced concrete beams, including 16 beams strengthened with CFRP laminate at different levels of preload and 2 control beams, were tested to investigate the influence of preload level on flexural behavior... Eighteen reinforced concrete beams, including 16 beams strengthened with CFRP laminate at different levels of preload and 2 control beams, were tested to investigate the influence of preload level on flexural behavior of CFRP-strengthened RC beam. The experimental parameters include rebar ratios, number of plies of CFRP laminates and preload level at the time of strengthening. Theoretical analysis was also carried out to explain the experimental phenomena and results. The experimental and theoretical results indicated that the preload level has more influence on the stiffness and deflection of the strengthened beam, both at post-cracking and post-yielding stage, than that on the yielding and ultimate flexural strength of the strengthened beam. The main failure mode of CFRP-strengthened beam is the intermediate crack-induced debonding of CFRP laminates, provided that the development length of CFRP laminates and shear capacity of the beam are sufficient. 展开更多
关键词 BEAM STRENGTHEN CFRP Flexural behavior Preload level
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Simulation of CO_2 Brayton Cycle for Engine Exhaust Heat Recovery under Various Operating Loads 被引量:2
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作者 舒歌群 张承宇 +3 位作者 田华 高媛媛 李团兵 仇荣赓 《Transactions of Tianjin University》 EI CAS 2015年第3期193-198,共6页
A bottoming cycle system based on CO2 Brayton cycle is proposed to recover the engine exhaust heat. Its performance is compared with the conventional air Brayton cycle under five typical engine conditions. The results... A bottoming cycle system based on CO2 Brayton cycle is proposed to recover the engine exhaust heat. Its performance is compared with the conventional air Brayton cycle under five typical engine conditions. The results show that CO2 Brayton cycle proves to be superior to the air Brayton cycle in terms of the system net output power, thermal efficiency and recovery efficiency. In most cases, the recovery efficiency of CO2 Brayton cycle can be higher than 9% and the system has a better performance at the engine's high operating load, The thermal efficiency can be as large as 24.83% under 100% olaerating load, accordingly, the net outnut nower of 14.86 kW in nhtnined 展开更多
关键词 CO2 Brayton cycle waste heat recovery
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低碳技术组合应用下纵向合作减排的随机微分对策模型 被引量:8
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作者 黄守军 陈其安 任玉珑 《中国管理科学》 CSSCI 北大核心 2015年第12期94-104,共11页
在低碳电力调度准则下,基于考虑减排技术及其协同效应对低碳负荷需求的影响与电网公司购电的有限理性学习过程,建立了发电商采用3种低碳技术组合应用时的纵向合作减排的随机微分对策模型。运用汉密尔顿-雅可比-贝尔曼方程分别求得了Stac... 在低碳电力调度准则下,基于考虑减排技术及其协同效应对低碳负荷需求的影响与电网公司购电的有限理性学习过程,建立了发电商采用3种低碳技术组合应用时的纵向合作减排的随机微分对策模型。运用汉密尔顿-雅可比-贝尔曼方程分别求得了Stackelberg博弈和合作博弈下均衡的减排技术投入、稳定的购电电量期望与方差以及Stackelberg博弈下最优的减排支付比例。考察了发电商减排技术的对称性及其应用数量对反馈均衡结果的影响,并对此两种博弈结构进行了比较分析。运用基于双向加权Rubinstein-Stahl讨价还价模型的利润共享契约使得决策系统达到协调,并将模型拓展到多种减排技术投入下的合作减排模型。研究发现:在一定条件和范围内,减排投入提高电网公司购电电量,同时发电商为此所带来的风险增大;合作博弈更适于优化电力市场电源结构,顺应低碳电力调度政策的导向;最优的减排技术应用、稳定的购电电量期望与方差以及系统均衡利润都与发电商选择的低碳技术投资效率、技术之间的协同作用以及数量正相关。 展开更多
关键词 碳负荷需求 合作减排 随机微分对策 STACKELBERG博弈 合作博弈 汉密尔顿-雅可比-贝尔曼方程
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Thermal-mechanical properties of short carbon fiber reinforced geopolymer matrix composites subjected to thermal load 被引量:4
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作者 林铁松 贾德昌 +1 位作者 何培刚 王美荣 《Journal of Central South University》 SCIE EI CAS 2009年第6期881-886,共6页
Short carbon fiber preform reinforced geopolymer composites containing different contents of α-Al2O3 filler (Cr(a-Al2O3)/geopolymer composites) were fabricated, and the effects of heat treatment temperatures up t... Short carbon fiber preform reinforced geopolymer composites containing different contents of α-Al2O3 filler (Cr(a-Al2O3)/geopolymer composites) were fabricated, and the effects of heat treatment temperatures up to 1 200 ℃ on the thermal-mechanical properties were studied. The results show that the thermal shrinkage in the direction perpendicular to the lamination of the composites gradually increases with the increase of the heat treatment temperatures from room temperature (25 ℃ ) to 1000 ℃. However, the composites in the direction parallel to the lamination show an expansion behavior. Beyond 1 000℃, in the two directions the composites exhibit a larger degree of shrinkage due to the densification and crystallization. The mechanical properties of the composites show the minimum values in the temperature range from 600 to 800 ℃ as the hydration water of geopolymer matrix is lost. The addition of α-Al2O3 particle filler into the composites clearly increases the onset crystalline temperature of leucite (KAlSi2O6) from the amorphous geopolymer matrix. In addition, the addition of α-Al2O3 particles into the composites can not only help to keep volume stable at high temperatures but also effectively improve the mechanical properties of the composites subjected to thermal load to a certain extent. The main toughening mechanisms of the composites subjected to thermal load are attributed to fiber pulling-out. 展开更多
关键词 short carbon fiber Α-AL2O3 thermal-mechanical properties GEOPOLYMER thermal load
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Gross Pollutants Study in Urban Areas under Tropical Climates
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作者 Lariyah Mohd Sidek Hidayah Basri +3 位作者 Mohamed Roseli Zainal Abidin Lira Chow Hock Md Nasir Md Nor Nor Azazi Zakaria 《Journal of Civil Engineering and Architecture》 2014年第1期107-114,共8页
Gross pollutants are the primary targeted pollutants in urban catchment management for urban water quality improvement as well as mitigation of flood. Apart from aesthetically unattractive because of its visibility, g... Gross pollutants are the primary targeted pollutants in urban catchment management for urban water quality improvement as well as mitigation of flood. Apart from aesthetically unattractive because of its visibility, gross pollutants also contributes to degradation of river water quality and loss of aquatic habitat as it carries harmful pollutants such as oxygen demanding material, hydrocarbons and heavy metals. This study analyzed trend of gross pollutant generated from two urban residential areas located in Selangor, Malaysia. The median value of gross pollutant load obtained fi'om the Amanah Apartment and Bandar Botanic are 347.41 kg/ha/year and 32.46 kg/ha/year, respectively. Relationship between gross pollutant wet load with rainfall depths was derived using regression equation. A significant trend of increasing gross pollutant wet load into drainage system with increasing rainfall depth was observed. The behavior of pollutant load is related to the one observed in Australia. 展开更多
关键词 Gross pollutant load urban stormwater quality urban stormwater management.
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Combined torsional buckling of double-walled carbon nanotubes with axial load in the multi-field coupled condition 被引量:2
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作者 SUN YuGang YAO XiaoHu HAN Qiang 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2011年第9期1659-1665,共7页
The present study has theoretically investigated the combined torsional buckling of double-walled carbon nanotubes (DWCNTs) with axial load in the multi-field coupled condition. The effects of torsion, axial load, the... The present study has theoretically investigated the combined torsional buckling of double-walled carbon nanotubes (DWCNTs) with axial load in the multi-field coupled condition. The effects of torsion, axial load, thermal-electrical change, surrounding elastic medium and the Van der Waals forces are all taken into consideration. The governing equation of buckling for CNTs subjected to thermo-electro-mechanical loadings has been established based on an elastic shell model of continuum mechanics. Reasonable simplifications are made to get the explicit expression of the critical buckling shear stress of DWCNTs, and numerical experiments are conducted for further research. It is shown that under certain electric and temperature field the critical buckling shear stress of DWCNTs only depends on the wave number of buckling modes. On the other hand, all the related impact factors have enormous influence on the critical buckling shear stress under a certain buckling mode. The critical buckling shear stress changes linearly with the axial-to-shear stress ratio, as well as the thermal and electric change. Axial compression tends to make DWCNTs unstable, while axial tension benefits the buckling stability. The critical buckling shear stress is directly proportional to the applied voltage. At room or lower temperature, the critical shear stress for infinitesimal buckling increases as the temperature change increases, while it decreases at a higher temperature. The conclusions are useful for the design of nano-structures related to the buckling stability of DWCNTs. 展开更多
关键词 Carbon nanotubes BUCKLING multi-field coupling
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