流化床内CaO循环碳酸盐化/煅烧实验研究

以石灰石为吸收剂在流化床反应器内对CaO循环吸收CO2以及循环煅烧特性进行了实验研究.结果表明:当吸收温度为650℃时,在稳定吸收阶段,反应器出口气体中CO2体积分数不超过3%,表明CaO吸收剂在流化床内能有效吸收CO2.随循环反应次数的增加,CaO吸收剂循环反应活性下降,使得稳定吸收CO2阶段所持续的时间随循环次数的增加而减少.CaO吸收剂比表面积和孔隙率随循环反应次数的增加而减少,因此会导致CaO转化率随循环次数的增加而快速降低.

Cyclic metallurgical process for extracting V and Cr from vanadium slag: Part Ⅱ. Separation and recovery of Cr from vanadium precipitated solution

Cyclic metallurgical process for separation and recovery of Cr from vanadium precipitated solution by precipitation with PbCO_(3)and leaching with Na_(2)CO_(3)was investigated.The concentration of Cr residue in the solution decreases from 2.360 to 0.001 g/L by adding PbCO_(3)into vanadium precipitated solution according to Pb/Cr molar ratio of 2.5,adjusting the pH to 3.0 and stirring for 180 min at 30℃.Then,the precipitates were leached with hot Na_(2)CO_(3)solution to obtain leaching solution containing Na_(2)CrO_(4)and leaching residue containing PbCO_(3).The leaching efficiency of Cr reaches 96.43%by adding the precipitates into 0.5 mol/L Na_(2)CO_(3)solution with the mass ratio of liquid to solid(L/S)of 10:1 mL/g and stirring for 60 min under pH 9.5 at 70℃.After filtration,leaching residue is reused in Cr precipitation and leaching solution is used to circularly leach the Cr precipitates until Na_(2)CrO_(4)approaches the saturation.Finally,the product of Na_(2)CrO_(4)·4H_(2)O is obtained by evaporation and crystallization of leaching solution.

Cyclic metallurgical process for extracting Ⅴ and Cr from vanadium slag: Part Ⅰ. Separation and recovery of Ⅴ from chromium-containing vanadate solution

The separation and recovery of V from chromium-containing vanadate solution were investigated by a cyclic metallurgical process including selective precipitation of vanadium,vanadium leaching and preparation of vanadium pentoxide.By adding Ca(OH)_(2) and ball milling,not only the V in the solution can be selectively precipitated,but also the leaching kinetics of the precipitate is significantly improved.The precipitation efficiency of V is 99.59%by adding Ca(OH)_(2) according to Ca/V molar ratio of 1.75:1 into chromium-containing vanadate solution and ball milling for 60 min at room temperature,while the content of Cr in the precipitate is 0.04%.The leaching rate of V reaches 99.35%by adding NaHCO_(3) into water according to NaHCO_(3)/V molar ratio of 2.74:1 to leach V from the precipitate with L/S ratio of 4:1 mL/g and stirring for 60 min at room temperature.The crystals of NH_(4)VO_(3) are obtained by adjusting the leaching solution pH to be 8.0 with CO2 and then adding NH_(4)HCO_(3) according to NH_(4)HCO_(3)/NaVO_(3) molar ratio of 1:1 and stirring for 8 h at room temperature.After filtration,the crystallized solution containing ammonia is reused to leach the precipitate of calcium vanadates,and the leaching efficiency of V is>99%after stirring for 1 h at room temperature.Finally,the product of V_(2)O_(5) with purity of 99.6%is obtained by calcining the crystals at 560℃ for 2 h.

Paleoceanographic records in the sedimentary cores from the middle Okinawa Trough

Two gravity piston cores (Cores 155 and 180) involved in this study were collected from the middle Okinawa Trough. Stratigraphy of the two cores was divided and classified based on the features of planktonic foraminifera oxygen isotope changes together with depositional sequence,millennium-scale climatic event comparison, carbonate cycles and AMS^14C dating. Some paleoclimatic information contained in sediments of these cores was extracted to discuss the paleoclimatic change rules and the short-time scale events presented in interglacial period. Analysis on the variation of oxygen isotope values in stage two shows that the middle part of the Okinawa Trough may have been affected by fresh water from the Yellow River and the Yangtze River during the Last Glacial Maximum (LGM). The oxygen isotope value oscillating ranges of the cores have verified that the marginal sea has an amplifying effect on climate changes.The δ^13C of benthic foraminifera Uvigerina was lighter in the glacial period than that in the interglacial period, which indicates that the Paleo-Kuroshio's main stream moved eastward and its influence area decreased. According to the temperature difference during the “YD” period existing in Core 180 and other data, we can reach the conclusion that the climatic changes in the middle Okinawa Trough area were controlled by global climatic changes, but some regional factors had also considerable influence on the climatechanges. Some results in this paper support Fairbanks's point that the “YD” event was a brief stagnation of sea level rising during the global warming up procession. Moreover,the falling of sea level in the glacial period weakened the exchange between the bottom water of the Okinawa Trough and the deep water of the northwestern Pacific Ocean and resulted in low oxygen state of bottom water in this area.These procedures are the reasons for carbonate cycle in the Okinawa Trough area being consistent with the “Atlantic type”carbonate cycle.

Formation time of the big mantle wedge beneath eastern China and a new lithospheric thinning mechanism of the North China craton—Geodynamic effects of deep recycled carbon

High-resolution P wave tomography shows that the subducting Pacific slab is stagnant in the mantle transition zone and forms a big mantle wedge beneath eastern China. The Mg isotopic investigation of large numbers of mantle-derived volcanic rocks from eastern China has revealed that carbonates carried by the subducted slab have been recycled into the upper mantle and formed carbonated peridotite overlying the mantle transition zone, which becomes the sources of various basalts. These basalts display light Mg isotopic compositions(δ26 Mg = –0.60‰ to –0.30‰) and relatively low87 Sr/86 Sr ratios(0.70314–0.70564) with ages ranging from 106 Ma to Quaternary, suggesting that their mantle source had been hybridized by recycled magnesite with minor dolomite and their initial melting occurred at 300-360 km in depth. Therefore, the carbonate metasomatism of their mantle source should have occurred at the depth larger than 360 km, which means that the subducted slab should be stagnant in the mantle transition zone forming the big mantle wedge before 106 Ma. This timing supports the rollback model of subducting slab to form the big mantle wedge. Based on high P-T experiment results, when carbonated silicate melts produced by partial melting of carbonated peridotite was raising and reached the bottom(180–120 km in depth) of cratonic lithosphere in North China, the carbonated silicate melts should have 25–18 wt% CO2 contents, with lower Si O2 and Al2 O3 contents, and higher Ca O/Al2 O3 values, similar to those of nephelinites and basanites, and have higher εNdvalues(2 to 6). The carbonatited silicate melts migrated upward and metasomatized the overlying lithospheric mantle, resulting in carbonated peridotite in the bottom of continental lithosphere beneath eastern China. As the craton lithospheric geotherm intersects the solidus of carbonated peridotite at 130 km in depth, the carbonated peridotite in the bottom of cratonic lithosphere should be partially melted, thus its physical characters are similar to the asthenosphere and it could be easily replaced by convective mantle. The newly formed carbonated silicate melts will migrate upward and metasomatize the overlying lithospheric mantle. Similarly, such metasomatism and partial melting processes repeat, and as a result the cratonic lithosphere in North China would be thinning and the carbonated silicate partial melts will be transformed to high-Si O2 alkali basalts with lower εNdvalues(to-2). As the lithospheric thinning goes on,initial melting depth of carbonated peridotite must decrease from 130 km to close 70 km, because the craton geotherm changed to approach oceanic lithosphere geotherm along with lithospheric thinning of the North China craton. Consequently, the interaction between carbonated silicate melt and cratonic lithosphere is a possible mechanism for lithosphere thinning of the North China craton during the late Cretaceous and Cenozoic. Based on the age statistics of low δ26 Mg basalts in eastern China, the lithospheric thinning processes caused by carbonated metasomatism and partial melting in eastern China are limited in a timespan from 106 to25 Ma, but increased quickly after 25 Ma. Therefore, there are two peak times for the lithospheric thinning of the North China craton: the first peak in 135-115 Ma simultaneously with the cratonic destruction, and the second peak caused by interaction between carbonated silicate melt and lithosphere mainly after 25 Ma. The later decreased the lithospheric thickness to about70 km in the eastern part of North China craton.