Homogeneous(unseeded)precipitation of magnesium carbonate hydrates by the reaction of MgCl2 with Na2CO3 in supersaturated solutions between 273 and 363K was investigated.The compositions,morphologies and filtration ch...Homogeneous(unseeded)precipitation of magnesium carbonate hydrates by the reaction of MgCl2 with Na2CO3 in supersaturated solutions between 273 and 363K was investigated.The compositions,morphologies and filtration characteristics of the precipitates were studied in detail.The magnesium carbonate hydrates obtained at 313K and in the range of 343-363K showed good morphologies and filtration characteristics.Magnesium oxides(MgO)with high purity(97.6%-99.4%)were obtained by calcining magnesium carbonate hydrates at 1073K.展开更多
The membrane-based CO2 separation process has an advantage compared to traditional CO2 separation technologies. The membrane is the key of the membrane separation process. In this paper, preparation, characterization ...The membrane-based CO2 separation process has an advantage compared to traditional CO2 separation technologies. The membrane is the key of the membrane separation process. In this paper, preparation, characterization and laboratory testing of the membrane, which was prepared from sodium alginate, hydrogen bond cross-linked with sodium tartrate and used for CO2/N2 separation, were reported. The resistance to SO2 of the membrane was also investigated. The experimental results demonstrate that the membrane possesses a high resistance to SO2.Finally,based on experimental results, the economic feasibility of the membrane used for CO2/N2 separation was evaluated,indicating the two-stage membrane process can compete with the traditional chemical absorption method.展开更多
This article adopts the double decomposition method, select the appropriate experimental conditions and operation process, respectively add appropriate amount of sodium carboxymethyl cellulose （CMC） as crystal contr...This article adopts the double decomposition method, select the appropriate experimental conditions and operation process, respectively add appropriate amount of sodium carboxymethyl cellulose （CMC） as crystal control agent to study the influence of crystalline of ultrafine calcium carbonate. The experimental results show that the different concentrations of CMC as crystal control agent on the morphology and crystal structure of calcium carbonate have obvious effect, which emerge morphology change from square to spherical, crystalline transition from calcite to aragonite. Thus, the results provide experimental data and theoretical basis for the use of different additives, and provide experimental basis and feasible solution for this kind of reaction.展开更多
基金Supported by the National Natural Science Foundation of China （20876161） and the National Basic Research Program of China （2007CB613501, 2009CB219904）.
文摘Homogeneous(unseeded)precipitation of magnesium carbonate hydrates by the reaction of MgCl2 with Na2CO3 in supersaturated solutions between 273 and 363K was investigated.The compositions,morphologies and filtration characteristics of the precipitates were studied in detail.The magnesium carbonate hydrates obtained at 313K and in the range of 343-363K showed good morphologies and filtration characteristics.Magnesium oxides(MgO)with high purity(97.6%-99.4%)were obtained by calcining magnesium carbonate hydrates at 1073K.
基金Supported by the National Natural Science Foundation of China （20836006）, the National Basic Research Program （2009CB623405）, the Science ＆ Technology Pillar Program of Tianjin （10ZCKFSH01700）, the Programme of Introducing Talents of Discipline to Universities （B06006） and the Cheung Kong Scholar Program for Innovative Teams of the Ministry of Education （IRT064.1）.
文摘The membrane-based CO2 separation process has an advantage compared to traditional CO2 separation technologies. The membrane is the key of the membrane separation process. In this paper, preparation, characterization and laboratory testing of the membrane, which was prepared from sodium alginate, hydrogen bond cross-linked with sodium tartrate and used for CO2/N2 separation, were reported. The resistance to SO2 of the membrane was also investigated. The experimental results demonstrate that the membrane possesses a high resistance to SO2.Finally,based on experimental results, the economic feasibility of the membrane used for CO2/N2 separation was evaluated,indicating the two-stage membrane process can compete with the traditional chemical absorption method.
文摘This article adopts the double decomposition method, select the appropriate experimental conditions and operation process, respectively add appropriate amount of sodium carboxymethyl cellulose （CMC） as crystal control agent to study the influence of crystalline of ultrafine calcium carbonate. The experimental results show that the different concentrations of CMC as crystal control agent on the morphology and crystal structure of calcium carbonate have obvious effect, which emerge morphology change from square to spherical, crystalline transition from calcite to aragonite. Thus, the results provide experimental data and theoretical basis for the use of different additives, and provide experimental basis and feasible solution for this kind of reaction.
