In this paper, we first theoretically report the magnetic and magneto-opticalproperties in paramagnetic media under high external magnetic field. Considering the action of theexternal magnetic Geld H_e and indirect ex...In this paper, we first theoretically report the magnetic and magneto-opticalproperties in paramagnetic media under high external magnetic field. Considering the action of theexternal magnetic Geld H_e and indirect exchange interaction H_v, the characteristic of the magneticsaturation and the property of the Faraday rotation to be nonlinear with external magnetic Geld arepresented in paramagnetic NdF_3. In terms of our theory, the indirect exchange interaction plays auimportant role in the magnetization M and the Faraday rotation θ in NdF_3 under high externalmagnetic Geld. The theory is in good agreement with experimental results. On the other hand, areasonable explanation for the temperature dependence of the ratio of the Verdet constant to themagnetic susceptibility V/x is obtained.展开更多
Magnetic ion exchange(MIEX) resins have received considerable attention in drinking water treatment due to their fast and efficient removal of dissolved organic carbon(DOC). Two types of mechanisms, i.e., ion exchange...Magnetic ion exchange(MIEX) resins have received considerable attention in drinking water treatment due to their fast and efficient removal of dissolved organic carbon(DOC). Two types of mechanisms, i.e., ion exchange,reversible and irreversible adsorption, may occur during pollutants removal by MIEX. This work examined the removal mechanism of 17α-Ethinylestradiol(EE2) by MIEX. As one of typical estrogen micro-pollutants,EE2 existed as neutral molecule in natural water, and its charge density was close to zero [(0.00000219 ±0.00000015) meq·(μg EE2)^(-1)] based on the potentiometric titration method. However, the removal of EE2 by MIEX was much higher than that of other micro-pollutants previously reported. Multi-cycle adsorptionregeneration experiments and ion exchange stoichiometry analysis were conducted to elucidate the removal mechanism of EE2 by MIEX resin. The results suggested that the main removal mechanism of EE2 by MIEX was ion exchange instead of reversible micro-pore adsorption. The experimental analysis based on Donnan theory indicated that the internal micro-environment of resin beads was alkaline, in the alkaline environment EE2 would be ionized into negatively charged groups. As a result, ion exchange reaction occurred inside the pore of MIEX resin, and the removal process of EE2 by MIEX was dominated by the ion exchange reaction.展开更多
Exchange bias between ferromagnetic and antiferromagnetic layers has been widely utilized in spintronic devices.Controlling the exchange bias in magnetic multilayers by an electric field(E-field)has been proposed as a...Exchange bias between ferromagnetic and antiferromagnetic layers has been widely utilized in spintronic devices.Controlling the exchange bias in magnetic multilayers by an electric field(E-field)has been proposed as a low-power solution for manipulating the macroscopic properties such as exchange bias fields and magnetization values,while how the magnetic domains respond to the E-fields has rarely been reported in an exchange-biased system.Here,we realize the vector imaging of reversible electrical modulation of magnetization reversal in exchange-biased CoFeB/IrMn/PMN-PT(011)multiferroic heterostructures,utilizing in-situ quantitative magneto-optical Kerr effect(MOKE)microscopy.Under the electrical control,magnetic domains at-80 Oe rotate reversibly between around 160°and 80°-120°,whose transverse components reverse from 225°to 45°correspondingly.Moreover,pixel-by-pixel comparisons are conducted to further imply the reversible magnetization reversal by E-fields.Efield-induced reversible magnetization reversal is also demonstrated without applying external magnetic fields.Vector imaging of electrical manipulation of exchange bias is of great significance in understanding the magnetoelectric effect and the development of next-generation spintronic devices.展开更多
文摘In this paper, we first theoretically report the magnetic and magneto-opticalproperties in paramagnetic media under high external magnetic field. Considering the action of theexternal magnetic Geld H_e and indirect exchange interaction H_v, the characteristic of the magneticsaturation and the property of the Faraday rotation to be nonlinear with external magnetic Geld arepresented in paramagnetic NdF_3. In terms of our theory, the indirect exchange interaction plays auimportant role in the magnetization M and the Faraday rotation θ in NdF_3 under high externalmagnetic Geld. The theory is in good agreement with experimental results. On the other hand, areasonable explanation for the temperature dependence of the ratio of the Verdet constant to themagnetic susceptibility V/x is obtained.
基金Supported by the National Natural Science Foundation of China(51678408,51478314,51638011)the National Key Research and Development Program of China(2016YFC0400506)+1 种基金the Natural Science Foundation of Tianjin(14JCQNJC09000)the Research Fund of Tianjin Key Laboratory of Aquatic Science and Technology(TJKLASTZD-2016-06)
文摘Magnetic ion exchange(MIEX) resins have received considerable attention in drinking water treatment due to their fast and efficient removal of dissolved organic carbon(DOC). Two types of mechanisms, i.e., ion exchange,reversible and irreversible adsorption, may occur during pollutants removal by MIEX. This work examined the removal mechanism of 17α-Ethinylestradiol(EE2) by MIEX. As one of typical estrogen micro-pollutants,EE2 existed as neutral molecule in natural water, and its charge density was close to zero [(0.00000219 ±0.00000015) meq·(μg EE2)^(-1)] based on the potentiometric titration method. However, the removal of EE2 by MIEX was much higher than that of other micro-pollutants previously reported. Multi-cycle adsorptionregeneration experiments and ion exchange stoichiometry analysis were conducted to elucidate the removal mechanism of EE2 by MIEX resin. The results suggested that the main removal mechanism of EE2 by MIEX was ion exchange instead of reversible micro-pore adsorption. The experimental analysis based on Donnan theory indicated that the internal micro-environment of resin beads was alkaline, in the alkaline environment EE2 would be ionized into negatively charged groups. As a result, ion exchange reaction occurred inside the pore of MIEX resin, and the removal process of EE2 by MIEX was dominated by the ion exchange reaction.
基金supported by the National Key R&D Program of China(2018YFB0407601)the National Natural Science Foundation of China(91964109,62071374 and 51802248)the National 111 Project of China(B14040).
文摘Exchange bias between ferromagnetic and antiferromagnetic layers has been widely utilized in spintronic devices.Controlling the exchange bias in magnetic multilayers by an electric field(E-field)has been proposed as a low-power solution for manipulating the macroscopic properties such as exchange bias fields and magnetization values,while how the magnetic domains respond to the E-fields has rarely been reported in an exchange-biased system.Here,we realize the vector imaging of reversible electrical modulation of magnetization reversal in exchange-biased CoFeB/IrMn/PMN-PT(011)multiferroic heterostructures,utilizing in-situ quantitative magneto-optical Kerr effect(MOKE)microscopy.Under the electrical control,magnetic domains at-80 Oe rotate reversibly between around 160°and 80°-120°,whose transverse components reverse from 225°to 45°correspondingly.Moreover,pixel-by-pixel comparisons are conducted to further imply the reversible magnetization reversal by E-fields.Efield-induced reversible magnetization reversal is also demonstrated without applying external magnetic fields.Vector imaging of electrical manipulation of exchange bias is of great significance in understanding the magnetoelectric effect and the development of next-generation spintronic devices.
