We find quantum mechanical Fourier-Hankel representation transform for an electron moving in a uniform magnetic field. The physical meaning of Fourier decomposition states of electron's coordinate eigenstate and t...We find quantum mechanical Fourier-Hankel representation transform for an electron moving in a uniform magnetic field. The physical meaning of Fourier decomposition states of electron's coordinate eigenstate and the momentum eigenstate are revealed.展开更多
We review the progress and future possibilities in the emerging area of molecular spintronics. We first provide an overview of the different transport regimes in which electronic nanodevices can operate, then briefly ...We review the progress and future possibilities in the emerging area of molecular spintronics. We first provide an overview of the different transport regimes in which electronic nanodevices can operate, then briefly overview the important characteristics of molecular magnetic materials that can be useful for application in spintronics and we eventually present several schemes to include such systems into spintronic nanodevices. We hightlight the importance of a chemical approach to the area, and in the last section we showcase some approaches to the creation of hybrids made of carbon nanostructures and molecular magnets, which are gaining increasing attention.展开更多
Single crystals of organic semiconductors with perfect crystal structure and minimal density of defects can exhibit high mobility and low spin scattering compared with their amorphous or polycrystalline counterparts.T...Single crystals of organic semiconductors with perfect crystal structure and minimal density of defects can exhibit high mobility and low spin scattering compared with their amorphous or polycrystalline counterparts.Therefore,these materials are promising candidates as the spin transport media to obtain long spin relaxation times and spin diffusion lengths in spintronic devices.However,the investigation of spin injection and transport properties in organic single crystals is hindered by the inability to construct devices such as single-crystalline organic spin valves(OSVs).Herein,thin and large organic single crystals of 6,13-bis(triisopropylsilylethynyl)pentacene(TIPS-pentacene)were grown on a liquid substrate and transferred to a target substrate carrying ferromagnetic electrodes to construct single-crystalline OSVs.The magnetoresistance(MR)responses of the single crystals were investigated to study their spin injection and transport properties.MR value as high as 17%was probed with an intermediate layer thickness of 269 nm.More importantly,spin transport was still observed in a single crystal of a thickness up to 457 nm,which was much larger than that of polycrystalline thin film.Our research provides a general methodology for constructing single-crystalline OSVs and paves the way to probe the intrinsic spin transport properties of organic semiconductors based on single crystals.展开更多
A coherent nonlinear coupling between the charge and spin dynamics of electrons results in the rectification of microwaves,which is enhanced through resonant magnetization dynamics such as ferromagnetic resonance.This...A coherent nonlinear coupling between the charge and spin dynamics of electrons results in the rectification of microwaves,which is enhanced through resonant magnetization dynamics such as ferromagnetic resonance.This property,known as the spin rectification effect,enables the spin dynamics within a material to be electrically detected with a high sensitivity.Techniques utilizing this property have been widely used to study the magnetization dynamics of various ferromagnetic materials and structures in the past decade.Additionally,the coherent nature of spin rectification opens the door for spintronic devices to be used in phase-resolved microwave sensing techniques.In this work we review the physics of spin rectification and its applications in several interesting topics of magnetism and spintronics.展开更多
Antiferromagnetic (AFM) materials have attracted wide attention in spin-orbit torque (SOT)-based spintronic due to its abundant spin-dependent properties and unique advantage of immunity against external field perturb...Antiferromagnetic (AFM) materials have attracted wide attention in spin-orbit torque (SOT)-based spintronic due to its abundant spin-dependent properties and unique advantage of immunity against external field perturbations.To act as the charge-to-spin conversion source in energy-saving spintronic devices,it is of great importance for the AFM material to possess a large spin torque efficiency(ξDL).In this work,using the spin torque ferromagnetic resonance (ST-FMR) technique and a Mn2Au/Ni Fe(Py) bilayer system,we systemically study the ξDLof AFM Mn2Au films with different crystal structures.Compared with polycrystalline Mn2Au with effective ξDL<0.051,we show a much larger ξDLof~0.333 in single-crystal Mn2Au,which arises from the large spin Hall conductivity instead of electrical resistivity.Moreover,with a further contribution of interfacial effects,the effective ξDLof single-crystalline Mn2Au/Py system increases to 0.731,which is more than two times larger than the value of ~0.22 reported for the Mn2Au/CoFeB system.By utilizing the largeξDLof Mn2Au in a perpendicularly magnetized Mn Ga/Mn2Au system,energy-efficient deterministic magnetization switching with a current density at ~10^(6)A cm^(-2)is achieved.Our results reveal a significant potential of Mn2Au as an efficient SOT source and shed light on its application in future AFM material-based SOT integration technology.展开更多
We prepared the DNA-cetyltrimethyl ammonium complex, as well as the same complex intercalated with stable organic free radicals, and studied their magnetic properties by electron magnetic resonance (EMR) spectroscopy ...We prepared the DNA-cetyltrimethyl ammonium complex, as well as the same complex intercalated with stable organic free radicals, and studied their magnetic properties by electron magnetic resonance (EMR) spectroscopy and by measuring the magnetization on a superconducting quantum interference device (SQUID). The UV-vis and CD spectra of DNA-quaternary alkyl ammonium complex (DNA--Q+) in organic solvent clearly demonstrated that it retained the double helical B-form conformation. The interhelical spacing of double strand DNA (dsDNA) increased when the counter ions (Na+) of phosphate groups of the natural DNA were replaced with the long alkyl quaternary ammonium groups. The inter-helical distance of DNA-cetyltrimethyl ammonium (CTMA) was 39.1 as confirmed by X-ray diffractometry. In general, the magnetization of the DNA-CTMA complex solid was found to be significantly lower than that of natural DNA. Moreover, intercalation of the complex with stable organic free radicals did not improve magnetization, which again was in marked contrast to natural DNA. EMR spectroscopic behavior of the complex in the solid state also was quite different from that of natural DNA: The unique broad EMR signal of natural DNA in the low field region with g-value greater than 10 disappeared in the DNA-CTMA complex.展开更多
基金The project supported by National Natural Science Foundation of China under Grant No.10175057the President Foundation of the Chinese Academy of Sciences
文摘We find quantum mechanical Fourier-Hankel representation transform for an electron moving in a uniform magnetic field. The physical meaning of Fourier decomposition states of electron's coordinate eigenstate and the momentum eigenstate are revealed.
基金financial support from the Humboldt Stiftung (Sofja Kovalevskaja Prize)the German DFG (SPP 1601)the BW Stiftung via the Kompetenznetz Funktionelle Nanostrukturen
文摘We review the progress and future possibilities in the emerging area of molecular spintronics. We first provide an overview of the different transport regimes in which electronic nanodevices can operate, then briefly overview the important characteristics of molecular magnetic materials that can be useful for application in spintronics and we eventually present several schemes to include such systems into spintronic nanodevices. We hightlight the importance of a chemical approach to the area, and in the last section we showcase some approaches to the creation of hybrids made of carbon nanostructures and molecular magnets, which are gaining increasing attention.
基金the National Natural Science Foundation of China(61674116,51873148,51633006,and 52003190)the Ministry of Science and Technology of China(2016YFA0202302)the Natural Science Foundation of Tianjin(18JC-YBJC18400)。
文摘Single crystals of organic semiconductors with perfect crystal structure and minimal density of defects can exhibit high mobility and low spin scattering compared with their amorphous or polycrystalline counterparts.Therefore,these materials are promising candidates as the spin transport media to obtain long spin relaxation times and spin diffusion lengths in spintronic devices.However,the investigation of spin injection and transport properties in organic single crystals is hindered by the inability to construct devices such as single-crystalline organic spin valves(OSVs).Herein,thin and large organic single crystals of 6,13-bis(triisopropylsilylethynyl)pentacene(TIPS-pentacene)were grown on a liquid substrate and transferred to a target substrate carrying ferromagnetic electrodes to construct single-crystalline OSVs.The magnetoresistance(MR)responses of the single crystals were investigated to study their spin injection and transport properties.MR value as high as 17%was probed with an intermediate layer thickness of 269 nm.More importantly,spin transport was still observed in a single crystal of a thickness up to 457 nm,which was much larger than that of polycrystalline thin film.Our research provides a general methodology for constructing single-crystalline OSVs and paves the way to probe the intrinsic spin transport properties of organic semiconductors based on single crystals.
基金supported by NSERC,CFI,URGPthe National Natural Science Foundation of China(Oversea Scholar Collaborative Research Grant No.11128408)
文摘A coherent nonlinear coupling between the charge and spin dynamics of electrons results in the rectification of microwaves,which is enhanced through resonant magnetization dynamics such as ferromagnetic resonance.This property,known as the spin rectification effect,enables the spin dynamics within a material to be electrically detected with a high sensitivity.Techniques utilizing this property have been widely used to study the magnetization dynamics of various ferromagnetic materials and structures in the past decade.Additionally,the coherent nature of spin rectification opens the door for spintronic devices to be used in phase-resolved microwave sensing techniques.In this work we review the physics of spin rectification and its applications in several interesting topics of magnetism and spintronics.
基金supported by the Agency for Science,Technology and Research (A*STAR) of Singapore (A1983c0036)the Singapore Ministry of Education (MOE2018-T2-2043)A*STAR IAF-ICP 11801E0036。
文摘Antiferromagnetic (AFM) materials have attracted wide attention in spin-orbit torque (SOT)-based spintronic due to its abundant spin-dependent properties and unique advantage of immunity against external field perturbations.To act as the charge-to-spin conversion source in energy-saving spintronic devices,it is of great importance for the AFM material to possess a large spin torque efficiency(ξDL).In this work,using the spin torque ferromagnetic resonance (ST-FMR) technique and a Mn2Au/Ni Fe(Py) bilayer system,we systemically study the ξDLof AFM Mn2Au films with different crystal structures.Compared with polycrystalline Mn2Au with effective ξDL<0.051,we show a much larger ξDLof~0.333 in single-crystal Mn2Au,which arises from the large spin Hall conductivity instead of electrical resistivity.Moreover,with a further contribution of interfacial effects,the effective ξDLof single-crystalline Mn2Au/Py system increases to 0.731,which is more than two times larger than the value of ~0.22 reported for the Mn2Au/CoFeB system.By utilizing the largeξDLof Mn2Au in a perpendicularly magnetized Mn Ga/Mn2Au system,energy-efficient deterministic magnetization switching with a current density at ~10^(6)A cm^(-2)is achieved.Our results reveal a significant potential of Mn2Au as an efficient SOT source and shed light on its application in future AFM material-based SOT integration technology.
基金Young-Wan Kwon would like to express his gratitude to the Korean National Foundation for the support (2010-0013225)
文摘We prepared the DNA-cetyltrimethyl ammonium complex, as well as the same complex intercalated with stable organic free radicals, and studied their magnetic properties by electron magnetic resonance (EMR) spectroscopy and by measuring the magnetization on a superconducting quantum interference device (SQUID). The UV-vis and CD spectra of DNA-quaternary alkyl ammonium complex (DNA--Q+) in organic solvent clearly demonstrated that it retained the double helical B-form conformation. The interhelical spacing of double strand DNA (dsDNA) increased when the counter ions (Na+) of phosphate groups of the natural DNA were replaced with the long alkyl quaternary ammonium groups. The inter-helical distance of DNA-cetyltrimethyl ammonium (CTMA) was 39.1 as confirmed by X-ray diffractometry. In general, the magnetization of the DNA-CTMA complex solid was found to be significantly lower than that of natural DNA. Moreover, intercalation of the complex with stable organic free radicals did not improve magnetization, which again was in marked contrast to natural DNA. EMR spectroscopic behavior of the complex in the solid state also was quite different from that of natural DNA: The unique broad EMR signal of natural DNA in the low field region with g-value greater than 10 disappeared in the DNA-CTMA complex.