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硫铁矿制酸装置磁性焙烧技术改造及综合利用 被引量:1
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作者 孙永宝 《安徽化工》 CAS 2012年第4期46-47,共2页
以120kt/a硫铁矿制酸装置为例,介绍了硫酸的生产原理、磁性焙烧的生产控制、干法排渣装置存在问题及技术改造。尾渣的综合利用,提高了铁资源的利用率,年新增经济效益约984万元,同时具有较好的社会效益。
关键词 硫铁矿制酸 磁性焙烧 技术改造 综合利用
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磁性焙烧态锌铝类水滑石吸附腐殖酸与再生
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作者 李绍秀 杨玉和 +2 位作者 彭士城 王志红 李冬梅 《环境科学与技术》 CAS CSCD 北大核心 2019年第5期70-76,共7页
采用化学共沉淀一步法制备了磁性锌铝类水滑石(M·Zn/Al LDHs),并经煅烧得到磁性焙烧态锌铝类水滑石(M·Zn/Al LDO),用以吸附去除水中腐殖酸。文章探讨了M·Zn/Al LDO去除腐殖酸的影响因素,研究了M·Zn/Al LDO吸附腐殖... 采用化学共沉淀一步法制备了磁性锌铝类水滑石(M·Zn/Al LDHs),并经煅烧得到磁性焙烧态锌铝类水滑石(M·Zn/Al LDO),用以吸附去除水中腐殖酸。文章探讨了M·Zn/Al LDO去除腐殖酸的影响因素,研究了M·Zn/Al LDO吸附腐殖酸的动力学与热力学,考察了吸附腐殖酸后M·Zn/Al LDO焙烧再生的条件。结果表明,当M·Zn/Al LDO投加量<0.2 g/L时腐殖酸去除率随着投加量的增大而增大,腐殖酸的初始浓度增大时吸附量增大但去除率减小。在pH 4~8腐殖酸去除率较高,保持在97%以上。NO3-和F-对去除腐殖酸的影响甚微,而H2PO4-则影响较大。拟二级动力学模型与Langmuir吸附等温线较好地描述吸附过程,吸附过程以物理吸附为主,化学吸附为辅。吸附腐殖酸后的M·Zn/Al LDO通过煅烧恢复焙烧态锌铝类水滑石结构,腐殖酸分解,再生效果良好,且磁性未被破坏。可见,磁性焙烧态锌铝类水滑石是一种高效且有潜在应用前景的去除腐殖酸的水处理材料。 展开更多
关键词 焙烧磁性锌铝类水滑石 腐殖酸 吸附 再生
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200kt/a硫精砂制酸装置磁性焙烧设计与生产实践
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作者 仲数 吴卫民 王新耀 《硫酸工业》 CAS 2015年第1期37-42,共6页
介绍了200 kt/a硫酸装置磁性焙烧的工艺设计特点、设备选型,以及硫酸装置开车生产的实践情况。试生产期间通过对沸腾炉点火工艺改进,以及对系统设备、工艺方面的调试和完善,使装置目前运行平稳。硫酸产量、工艺指标、消耗等方面优于设计... 介绍了200 kt/a硫酸装置磁性焙烧的工艺设计特点、设备选型,以及硫酸装置开车生产的实践情况。试生产期间通过对沸腾炉点火工艺改进,以及对系统设备、工艺方面的调试和完善,使装置目前运行平稳。硫酸产量、工艺指标、消耗等方面优于设计值,为以后的矿渣产品、余热发电、蒸汽外卖、循环利用和经济发展打下基础。 展开更多
关键词 硫精砂 硫酸 磁性焙烧 设计 循环利用 生产实践
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Characterization and technology of fast reducing roasting for fine iron materials 被引量:15
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作者 罗立群 黄红 余永富 《Journal of Central South University》 SCIE EI CAS 2012年第8期2272-2278,共7页
The features of the techniques of fast reducing roasting (FRR) and conventional magnetic roasting, as well as tremendous demands of iron ores in iron and steel industry of China, were briefly described. The test equ... The features of the techniques of fast reducing roasting (FRR) and conventional magnetic roasting, as well as tremendous demands of iron ores in iron and steel industry of China, were briefly described. The test equipment suitable for FRR of fine-grained materials was introduced. Weakly magnetic materials with grain size of 〈0.30 mm were converted into strongly magnetic materials by FRR for several to dozens of seconds. In a weakly reducing atmosphere and at 740-800 ~C, refractory powder iron material (〈0.30 mm) which is rich in specularite, limonite and Mg-Mn siderite was subjected to FRR for a few seconds to 60 s. Concentrate with iron grade of 55.67%-55.21%, high contents of Mg and Mn in the ore is obtained and the yield of magnetic separation reaches 81.66%-86.57%. The results of X-ray diffraction (XRD) analysis and magnetism detection of the material before and after FRR indicate that weakly magnetic material is mainly converted into strongly magnetic material Fe304 with specific saturation magnetic moment. The efficiency of FRR is consistent with TFe recovery of magnetic separation; meantime, the specific sa^u'ation magnetic moment increases from 33 to 42 times after FRR. Calculations show that speeds of flash magnetic roasting are obtained from several dozen to two or three hundred times, compared with rotary kiln or shaft furnace. This indicates that it is practicable to use the fast reducing roasting technique to improve the comprehensive utilization of iron ore resources. 展开更多
关键词 iron material reducing roasting thermal decomposition X-ray diffraction magnetic property
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Effects of intense magnetic field on digestion and settling performances of bauxite 被引量:1
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作者 吕国志 张廷安 +4 位作者 王小晓 张旭华 刘燕 赵秋月 豆志河 《Journal of Central South University》 SCIE EI CAS 2014年第6期2168-2175,共8页
The effects of magnetic field intensity, roasting temperature and roasting time on digestion rate and settling performance of bauxite with different iron contents were investigated systematically. The results indicate... The effects of magnetic field intensity, roasting temperature and roasting time on digestion rate and settling performance of bauxite with different iron contents were investigated systematically. The results indicate that such magnetic treatment can profoundly change the microstructure and digestion performance of bauxite. For the two samples carrying different iron contents, phase transformation of the aluminum oxide phase proceeds faster in the high iron bauxite than the low one. The optimal pretreatment conditions of low iron bauxite are roasting temperature 550 ℃ and magnetic field intensity 6 T, while for high iron bauxite are 500 ℃ and 9 T. The digestion rate of alumina can reach 95% and 92% at digestion temperature of 190 ℃ and 250 ℃. The settling performances of roasted ore by intense magnetic field after digestion are enhanced through pretreatment. 展开更多
关键词 BAUXITE intense magnetic field phase transformation digestion performance settling performance
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