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高Fe_3O_4含量微米尺寸磁性复合微球的合成及其在化学发光免疫检测中应用初探 被引量:5
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作者 徐雅雯 徐宏 +1 位作者 丁玮洁 古宏晨 《高分子学报》 SCIE CAS CSCD 北大核心 2010年第11期1340-1345,共6页
采用种子乳液聚合方法制得了微米尺度的高磁性物质含量的磁性复合微球.聚合体系中,以0.7~0.8μm的Fe3O4磁性聚集体细乳液作为种子,将苯乙烯,二乙烯基苯作为聚合单体加入到磁性聚集体细乳液中,对Fe3O4磁性聚集体进行溶胀后进行聚合.研... 采用种子乳液聚合方法制得了微米尺度的高磁性物质含量的磁性复合微球.聚合体系中,以0.7~0.8μm的Fe3O4磁性聚集体细乳液作为种子,将苯乙烯,二乙烯基苯作为聚合单体加入到磁性聚集体细乳液中,对Fe3O4磁性聚集体进行溶胀后进行聚合.研究了聚合过程中,溶胀时间对复合微球形貌和磁性物质含量的影响,获得系列形貌微球.通过透射电镜(TEM)、热重分析(TGA)、红外分析(FTIR)、振动样品磁强计(VSM)等表征手段对所制备的磁性聚合物微球进行分析表征.结果显示,所得到的磁性聚合物微球粒度为0.7~1μm,尺寸分布较均一,具有超顺磁性,磁性物质含量为29wt%~57wt%.然后又通过丙烯酸和苯乙烯共聚对微球表面羧基功能化后,得到了表面羧基密度为0.92mmol/g的微球,再将所制备的微球与生物分子偶联后(以hCG作为模式待检分子),在化学发光免疫检测上进行了初步的应用,取得到了较好的应用结果. 展开更多
关键词 磁性聚合物微球 磁性物质含量 微米 羧基 形貌调控 生物应用
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2019年长江口南北槽水域表层沉积物特征分析
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作者 刘启雄 陈家祺 +1 位作者 刘海江 张东来 《海洋工程》 CSCD 北大核心 2020年第4期100-108,共9页
为探究长江口区域最新的泥沙运动特征,于2019年枯季(1月,21个样本)和洪季(8月,58个样本)在长江口南北槽及周边区域现场取样河床表层泥沙样本,测量了样本的中值粒径和级配分布。采用Folk-Ward公式计算了泥沙样本的粒度参数(分选系数、偏... 为探究长江口区域最新的泥沙运动特征,于2019年枯季(1月,21个样本)和洪季(8月,58个样本)在长江口南北槽及周边区域现场取样河床表层泥沙样本,测量了样本的中值粒径和级配分布。采用Folk-Ward公式计算了泥沙样本的粒度参数(分选系数、偏度和峰度),并分析了沙样本内磁性物质含量。基于上述泥沙物理参数,进一步对比分析洪枯季研究区域河床表层泥沙的时空分布变化特征。分析结果表明北槽内洪枯季泥沙样本中值粒径空间分布特征一致,南槽中段洪季泥沙样本中值粒径远小于枯季泥沙样本中值粒径,南槽其他区域洪枯季泥沙样本中值粒径空间分布特征一致。同一中值粒径下,不同沙样本(中值粒径大于63μm)各粒度参数之间差异显著,而泥样本(中值粒径小于63μm)粒度参数间差异相对较小。此外,磁性物质含量测量结果表明枯季沙样本磁性物质组成的空间分布存在一定的差异,而洪季沙样本磁性物质的空间分布相对均一。 展开更多
关键词 长江口南北槽 深水航道 洪枯季 泥沙样本 中值粒径空间分布特征 粒度参数 磁性物质含量
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出口茶叶遭退货的分析与思考
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《蚕桑茶叶通讯》 2003年第1期2-2,共1页
关键词 中国 磁性物质含量 原料茶加工工艺 去磁装置 企业管理人员培训 出口茶叶
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Effects of Enriched Biochars Containing Magnetic Iron Nanoparticles on Mycorrhizal Colonisation,Plant Growth,Nutrient Uptake and Soil Quality Improvement 被引量:8
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作者 Stephen JOSEPH Hossain M.ANAWAR +8 位作者 Paul STORER Paul BLACKWELL Chee CHIA Yun LIN Paul MUNROE Scott DONNE Josip HORVAT Jianli WANG Zakaria M.SOLAIMAN 《Pedosphere》 SCIE CAS CSCD 2015年第5期749-760,共12页
At present, there is little commercial sale of biochar, since farmers find they can not gain a return on their investment in this amendment in the first few years after its application, because of the high cost associ... At present, there is little commercial sale of biochar, since farmers find they can not gain a return on their investment in this amendment in the first few years after its application, because of the high cost associated with large application rates. To overcome this constraint, development of artificially aged enriched biochar-mineral complexes(BMCs), having a higher mineral content, surface functionality, exchangeable cations, high concentration of magnetic iron(Fe) nanoparticles, and higher water-extractable organic compounds has been undertaken by a combined team of researchers and a commercial company. Two biochars produced under different pyrolysis conditions were activated with a phosphoric acid treatment. A mixture of clay, chicken litter, and minerals were added to the biochar, and then this composite was torrefied at either 180 or 220?C. In this study a pot experiment was carried out in glasshouse conditions to determine the effects of four different BMCs, with different formulations applied at rates of 100 and 200 kg ha-1, on the mycorrhizal colonisation, wheat growth and nutrient uptake, and soil quality improvement. It was found that the phosphorus(P) and nitrogen uptake in wheat shoots were significantly greater for a low application rate of BMCs(100 kg ha-1). The present formulation of BMC was effective in enhancing growth of wheat at low application rate(100 kg ha-1). The increase in growth appeared due to an increase in P uptake in the plants that could be partly attributed to an increase in mycorrhizal colonisation and partly due to the properties of the BMC. 展开更多
关键词 biochar-mineral complexes Fe nanoparticles P uptake redox reactions
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