In this study, poly(y-glutamic acid)-coated Fe3O4 magnetic nanoparticles (y-PGA/Fe304 MNPs) were successfully fabricated using the co-precipitation method. Fe3O4 MNPs were also prepared for comparison. The av erag...In this study, poly(y-glutamic acid)-coated Fe3O4 magnetic nanoparticles (y-PGA/Fe304 MNPs) were successfully fabricated using the co-precipitation method. Fe3O4 MNPs were also prepared for comparison. The av erage size and specific surface area results reveal that 7-PGA/Fe304 MNPs (52.4 nm, 88.41 m2.g-1) have smaller particle size and larger specific surface area_ than Fe3O4 MNPs (62.0 nm, 76.83 mLg-1). The y-PGA/Fe3O4 MNPs展开更多
In this paper,we present a review of electron transport properties of magnetic granular films.Magnetic granular films are nanocomposite materials which consist of magnetic nanoparticles embedded in a nonmagnetic matri...In this paper,we present a review of electron transport properties of magnetic granular films.Magnetic granular films are nanocomposite materials which consist of magnetic nanoparticles embedded in a nonmagnetic matrix or assembling of magnetic nanoparticles.According to the style of the nonmagnetic matrix,microstructure and the electron transport mechanism of the films,the magnetic granular films were divided into three groups:(1) magnetic metal-metal granular films,(2) magnetic metal-insulator granular films and(3) magnetic nanocluster-assembled granular films.Moreover,we also systematically review the magnetic properties,transport properties and magnetoresistance effect of size-monodispersed Co and Fe nanocluster-assembled films.展开更多
Dispersion of metal particles in fluids can be used to manufacture magnetorheologic fluids(MRF).Properties of these dispersion systems are mainly determined by the arrangements and contacts among particles.In this pap...Dispersion of metal particles in fluids can be used to manufacture magnetorheologic fluids(MRF).Properties of these dispersion systems are mainly determined by the arrangements and contacts among particles.In this paper,particles with smaller sizes than those in the target dispersion system are added using iron particles dispersed in silicon oil as a model to control the arrangements and contacts.The result suggests that these small-sized particles have a significant effect on the viscoelastic properties of the dispersion.The maximum packing density and the fluid viscosity depend mainly on the adhesion of small particles,which is directly related to the fraction of small particles in the model dispersion system.Under a magnetic field,the yield stress of the dispersion system is proportional to the concentration of iron particles,suggesting that the yield stress relies directly on the presence of small particles.These small particles in the fluid determine the difference in stress of the magnetorheological fluid(MRF) with or without a magnetic field.展开更多
基金Supported by the National Natural Science Foundation of China (21276124), the Research Project of Natural Science for Universities Affiliated to Jiangsu Province (10KJB530002), Key Projects in the National Science & Technology Pillar Pro-gram (2011BAE07B09-3), the Jiangsu Provincial Science and Technology Support Program (BE2011831), and the State High Technology Research and Development Prograr of China (2011AA02A201).
文摘In this study, poly(y-glutamic acid)-coated Fe3O4 magnetic nanoparticles (y-PGA/Fe304 MNPs) were successfully fabricated using the co-precipitation method. Fe3O4 MNPs were also prepared for comparison. The av erage size and specific surface area results reveal that 7-PGA/Fe304 MNPs (52.4 nm, 88.41 m2.g-1) have smaller particle size and larger specific surface area_ than Fe3O4 MNPs (62.0 nm, 76.83 mLg-1). The y-PGA/Fe3O4 MNPs
基金supported by the National Basic Research Program of China (Grant No. 2012CB933103)the National Science Fund for Distinguished Young Scholars (Grant No. 50825101)the National Natural Science Foundation of China (Grant Nos. 50971108 and 51171158)
文摘In this paper,we present a review of electron transport properties of magnetic granular films.Magnetic granular films are nanocomposite materials which consist of magnetic nanoparticles embedded in a nonmagnetic matrix or assembling of magnetic nanoparticles.According to the style of the nonmagnetic matrix,microstructure and the electron transport mechanism of the films,the magnetic granular films were divided into three groups:(1) magnetic metal-metal granular films,(2) magnetic metal-insulator granular films and(3) magnetic nanocluster-assembled granular films.Moreover,we also systematically review the magnetic properties,transport properties and magnetoresistance effect of size-monodispersed Co and Fe nanocluster-assembled films.
基金supported by the Central University Basic Research and Operating Expenses (Grant No. YWF-10-03-019, YWF-11-03-H-005, YWF-11-04-009)the Scientific Research Foundation for Returned Overseas Chinese Scholars, State Education Ministry
文摘Dispersion of metal particles in fluids can be used to manufacture magnetorheologic fluids(MRF).Properties of these dispersion systems are mainly determined by the arrangements and contacts among particles.In this paper,particles with smaller sizes than those in the target dispersion system are added using iron particles dispersed in silicon oil as a model to control the arrangements and contacts.The result suggests that these small-sized particles have a significant effect on the viscoelastic properties of the dispersion.The maximum packing density and the fluid viscosity depend mainly on the adhesion of small particles,which is directly related to the fraction of small particles in the model dispersion system.Under a magnetic field,the yield stress of the dispersion system is proportional to the concentration of iron particles,suggesting that the yield stress relies directly on the presence of small particles.These small particles in the fluid determine the difference in stress of the magnetorheological fluid(MRF) with or without a magnetic field.