Geomagnetic orbit determination fits for nanosatellites which pursue low cost and high-density ratio,but one of its disadvantages is the poor position accuracy introduced by magnetic bias.Here,a new method,named the f...Geomagnetic orbit determination fits for nanosatellites which pursue low cost and high-density ratio,but one of its disadvantages is the poor position accuracy introduced by magnetic bias.Here,a new method,named the fuzzy regulating unscented Kalman filter(FRUKF),is proposed.The magnetic bias is regarded as a random walk model,and a fuzzy regulator is designed to estimate the magnetic bias more accurately.The input of the regulator is the derivative of magnetic bias estimated from unscented Kalman filter(UKF).According to the fuzzy rule,the process noise covariance is adaptively determined.The FRUKF is evaluated using the real-flight data of the SWARMA.The experimental results show that the root-mean-square(RMS)position error is 3.1 km and the convergence time is shorter than the traditional way.展开更多
A magnetic bar carbon paste electrode (MBCPE) modified with Fe3O4 magnetic nanoparticles (Fe3O4NPs) and 2‐(3,4‐dihydroxyphenyl) benzothiazole (DPB) for the electrochemical determina‐tion of hydrazine was de...A magnetic bar carbon paste electrode (MBCPE) modified with Fe3O4 magnetic nanoparticles (Fe3O4NPs) and 2‐(3,4‐dihydroxyphenyl) benzothiazole (DPB) for the electrochemical determina‐tion of hydrazine was developed. The DPB was firstly self‐assembled on the Fe3O4NPs, and the re‐sulting Fe3O4NPs/DPB composite was then absorbed on the designed MBCPE. The MBCPE was used to attract the magnetic nanoparticles to the electrode surface. Owing to its high conductivity and large effective surface area, the novel electrode had a very large current response for the electrocat‐alytic oxidation of hydrazine. The modified electrode was characterized by voltammetry, scanning electron microscopy, electrochemical impedance spectroscopy, infrared spectroscopy, and UV‐visible spectroscopy. Voltammetric methods were used to study the electrochemical behaviour of hydrazine on MBCPE/Fe3O4NPs/DPB in phosphate buffer solution (pH = 7.0). The MBCPE/Fe3O4NPs/DPB, acting as an electrochemical sensor, exhibited very high electrocatalytic activity for the oxidation of hydrazine. The presence of DPB was found to reduce the oxidation potential of hydrazine and increase the catalytic current. The dependence of the electrocatalytic current on the hydrazine concentration exhibited two linear ranges, 0.1–0.4 μmol/L and 0.7–12.0 μmol/L, with a detection limit of 18.0 nmol/L. Additionally, the simultaneous determination of hydrazine and phe‐nol was investigated using the MBCPE/Fe3O4NPs/DPB electrode. Voltammetric experiments showed a linear range of 100–470 μmol/L and a detection limit of 24.3 μmol/L for phenol, and the proposed electrode was applied to the determination of hydrazine and phenol in water samples.展开更多
A simple and rapid strategy to construct laccase biosensor for determination of catechol was investigated. Magnetic multiwalled carbon nanotubes (MMCNT) which possess excellent capability of electron transfer were pre...A simple and rapid strategy to construct laccase biosensor for determination of catechol was investigated. Magnetic multiwalled carbon nanotubes (MMCNT) which possess excellent capability of electron transfer were prepared by chemical coprecipitation method. Scanning electron microscope (SEM) and vibrating sample magnetometer (VSM) were used to identify its surfacetopography and magnetization, respectively. Laccase was immobilized on the MMCNT modified magnetic carbon paste electrode by the aid of chitosan/silica (CS) hybrid membrane. Using current-time detection method, the biosensor shows a linear response related to the concentration of catechol in the range from 10-7 to 0.165×10-3 mol/L. The corresponding detection limit is 3.34×10-8 mol/L based on signal-to-noise ratios (S/N) ≥3 under the optimized conditions. In addition, its response current retains 90% of the original after being stored for 45 d. The results indicate that this proposed strategy can be expected to develop other enzyme-based biosensors.展开更多
Aimed at the problems of large torque ripple,obvious chattering and poor estimation accuracy of back-EMFs in traditional permanent magnet synchronous motor(PMSM)control system with sliding mode observer(SMO),an improv...Aimed at the problems of large torque ripple,obvious chattering and poor estimation accuracy of back-EMFs in traditional permanent magnet synchronous motor(PMSM)control system with sliding mode observer(SMO),an improved control strategy for PMSM based on a fuzzy sliding mode control(FSMC)and a two-stage filter sliding mode observer(TFSMO)is proposed.Firstly,a novel reaching law(NRL)used in the speed loop based on hyperbolic sine function is studied,and fuzzy control ideal is shown to achieve the self-turning of the parameter for the reaching law,thus a fuzzy integral sliding mode controller based on the novel reaching law is designed in speed loop.Then the suppression effect upon chattering caused by the novel reaching law is analyzed strictly by discrete equation.Secondly,in order to restrain the high frequency components and measurement noise in back-EMFs,a two-stage filter structure based on a variable cut-off frequency low-pass filter(VCF-LPF)and a modified back-EMF observer(MBO)is conceived,and the rotor position is compensated reasonably.As a result,a TFSMO is designed.The stability of the proposed control strategy is proved by Lyapunov Criterion.The simulation and experiment results show that,compared with traditional SMO,the controller suggested above can obtain very nice system respond when the motor starts and is subjected to external disturbances,and effectively improve the problems about torque ripple,chattering and the estimation accuracy of back-EMF.展开更多
The main requirement of a vector controller is knowing the magnitude and position of the rotating flow in the rotor. This feature permits to use either flow sensors or flow estimators. The solution chosen was the esti...The main requirement of a vector controller is knowing the magnitude and position of the rotating flow in the rotor. This feature permits to use either flow sensors or flow estimators. The solution chosen was the estimation of rotor flux with the hybrid neuro-fuzzy system. The motor characteristics are: 3.75 kW (5 HP), two pole-pair, operate at 60 Hz and air-gap length 0.2 mm. The ANFIS (adaptive neuro-fuzzy inference system) was used to tune the membership functions in fuzzy system. The hybrid estimator aims at compensating possible parametric variations of the machine caused by agents, such as temperature or nucleus saturation. The simulated results have shown good performance.展开更多
The main aim of this work is to study numerically the influence of an external magnetic field on the solidification processes of two-component materials. Based on the continuum model of two-phase flow a mathematical m...The main aim of this work is to study numerically the influence of an external magnetic field on the solidification processes of two-component materials. Based on the continuum model of two-phase flow a mathematical model for the directional solidification of a binary alloy in a magnetic field is presented. The model includes mass, momentum, energy and species mass conservation equations written in compressible form and additional relationships describing the temperature-solute coupling. The geometry under study is a cylindrical mold with adiabatic walls and cooled bottom. The macroscale transport in the solidification of alloys is governed by the progress of the two-phase mushy zone, which is treated by means of a porous medium approach. The volume fraction of liquid and solid phases, respectively, is calculated from a 2D approximation of the phase diagram. The results of calculation are compared with experimental data.展开更多
基金supported by the National Natural Science Foundation of China(No.61673212).
文摘Geomagnetic orbit determination fits for nanosatellites which pursue low cost and high-density ratio,but one of its disadvantages is the poor position accuracy introduced by magnetic bias.Here,a new method,named the fuzzy regulating unscented Kalman filter(FRUKF),is proposed.The magnetic bias is regarded as a random walk model,and a fuzzy regulator is designed to estimate the magnetic bias more accurately.The input of the regulator is the derivative of magnetic bias estimated from unscented Kalman filter(UKF).According to the fuzzy rule,the process noise covariance is adaptively determined.The FRUKF is evaluated using the real-flight data of the SWARMA.The experimental results show that the root-mean-square(RMS)position error is 3.1 km and the convergence time is shorter than the traditional way.
文摘A magnetic bar carbon paste electrode (MBCPE) modified with Fe3O4 magnetic nanoparticles (Fe3O4NPs) and 2‐(3,4‐dihydroxyphenyl) benzothiazole (DPB) for the electrochemical determina‐tion of hydrazine was developed. The DPB was firstly self‐assembled on the Fe3O4NPs, and the re‐sulting Fe3O4NPs/DPB composite was then absorbed on the designed MBCPE. The MBCPE was used to attract the magnetic nanoparticles to the electrode surface. Owing to its high conductivity and large effective surface area, the novel electrode had a very large current response for the electrocat‐alytic oxidation of hydrazine. The modified electrode was characterized by voltammetry, scanning electron microscopy, electrochemical impedance spectroscopy, infrared spectroscopy, and UV‐visible spectroscopy. Voltammetric methods were used to study the electrochemical behaviour of hydrazine on MBCPE/Fe3O4NPs/DPB in phosphate buffer solution (pH = 7.0). The MBCPE/Fe3O4NPs/DPB, acting as an electrochemical sensor, exhibited very high electrocatalytic activity for the oxidation of hydrazine. The presence of DPB was found to reduce the oxidation potential of hydrazine and increase the catalytic current. The dependence of the electrocatalytic current on the hydrazine concentration exhibited two linear ranges, 0.1–0.4 μmol/L and 0.7–12.0 μmol/L, with a detection limit of 18.0 nmol/L. Additionally, the simultaneous determination of hydrazine and phe‐nol was investigated using the MBCPE/Fe3O4NPs/DPB electrode. Voltammetric experiments showed a linear range of 100–470 μmol/L and a detection limit of 24.3 μmol/L for phenol, and the proposed electrode was applied to the determination of hydrazine and phenol in water samples.
基金Project(IRT0719) supported by the Program for Changjiang Scholars and Innovative Research Team in University, ChinaProjects (50978088, 51039001) supported by the National Natural Science Foundation of China+3 种基金Project(2009FJ1010) supported by the Hunan Key Scientific Research Program, ChinaProject(10JJ7005) supported by the Natural Science Foundation of Hunan Province, ChinaProjects(CX2009B080, CX2010B157) supported by the Hunan Provincial Innovation Foundation For PostgraduateProject supported by the Fundamental Research Funds for the Central Universities, Hunan University, China
文摘A simple and rapid strategy to construct laccase biosensor for determination of catechol was investigated. Magnetic multiwalled carbon nanotubes (MMCNT) which possess excellent capability of electron transfer were prepared by chemical coprecipitation method. Scanning electron microscope (SEM) and vibrating sample magnetometer (VSM) were used to identify its surfacetopography and magnetization, respectively. Laccase was immobilized on the MMCNT modified magnetic carbon paste electrode by the aid of chitosan/silica (CS) hybrid membrane. Using current-time detection method, the biosensor shows a linear response related to the concentration of catechol in the range from 10-7 to 0.165×10-3 mol/L. The corresponding detection limit is 3.34×10-8 mol/L based on signal-to-noise ratios (S/N) ≥3 under the optimized conditions. In addition, its response current retains 90% of the original after being stored for 45 d. The results indicate that this proposed strategy can be expected to develop other enzyme-based biosensors.
基金National Key R&D Program of China(No.2018YFB1201602)。
文摘Aimed at the problems of large torque ripple,obvious chattering and poor estimation accuracy of back-EMFs in traditional permanent magnet synchronous motor(PMSM)control system with sliding mode observer(SMO),an improved control strategy for PMSM based on a fuzzy sliding mode control(FSMC)and a two-stage filter sliding mode observer(TFSMO)is proposed.Firstly,a novel reaching law(NRL)used in the speed loop based on hyperbolic sine function is studied,and fuzzy control ideal is shown to achieve the self-turning of the parameter for the reaching law,thus a fuzzy integral sliding mode controller based on the novel reaching law is designed in speed loop.Then the suppression effect upon chattering caused by the novel reaching law is analyzed strictly by discrete equation.Secondly,in order to restrain the high frequency components and measurement noise in back-EMFs,a two-stage filter structure based on a variable cut-off frequency low-pass filter(VCF-LPF)and a modified back-EMF observer(MBO)is conceived,and the rotor position is compensated reasonably.As a result,a TFSMO is designed.The stability of the proposed control strategy is proved by Lyapunov Criterion.The simulation and experiment results show that,compared with traditional SMO,the controller suggested above can obtain very nice system respond when the motor starts and is subjected to external disturbances,and effectively improve the problems about torque ripple,chattering and the estimation accuracy of back-EMF.
文摘The main requirement of a vector controller is knowing the magnitude and position of the rotating flow in the rotor. This feature permits to use either flow sensors or flow estimators. The solution chosen was the estimation of rotor flux with the hybrid neuro-fuzzy system. The motor characteristics are: 3.75 kW (5 HP), two pole-pair, operate at 60 Hz and air-gap length 0.2 mm. The ANFIS (adaptive neuro-fuzzy inference system) was used to tune the membership functions in fuzzy system. The hybrid estimator aims at compensating possible parametric variations of the machine caused by agents, such as temperature or nucleus saturation. The simulated results have shown good performance.
文摘The main aim of this work is to study numerically the influence of an external magnetic field on the solidification processes of two-component materials. Based on the continuum model of two-phase flow a mathematical model for the directional solidification of a binary alloy in a magnetic field is presented. The model includes mass, momentum, energy and species mass conservation equations written in compressible form and additional relationships describing the temperature-solute coupling. The geometry under study is a cylindrical mold with adiabatic walls and cooled bottom. The macroscale transport in the solidification of alloys is governed by the progress of the two-phase mushy zone, which is treated by means of a porous medium approach. The volume fraction of liquid and solid phases, respectively, is calculated from a 2D approximation of the phase diagram. The results of calculation are compared with experimental data.