This paper reports a sustainable,water-assisted,solid-state method for synthesizing ammonium nickel molybdate（（NH4）HNi2（OH）2（MoO4）2,ANM）,a precursor for an unsupported hydrodesulfurization（HDS） catalyst.The ...This paper reports a sustainable,water-assisted,solid-state method for synthesizing ammonium nickel molybdate（（NH4）HNi2（OH）2（MoO4）2,ANM）,a precursor for an unsupported hydrodesulfurization（HDS） catalyst.The associated ANM formation mechanism is also discussed.The synthesis route consists of physical mixing of the raw materials,water-assisted grinding and heating.The formation mechanism involves replacement of a Mo atom by a Ni atom,generating the metastable intermediate（NH4）4（NiH6Mo6O（24））·5H2O.Heating of this intermediate at 120 ℃ removes the added water and produces ANM.Catalysts prepared by this method exhibit almost the same physicochemical properties and catalytic performance during the HDS of dibenzothiophene as materials made from ANM synthesized by a chemical precipitation procedure.Compared with traditional hydrothermal or chemical precipitation methods,this water-assisted,solid-state synthesis provides several significant advantages,including simplifying the synthetic procedure,reducing waste and energy costs and increasing product yields.These features will be highly important with regard to allowing the application of ANM in industrial-scale processes involving HDS reactions.This water-assisted,solid-state strategy can also be extended to the synthesis of isomorphous compounds such as ammonium cobalt（zinc and copper） molybdate.展开更多
Many difficult-to-cut materials such as Ni-base super alloy, titanium alloy, and austenite stainless steel which are used extensively in aerospace generally have high strength-to-weight ratios, high corrosion resistan...Many difficult-to-cut materials such as Ni-base super alloy, titanium alloy, and austenite stainless steel which are used extensively in aerospace generally have high strength-to-weight ratios, high corrosion resistance, high strength retention ability at elevated temperatures, and low thermal conductivity. These characteristics can result in uneven tool wear and chatter vibration. Therefore, determining the appropriate end-milling conditions is more difficult for difficult-to-cut materials than for other materials. There has been much research on the high-speed milling of difficult-to-cut materials, and effective end-milling conditions, end-mill tool shapes, and processing methods have been reported. In addition, irregular pitch and lead end-mills with different helix angles have been developed by tool maker＇s to reduce chatter vibration, making it easier to perform high-speed milling. However, there have been few reports of slotting information useful for determining appropriate end-milling conditions and processing methods for Ni-base super alloy. The aim of this study is to derive end-milling condition with high efficiency grooving process for Ni-base super alloy （Inconel 718） sheet. Effects of cutting parameters were examined from the view point of cutting resistance, ＂tool tip maximum temperature and tool flank wear width. As a result from experiments, if the grooving process condition of axial depth of cut is smaller than other conditions on the same material removable rate value, it has been found that it is possible to reduce the tool tip maximum temperature and prolong the tool life.展开更多
基金supported by the National Natural Science Fundation of China(U1162203,21106185)the Fundamental Research Funds for the Central Universities(15CX02023A,15CX06051A)Financial support from Petro China Corporation Limited~~
文摘This paper reports a sustainable,water-assisted,solid-state method for synthesizing ammonium nickel molybdate（（NH4）HNi2（OH）2（MoO4）2,ANM）,a precursor for an unsupported hydrodesulfurization（HDS） catalyst.The associated ANM formation mechanism is also discussed.The synthesis route consists of physical mixing of the raw materials,water-assisted grinding and heating.The formation mechanism involves replacement of a Mo atom by a Ni atom,generating the metastable intermediate（NH4）4（NiH6Mo6O（24））·5H2O.Heating of this intermediate at 120 ℃ removes the added water and produces ANM.Catalysts prepared by this method exhibit almost the same physicochemical properties and catalytic performance during the HDS of dibenzothiophene as materials made from ANM synthesized by a chemical precipitation procedure.Compared with traditional hydrothermal or chemical precipitation methods,this water-assisted,solid-state synthesis provides several significant advantages,including simplifying the synthetic procedure,reducing waste and energy costs and increasing product yields.These features will be highly important with regard to allowing the application of ANM in industrial-scale processes involving HDS reactions.This water-assisted,solid-state strategy can also be extended to the synthesis of isomorphous compounds such as ammonium cobalt（zinc and copper） molybdate.
文摘Many difficult-to-cut materials such as Ni-base super alloy, titanium alloy, and austenite stainless steel which are used extensively in aerospace generally have high strength-to-weight ratios, high corrosion resistance, high strength retention ability at elevated temperatures, and low thermal conductivity. These characteristics can result in uneven tool wear and chatter vibration. Therefore, determining the appropriate end-milling conditions is more difficult for difficult-to-cut materials than for other materials. There has been much research on the high-speed milling of difficult-to-cut materials, and effective end-milling conditions, end-mill tool shapes, and processing methods have been reported. In addition, irregular pitch and lead end-mills with different helix angles have been developed by tool maker＇s to reduce chatter vibration, making it easier to perform high-speed milling. However, there have been few reports of slotting information useful for determining appropriate end-milling conditions and processing methods for Ni-base super alloy. The aim of this study is to derive end-milling condition with high efficiency grooving process for Ni-base super alloy （Inconel 718） sheet. Effects of cutting parameters were examined from the view point of cutting resistance, ＂tool tip maximum temperature and tool flank wear width. As a result from experiments, if the grooving process condition of axial depth of cut is smaller than other conditions on the same material removable rate value, it has been found that it is possible to reduce the tool tip maximum temperature and prolong the tool life.
