A long-term （21-year） field experiment was performed to study the responses of soil inorganic P fractions and P availability to annual fertilizer P application in a calcareous soil on the Loess Plateau of China. Soi...A long-term （21-year） field experiment was performed to study the responses of soil inorganic P fractions and P availability to annual fertilizer P application in a calcareous soil on the Loess Plateau of China. Soil Olsen-P contents increased by 3.7, 5.2, 11.2 and 20.6 mg P kg-1 after 21-year annual fertilizer P application at 20, 39, 59, and 79 kg P ha-1, respectively. Long-term fertilizer P addition also increased soil total P and inorganic P （Pi） contents significantly. The contents of inorganic P fractions were in the order of Ca10-P 〉 Cas-P 〉 Fe-P 〉 A1-P 〉 occluded P 〉 Ca2-P in the soil receiving annual fertilizer P application. Fertilizer P application increased Cas-P, A1-P and Ca2-P contents as well as their percentages relative to Pi. Pi application increased Fe-P and occluded P contents but nor their percentages. Soil Ca10- P content remained unchanged after fertilizer P application while its percentage relative to Pi declined with increasing fertilizer P rate. All Pi fractions but Ca10-P were correlated with Olsen-P significantly. 90% of variations in Olsen-P could be explained by Pi fractions, and the direct contribution of Cas-P was predominant. Long-term annual superphosphate application would facilitate the accumulation of soil Cas-P, and thus improve soil P availability.展开更多
Tuite has been suggested as a potential reservoir for trace elements in the deep mantle,but no evidence confirms this supposition.By using a natural apatite as starting material,the trace-element-bearing tuite large c...Tuite has been suggested as a potential reservoir for trace elements in the deep mantle,but no evidence confirms this supposition.By using a natural apatite as starting material,the trace-element-bearing tuite large crystals were obtained under highpressure and high-temperature conditions(15 GPa and 1800 K).X-ray diffraction pattern and Micro-Raman spectrum of the run product confirm that tuite was synthesized.The concentrations of trace elements in tuite crystals were analyzed by laser ablation-inductively coupled plasma-mass spectrometry(LA-ICP-MS).The rare earth element patterns of tuite show enrichment of light rare earth elements relative to heavy rare earth elements.Tuite shows high concentrations of Th and Sr,and negative anomalies of Rb,Nb,and Hf.The results show that tuite can accommodate a large amount of trace elements.Tuite might be an important host to accommodate trace elements if there is much apatite subducted into the deep mantle.展开更多
基金Supported by the National Basic Research Program (973 Program) of China (No.2005CB121102)the Knowledge Innovation Program of the Chinese Academy of Sciences (No.kzcx2-yw-424)the National Natural Science Foundation of China (No.30500077)
文摘A long-term （21-year） field experiment was performed to study the responses of soil inorganic P fractions and P availability to annual fertilizer P application in a calcareous soil on the Loess Plateau of China. Soil Olsen-P contents increased by 3.7, 5.2, 11.2 and 20.6 mg P kg-1 after 21-year annual fertilizer P application at 20, 39, 59, and 79 kg P ha-1, respectively. Long-term fertilizer P addition also increased soil total P and inorganic P （Pi） contents significantly. The contents of inorganic P fractions were in the order of Ca10-P 〉 Cas-P 〉 Fe-P 〉 A1-P 〉 occluded P 〉 Ca2-P in the soil receiving annual fertilizer P application. Fertilizer P application increased Cas-P, A1-P and Ca2-P contents as well as their percentages relative to Pi. Pi application increased Fe-P and occluded P contents but nor their percentages. Soil Ca10- P content remained unchanged after fertilizer P application while its percentage relative to Pi declined with increasing fertilizer P rate. All Pi fractions but Ca10-P were correlated with Olsen-P significantly. 90% of variations in Olsen-P could be explained by Pi fractions, and the direct contribution of Cas-P was predominant. Long-term annual superphosphate application would facilitate the accumulation of soil Cas-P, and thus improve soil P availability.
基金financially supported by National Natural Science Foundation of China(Grant No.40973045)
文摘Tuite has been suggested as a potential reservoir for trace elements in the deep mantle,but no evidence confirms this supposition.By using a natural apatite as starting material,the trace-element-bearing tuite large crystals were obtained under highpressure and high-temperature conditions(15 GPa and 1800 K).X-ray diffraction pattern and Micro-Raman spectrum of the run product confirm that tuite was synthesized.The concentrations of trace elements in tuite crystals were analyzed by laser ablation-inductively coupled plasma-mass spectrometry(LA-ICP-MS).The rare earth element patterns of tuite show enrichment of light rare earth elements relative to heavy rare earth elements.Tuite shows high concentrations of Th and Sr,and negative anomalies of Rb,Nb,and Hf.The results show that tuite can accommodate a large amount of trace elements.Tuite might be an important host to accommodate trace elements if there is much apatite subducted into the deep mantle.
