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火焰原子吸收光谱法测定磷矿砂中铅 被引量:6
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作者 蔡泓 汪丰 曲强 《检验检疫科学》 2001年第6期36-36,38,共2页
根据Pb2 + 与Cl-在王水介质中可形成稳定络合阴离子 [PbCl4 ]2 -的原理 ,建立了火焰原子光谱直接测定磷矿砂中Pb的方法 ,研究了样品测定中化学干扰和光谱干扰的消除 ,考察了溶样条件中酸介质和温度的影响 ,方法简便 ,快速 ,省略了日本... 根据Pb2 + 与Cl-在王水介质中可形成稳定络合阴离子 [PbCl4 ]2 -的原理 ,建立了火焰原子光谱直接测定磷矿砂中Pb的方法 ,研究了样品测定中化学干扰和光谱干扰的消除 ,考察了溶样条件中酸介质和温度的影响 ,方法简便 ,快速 ,省略了日本方法中繁琐的溶样、萃取步骤 ,加标回收率为 90 .2~ 111.3% ,RSD %为 1.75和 5 .2 3%。 展开更多
关键词 火焰原子吸收光谱法 测定 磷矿砂 精密度 酸介质
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冷原子吸收法测定磷矿石中的汞含量 被引量:2
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作者 张碧玲 《中国非金属矿工业导刊》 2016年第4期18-18,25,共2页
我国云南、贵州盛产磷矿,由于进口国对环保的要求,出口的磷矿石中要求检测汞的含量。在现行的国标和行业标中,没有相应的检测规范。参考有关文献资料,试样采用盐酸—硝酸分解,在高锰酸钾存在下,汞转化为二价,用盐酸羟胺还原过剩的氧化剂... 我国云南、贵州盛产磷矿,由于进口国对环保的要求,出口的磷矿石中要求检测汞的含量。在现行的国标和行业标中,没有相应的检测规范。参考有关文献资料,试样采用盐酸—硝酸分解,在高锰酸钾存在下,汞转化为二价,用盐酸羟胺还原过剩的氧化剂,在酸性介质中用二氧化锡将二价汞还原为金属汞,用冷原子吸收法,波长在253.7nm处进行测量,方法简单、快捷。 展开更多
关键词 磷矿砂 冷原子吸收
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Utilization of Nano Rock Phosphate by Maize (Zea mays L.) Crop in a Vertisol of Central India
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作者 Tapan Adhikari Samaresh Kundu Vasudeb Meena Anangi Subba Rao 《Journal of Agricultural Science and Technology(A)》 2014年第5期384-394,共11页
An attempt was made in the present investigation to utilize the vast deposit of rock phosphate (RP) of India by preparing nano RP using modem tool of nano-science and nano-technology for field application to maize c... An attempt was made in the present investigation to utilize the vast deposit of rock phosphate (RP) of India by preparing nano RP using modem tool of nano-science and nano-technology for field application to maize crop (Zea mays L.). To evaluate the efficacy of different nano RP, a field experiment was conducted during kharif season (June to September) of 2012 at India Institute of Soil Science (IISS), Bhopal, taking maize as a test crop. The experiment consisted of five treatments (control, NK (100%), NPK (100%), NK (I00%) + 60 kg P205) as nano RP through Udaipur nano RP (34% P205) and Udaipur nano RP (31% P205) were tested in randomized block design with four replications. The results showed that the shelling percentage, 1,000 grain weight, grain and stover yield, etc., were significantly higher in the maize plant treated with Udaipur nano RP (34% P205) as compared to the control, which was being at par with single super phosphate (SSP) treated plants. The total P content and its uptake were higher (0.65% and 40.29 kg/ha) in SSP treated plant, which was closely followed by Udaipur nano RP 34% (0.63% and 38.29 kg/ha) over the control (0.60% and 27.82 kg/ha). The SSP treated plants had significantly highest apparent P recovery (47.98%) which was comparable to Udaipur nano RP (34% P205), where as the Udaipur nano RP (31% P205) had the lowest. The additional N and K uptake by the plant was also observed with application of P sources, which were ranged from 16.5 kg/ha to 37.2 kg/ha and 27.9 kg/ha to 64.7 kg/ha under different P treatments. These results showed that crop utilization of P from nano RP was at par with that of P from SSP while yield response to P from nano RP was marginally lower than to P from SSP but serve as a cheaper source. 展开更多
关键词 Nano RP P uptake biomass yield apparent phosphorus recovery.
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