A new open-framework zincophosphite, Zn2(HPO3)3H2DACH 1, was hydro- thermally synthesized in the presence of 1,2-diaminocyclohexane (DACH) as structure-directing agent. Its structure was determined by single-crystal X...A new open-framework zincophosphite, Zn2(HPO3)3H2DACH 1, was hydro- thermally synthesized in the presence of 1,2-diaminocyclohexane (DACH) as structure-directing agent. Its structure was determined by single-crystal X-ray diffraction and further characterized by FTIR, elemental analysis, powder X-ray diffraction and thermogravimetric analysis. Crystal data for 1: Mr = 486.88, monoclinic, space group P21/c with a = 10.2287(11), b = 9.7624(11), c = 16.1686(18) , b = 92.573(2), V = 1612.9(3) 3, Z = 4, Dc = 2.005 g/cm3, F(000) = 984, = 3.314 mm-1 and S = 1.152. The final R = 0.0473 and wR = 0.1121 for 2456 observed reflections with I > 2s(I). The inorganic layer consisting of four- and eight-membered rings is constructed of alternating ZnO4 tetrahedra and HPO3 pseudo pyramids by sharing vertices. The organic template molecules reside in the interlayer region and interact with the inorganic network through H-bonds.展开更多
基金This work was supported by the NNSFC (No. 20271050 and 20171045) the Ministry of China and the Talents Program of the Chinese Academy of Sciences and the NSF(E0210029) of Fujian province.
文摘A new open-framework zincophosphite, Zn2(HPO3)3H2DACH 1, was hydro- thermally synthesized in the presence of 1,2-diaminocyclohexane (DACH) as structure-directing agent. Its structure was determined by single-crystal X-ray diffraction and further characterized by FTIR, elemental analysis, powder X-ray diffraction and thermogravimetric analysis. Crystal data for 1: Mr = 486.88, monoclinic, space group P21/c with a = 10.2287(11), b = 9.7624(11), c = 16.1686(18) , b = 92.573(2), V = 1612.9(3) 3, Z = 4, Dc = 2.005 g/cm3, F(000) = 984, = 3.314 mm-1 and S = 1.152. The final R = 0.0473 and wR = 0.1121 for 2456 observed reflections with I > 2s(I). The inorganic layer consisting of four- and eight-membered rings is constructed of alternating ZnO4 tetrahedra and HPO3 pseudo pyramids by sharing vertices. The organic template molecules reside in the interlayer region and interact with the inorganic network through H-bonds.
