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水分子和离子在地聚合物胶凝材料中的分子动力学研究 被引量:2
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作者 张景林 徐小倩 +7 位作者 侯东帅 陈际洲 金祖权 李绍纯 苗吉军 刘俊伟 张鹏 王鹏刚 《硅酸盐通报》 CAS 北大核心 2020年第2期383-388,共6页
地聚合物是一种具有三维网状结构的水泥基胶凝材料,其主要水化产物是水合硅酸铝钠凝胶(NASH)。在工程应用中,氯盐侵蚀与硫酸盐侵蚀是影响耐久性的主要原因。运用分子动力学方法,研究NaCl溶液与Na2SO4溶液在NASH凝胶纳米孔道中的传输特... 地聚合物是一种具有三维网状结构的水泥基胶凝材料,其主要水化产物是水合硅酸铝钠凝胶(NASH)。在工程应用中,氯盐侵蚀与硫酸盐侵蚀是影响耐久性的主要原因。运用分子动力学方法,研究NaCl溶液与Na2SO4溶液在NASH凝胶纳米孔道中的传输特性。结果表明,NaCl溶液与Na2SO4溶液在凝胶孔道的非饱和传输过程中,呈现出明显的毛细吸附现象,NASH凝胶界面呈现亲水性与电负性。Na2SO4溶液的侵入速率明显低于NaCl溶液,硫酸根离子对水分子侵入的抑制作用强于氯离子。 展开更多
关键词 地聚合物 NASH凝胶 NACL溶液 Na2SO4溶液 离子传输特性
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Ion-transport characteristics of new-old concrete composite system 被引量:4
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作者 龙广成 谢友均 +1 位作者 丁巍巍 Ahmed OMRAN 《Journal of Central South University》 SCIE EI CAS 2014年第2期790-798,共9页
New-old concrete composite system usually exists in concrete repairing structure.In the present work,series of experiments were carried out to investigate permeability and ion diffusion properties of new-old concrete ... New-old concrete composite system usually exists in concrete repairing structure.In the present work,series of experiments were carried out to investigate permeability and ion diffusion properties of new-old concrete composite by measuring 6-hour coulomb charge and chloride diffusivity.The interrelation among transport properties of new-old composites,new,and old concretes was also discussed.Results indicate that the permeability and chloride diffusivity of new-old concrete composite system closely interrelate to the corresponding new concrete and old concrete.The interfacial transition zone between new concrete and old concrete greatly influences the transport property of new-old concrete system.Compared with the corresponding new concrete and old concrete lower permeability and diffusivity values for the new-old concrete composites can be achieved by choosing suitable new concrete.It is possible to design the tailor-made new-old concrete composite system for repair given the transport property. 展开更多
关键词 new-old concrete composite chloride diffusivity PERMEABILITY transport property
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Sensing characteristics of a metal film coated long-period fiber grating
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作者 WANG Yan LIU Jia-ping +2 位作者 LIU Ji-hong HU Xing-liu FANG Ting 《Journal of Measurement Science and Instrumentation》 CAS CSCD 2017年第1期89-96,共8页
To obtain the influence rules of the coating parameters of a long-period fiber grating(LPFG)with respect to temperature,strain and refractive index sensing properties,based on the mode coupling theory,a strict four-la... To obtain the influence rules of the coating parameters of a long-period fiber grating(LPFG)with respect to temperature,strain and refractive index sensing properties,based on the mode coupling theory,a strict four-layer theorietical model of a metal film coated LPFG is established,and these parameters that affect the spectral characteristics of the metal film coated LPFG are studied.The simulation results show that there is an optimal metal film thickness on the surface of the LPFG that will induce the surface-plasmon resonance(SP R)effect,which results in higher sensitivity to the environmental temperature and refractive index but has little influence on the strain There is theoretical evidence that when the silver thickness is between0.8and1.2nm,the refractive index sensitivity will reach the peak point of42.4026,at which the refractive index sensor sensitivity is increased by4.S%.The theoretical results of coating a long-period fiber grating provide a good theoretical basis and guidance for LPFG design and parameters optimization 展开更多
关键词 metal film coated long-period fiber grating (L P FG ) surface plasmon resonance (SP R ) transmission spectrum sensing characteristics
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Ionic effects on the transport characteristics of nanowire-based FETs in a liquid environment
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作者 Daijiro Nozaki Jens Kunstmann +5 位作者 Felix Zorgiebel Sebastian Pregl Larysa Baraban Walter M. Weber Thomas Mikolajick Gianaurelio Cuniberti 《Nano Research》 SCIE EI CAS CSCD 2014年第3期380-389,共10页
For the development of ultra-sensitive electrical bio/chemical sensors based on nanowire field effect transistors (FETs), the influence of the ions in the solution on the electron transport has to be understood. For... For the development of ultra-sensitive electrical bio/chemical sensors based on nanowire field effect transistors (FETs), the influence of the ions in the solution on the electron transport has to be understood. For this purpose we establish a simulation platform for nanowire FETs in the liquid environment by implementing the modified Poisson-Boltzmann model into Landauer transport theory. We investigate the changes of the electric potential and the transport characteristics due to the ions. The reduction of sensitivity of the sensors due to the screening effect from the electrolyte could be successfully reproduced. We also fabricated silicon nanowire Schottky-barrier FETs and our model could capture the observed reduction of the current with increasing ionic concentration. This shows that our simulation platform can be used to interpret ongoing experiments, to design nanowire FETs, and it also gives insight into controversial issues such as whether ions in the buffer solution affect the transport characteristics or not. 展开更多
关键词 nanowire field effecttransistors (FETs) biosensors silicon nanowires Poisson-Boltzmann theory Landauer model
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