负离子与离子化系统

空气负离子是存在于大气中的一种自然物质,它是由于阳光照射、宇宙射线以及风雷雨电等的作用而产生。自然界的各种物理、电气现象使大量的游离子空气中的电子与氧分子结合成为负氧离子,在氧原子内的外层有两个不成偶的电子在运动。

一种光离子化检测系统的设计与实验研究

开发了基于高灵敏度电离室检测技术的通用型光离子化检测器。对光离子化检测器的核心部分进行了分析与设计,着重阐述了系统设计的原则、结构及特性。利用配制的标准气体和PID检测仪进行联测优化和线性度测量,并给出了仪器实验性能的实例。证明了该光离子化检测系统的确能够检测特定极低浓度的有机化合物,并且可以区分不同梯度的同种样品。

A non-invasive method for gastrointestinal parameter monitoring

AIM: To propose a new, non-invasive method for monitoring 24-h pressure, temperature and pH value in gastrointestinal tract.METHODS: The authors developed a miniature, multifunctional gastrointestinal monitoring system, which comprises a set of indigestible biotelemetry capsules and a data recorder.The capsule, after ingested by patients, could measure pressure, temperature and pH value in the gastrointestinal tract and transmit the data to the data recorder outside the body through a 434 MHz radio frequency data link. After the capsule passed out from the body, the data saved in the recorder were downloaded to a workstation via a special software for further analysis and comparison.RESULTS: Clinical experiments showed that the biotelemetry capsules could be swallowed by volunteers without any difficulties. The data recorder could receive the radio frequency signals transmitted by the biotelemetry in the body. The biotelemetry capsule could pass out from the body without difficulties. No discomfort was reported by any volunteer during the experiment. In vivo pressure and temperature data were acquired.CONCLUSION: A non-invasive method for monitoring 24-h gastrointestinal parameters was proposed and tested by the authors. The feasibility and functionality of this method are verified by laboratory tests and clinical experiments.

A new primal-dual path-following interior-point algorithm for linearly constrained convex optimization

In this paper, a primal-dual path-following interior-point algorithm for linearly constrained convex optimization(LCCO) is presented.The algorithm is based on a new technique for finding a class of search directions and the strategy of the central path.At each iteration, only full-Newton steps are used.Finally, the favorable polynomial complexity bound for the algorithm with the small-update method is deserved, namely, O(√n log n /ε).

Carbon dioxide induced degradation of diethanolamine during absorption and desorption processes

Alkanolamines are widely used in the purification of the sourgas sweetening process. During the sour gas absorption process, CO_2 significantly degrades the amine solvent and creates enormous problems for plant operation. In this work, CO_2 induced degradation of aqueous diethanolamine(DEA) solution was conducted in a 1.25 L jacketed glass reactor that functioned as an absorber and stripper at atmospheric conditions. Pure CO_2 was bubbled through the reactor until the solution became saturated. In this study, the concentrations of DEA used were in the range of concentrations between 2 mol·L^(-1) and 4 mol·L^(-1). In the degradation experiment, six generic cycles were conducted for each run. Each cycle was configured with the absorption and desorption of carbon dioxide at 55 ℃ and 100 ℃, respectively. Samples were collected after a predetermined experimental time and analyzed by ion chromatography(IC) to identify unknown ionic degradation products(DGPs). In the IC analysis, three different columns were used for anion, cation and ion exclusion systems, which are Metrosep A Supp 5150/4.0, Metrosep C Supp 4 150/4.0 and Metrosep Organic Acids, respectively. The major identified DGPs of D01 DEA2 M, D02 DEA3 M, and D03 DEA4 M are nitrite, acetate and ammonium. Phosphate product was found in the degraded amine samples which might be due to the contamination of water or chromatographic system.

Variation in soil properties in a transformed ecosystem in Southwestern Nigeria

Variation in soil properties as a result of the conversion of the tropical rainforest to a monospecific plantation of teak, tectona grandis, was examined in Akure forest reserve in Southwestern Nigeria. Comparison was made in the active rooting zone of 50 cm soil depth. It was discovered that there were no significant differences in the physical properties except in the value of organic matter content at the top 10 cm layer but chemical properties such as the pH and organic carbon changed significantly at the top 10 cm layer. Differences in other chemical properties, such as the available P, exchangeable cations K, Ca and Mg, the exchangeable acidity and the cation exchange capacity were minor. This showed that no nutrient was limiting or was likely to be limiting in the soil for subsequent short rotation of plantation development.

Reductive dechlorination of polychlorinated biphenyls is coupled to nitrogen fixation by a legume-rhizobium symbiosis

Chlorinated persistent organic pollutants, including polychlorinated biphenyls （PCBs）, represent a particularly serious environmental problem and human health risk worldwide. Leguminous plants and their symbiotic bacteria （rhizobia） are important components of the biogeochemical cycling of nitrogen in both agricultural and natural ecosystems. However, there have been relatively few detailed studies of the remediation of PCB-contaminated soils by legume-rhizobia symbionts. Here we report for the first time evidence of the reductive dechlorination of 2,4,4＇-trichlorobiphenyl （PCB 28） by an alfalfa-rhizobium nitrogen fixing symbiont. Alfalfa （Medicago sativa L.） inoculated with wild-type Sinorhizobiurn meliloti had significantly larger biomass and PCB 28 accumulation than alfalfa inoculated with the nitrogenase negative mutant rhizobium SmY. Dechlorination products of PCB 28, 2,4＇-dichlorobiphenyl （PCB 8）, and the emission of chloride ion （C1-） were also found to decrease significantly in the ineffective nodules infected by the mutant strain SmY. We therefore hypothesize that N2-fixation by the legume-rhizobium symbiont is coupled with the reductive dechlorination of PCBs within the nodules. The combination of these two processes is of great importance to the biogeochemical cycling and bioremediation of organochlorine pollutants in terrestrial ecosystems.

Chemical oscillations in the metal ion-catalyzed bromate-4-aminophenol reaction

Temporal oscillations of the bromate-4-aminophenol system have been studied in the presence of four different catalysts： tris（1,10-phenanthroline）iron（Ⅱ） sulfate （ferroin）, Ce（Ⅲ）, Mn（Ⅱ）, and Fe（Ⅱ）. Transient temporal oscillations were observed in the four catalyzed systems when the reactions were conducted in a stirred batch reactor. The induction time was prolonged by the presence of ferroin, but it was shortened in the Ce（Ⅲ）- and Mn（Ⅱ）-catalyzed systems. On the other hand, the number of peaks was significantly decreased in the presence of ferroin. The development of oscillatory behaviour was found to be more sensitive to the ratio of bromate and 4-aminophenol concentration than to their absolute concentrations. The reaction rates of 4-aminophenol with Ce（IV） and 4-aminophenol with ferritin were measured directly by spectroscopic methods in a sulfuric acid medium.