受阻Lewis酸碱对(Frustrated Lewis Pairs,FLPs)是一类具有特殊反应活性的Lewis酸碱对。自发现以来,FLPs受到了广泛关注并在许多领域崭露头角。本文对FLPs在不对称氢化、高分子聚合、CO_2催化还原等应用领域取得的突破进行了介绍;同时...受阻Lewis酸碱对(Frustrated Lewis Pairs,FLPs)是一类具有特殊反应活性的Lewis酸碱对。自发现以来,FLPs受到了广泛关注并在许多领域崭露头角。本文对FLPs在不对称氢化、高分子聚合、CO_2催化还原等应用领域取得的突破进行了介绍;同时对过渡金属FLPs和FLPs配位的过渡金属催化体系进行了综述;最后对FLPs领域未来的发展前景进行了展望。展开更多
Acrylonitrile (AN) was copolymerized with N-isopropylacrylamide (NIPA) to synthesize thermosensitive hy-drogels, and the on-off switch behavior of poly(NIPA-co-AN) hydrogels with different fraction of hydrophobic comp...Acrylonitrile (AN) was copolymerized with N-isopropylacrylamide (NIPA) to synthesize thermosensitive hy-drogels, and the on-off switch behavior of poly(NIPA-co-AN) hydrogels with different fraction of hydrophobic compo-nent (AN) was investigated. It is found that the lower critical solution temperature (LCST), the swelling ratio at certain temperature and the reswelling rate of poly(NIPA-co-AN) hydrogels decreased as AN unit fraction in copolymers in-creased. In order to improve the responsive rate of poly(NIPA-co-AN) hydrogels, they were further treated by surface crosslinking using N, N′-methylene bisacrylamide (BIS) as a crosslinking agent. The swelling and deswelling behaviors of these copolymers were compared with those of the untreated hydrogels. The results indicated that the responsive rate of poly(NIPA-co-AN) hydrogel was improved by surface crosslinking. The resulting hydrogels bearing cyano groups with fast response have potential applications in the field of drug-controlled release and immobilization of biomolecules.展开更多
文摘受阻Lewis酸碱对(Frustrated Lewis Pairs,FLPs)是一类具有特殊反应活性的Lewis酸碱对。自发现以来,FLPs受到了广泛关注并在许多领域崭露头角。本文对FLPs在不对称氢化、高分子聚合、CO_2催化还原等应用领域取得的突破进行了介绍;同时对过渡金属FLPs和FLPs配位的过渡金属催化体系进行了综述;最后对FLPs领域未来的发展前景进行了展望。
文摘Acrylonitrile (AN) was copolymerized with N-isopropylacrylamide (NIPA) to synthesize thermosensitive hy-drogels, and the on-off switch behavior of poly(NIPA-co-AN) hydrogels with different fraction of hydrophobic compo-nent (AN) was investigated. It is found that the lower critical solution temperature (LCST), the swelling ratio at certain temperature and the reswelling rate of poly(NIPA-co-AN) hydrogels decreased as AN unit fraction in copolymers in-creased. In order to improve the responsive rate of poly(NIPA-co-AN) hydrogels, they were further treated by surface crosslinking using N, N′-methylene bisacrylamide (BIS) as a crosslinking agent. The swelling and deswelling behaviors of these copolymers were compared with those of the untreated hydrogels. The results indicated that the responsive rate of poly(NIPA-co-AN) hydrogel was improved by surface crosslinking. The resulting hydrogels bearing cyano groups with fast response have potential applications in the field of drug-controlled release and immobilization of biomolecules.
