有效介质理论离子导电模型的修正

针对现有有效介质理论(EMT)导电模型存在的问题和不足,通过对复合固态聚合物电解质(CSPE)导电性增强机制的分析,引入新的无机填料界面层离子导电模型及模型参数,对EMT离子导电模型进行修正。采用原位复合法制备聚环氧乙烷(PEO)基聚合物电解质,通过实验测定样品离子电导率与无机填料SiO2含量之间的关系,应用现有的EMT离子导电模型和修正后的EMT离子导电模型分别对样品的离子电导率与无机填料含量关系进行计算,将计算数值与实验数值进行比较。结果表明,修正后的EMT离子导电模型的计算值与实验值吻合较好。

离子导电模型的分析与探讨

有关电解液中离子导电问题，一直使许多师生感到困惑，其根源在于缺乏理性思考，对离子导电模型认识不清，误认为离子导电中的电流总是单向离子电流的二倍。本文通过探究联想提出离子导电模型，建立清晰的物理图景，以释疑解惑。

混合液地层水电阻率反演在水淹层评价中的应用

注水开发油田由于注入水与原生地层水矿化度的差异导致储层地层水电阻率发生变化,准确计算混合液地层水电阻率对正确评价剩余油饱和度、划分水淹级别至关重要。通过不同体积、不同矿化度溶液混合实验分析了混合液地层水电阻率的变化规律及其影响因素,提出了混合液地层水离子导电模型,结合饱和度模型,利用最优化算法,通过约束迭代反演得到混合液地层水电阻率以及剩余油饱和度和束缚水饱和度。该方法应用于渤海SZ油田综合调整阶段水淹层定量评价中,经密闭取心、生产动态验证,计算结果可信,对渤海油田大井距复杂水淹层定量评价具有一定的指导意义。

Efficient Thickness of Solid Oxide Fuel Cell Composite Electrode

The efficient thickness of a composite electrode for solid oxide fuel cells was directly calculated by developing a physical model taking into account of the charge transfer process, the oxygen ion and electron transportation, and the microstructure characteristics of the electrode. The efficient thickness, which is defined as the electrode thickness corresponding to the minimum electrode polarization resistance, is formulated as a function of charge transfer resistivity, effective resistivity to ion and electron transport, and three-phase boundary length per unit volume. The model prediction is compared with the experimental reports to check the validity. Simulation is performed to show the effect of microstructure, intrinsic material properties, and electrode reaction mechanism on the efficient thickness. The results suggest that when an electrode is fabricated, its thickness should be controlled regarding its composition, particle size of its components, the intrinsic ionic and electronic conductivities,and its reaction mechanisms as well as the expected operation temperatures. The sensitivity of electrode polarization resistance to its thickness is also discussed.