The construction of novel inorganic‐organic hybrid nanomaterials for synchronous photocatalyticremoval of heavy metal ions and organic pollutants has received significant attention.We successfullysynthesized gold‐lo...The construction of novel inorganic‐organic hybrid nanomaterials for synchronous photocatalyticremoval of heavy metal ions and organic pollutants has received significant attention.We successfullysynthesized gold‐loaded graphene oxide/PDPB(polymer poly(diphenylbutadiyne))composites(Au‐GO/PDPB)through a facile mechanical agitation and photoreduction method.The compositeswere characterized by XPS and TEM images,which confirmed the presence of GO and Au nanoparticleson the PDPB.The as‐prepared Au‐GO/PDPB composites displayed enhanced photocatalytic activity compared with that of pure PDPB for the synchronous photoreduction of hexavalent chromium(Cr(VI))and photo‐oxidation of phenol.We also determined the optimal loading mass of GO and Au nanoparticles on the PDPB;the Au1‐GO2/PDPB(2.0wt%GO and1.0wt%Au)composite displayed the best photocatalytic activity among all the catalysts.Our study provides a facile way to prepare inorganic‐organic composites for the synchronous photocatalytic removal of heavy metal ions and organic pollutants.?2018,Dalian Institute of Chemical Physics,Chinese Academy of Sciences.Published by Elsevier B.V.All rights reserved.展开更多
Adsorption of Cr(Ⅵ) and p-chloroaniline on three typical soil colloids and pH influence were studied using batch equilibrium method. Both of Cr(Ⅵ) and p-chloroaniline adsorption on the colloids could be well describ...Adsorption of Cr(Ⅵ) and p-chloroaniline on three typical soil colloids and pH influence were studied using batch equilibrium method. Both of Cr(Ⅵ) and p-chloroaniline adsorption on the colloids could be well described by general adsorption simulation equations. The adsorption processes changed with media pH. When Cr(Ⅵ) and p-chloroaniline coexisted on soil colloids, their interactions could be observed in a certain pH range to be accompanied with Cr(Ⅵ) reduction, which clearly suggested that a surface catalytic reaction occurred in this system. Soil colloid acted as an efficient catalyst for the interaction of Cr(Ⅵ) and p-chloroaniline. The pH values at which no interaction was observed were 4.0, 4.5 and 5.0 for the colloids of indigotic black soil, yellow-brown soil and latosol, respectively. Capillary electrophoresis used to analyze p-chloroaniline provided a high separation efficiency and short separation time, and needed no more extensive pretreatment of samples.展开更多
Magnetic ion exchange(MIEX) resins have received considerable attention in drinking water treatment due to their fast and efficient removal of dissolved organic carbon(DOC). Two types of mechanisms, i.e., ion exchange...Magnetic ion exchange(MIEX) resins have received considerable attention in drinking water treatment due to their fast and efficient removal of dissolved organic carbon(DOC). Two types of mechanisms, i.e., ion exchange,reversible and irreversible adsorption, may occur during pollutants removal by MIEX. This work examined the removal mechanism of 17α-Ethinylestradiol(EE2) by MIEX. As one of typical estrogen micro-pollutants,EE2 existed as neutral molecule in natural water, and its charge density was close to zero [(0.00000219 ±0.00000015) meq·(μg EE2)^(-1)] based on the potentiometric titration method. However, the removal of EE2 by MIEX was much higher than that of other micro-pollutants previously reported. Multi-cycle adsorptionregeneration experiments and ion exchange stoichiometry analysis were conducted to elucidate the removal mechanism of EE2 by MIEX resin. The results suggested that the main removal mechanism of EE2 by MIEX was ion exchange instead of reversible micro-pore adsorption. The experimental analysis based on Donnan theory indicated that the internal micro-environment of resin beads was alkaline, in the alkaline environment EE2 would be ionized into negatively charged groups. As a result, ion exchange reaction occurred inside the pore of MIEX resin, and the removal process of EE2 by MIEX was dominated by the ion exchange reaction.展开更多
The effect of chloride on the atmospheric corrosion of cast iron in sulphur or nitrogen-bearing pollutant was investigated by using periodic wet-dry test, electrochemical experiment and surface tension test. Scanning ...The effect of chloride on the atmospheric corrosion of cast iron in sulphur or nitrogen-bearing pollutant was investigated by using periodic wet-dry test, electrochemical experiment and surface tension test. Scanning electron microscopy coupled with energy dispersive atomic （EDAX） and stereoscopic microscopy was used to identify the corrosion processes and products. Cl^- and NO3^- were shown accelerating effects during the whole corrosion process but depression effects were observed in Cl^- and HSO3^- bearing pollutant at the initial corrosion stage. However, with the corrosion going on, the depression effects was less obviously and the initial corrosion process was investigated from the viewpoint of surface activity. At the initial corrosion stage, the corrosion rate was proportional to the adsorptivity of anions, but as corrosion went on, the penetration effect of anions and different characteristics of the corrosion products began to dominate the corrosion process, which led to changes on the corrosion rate.展开更多
Filters filled with a micelle-clay complex mixed with sand were employed to investigate their purification capability of tertiary treated wastewater with loose UF-membranes. The UF membrane was hollow fiber with a mol...Filters filled with a micelle-clay complex mixed with sand were employed to investigate their purification capability of tertiary treated wastewater with loose UF-membranes. The UF membrane was hollow fiber with a molecular weight cutoff of 100 kD. The complex was prepared from the organic cation octadecyltrimethylammonium （ODTMA） and the negatively charged clay-mineral, montmoriIIonite. This complex has a very large surface area, which includes large hydrophobic domains and is positively charged, about half of the cation exchange capacity of the clay. Two sets of filtration experiments were carried out at flow rates of 1.2 and 50 mL/min, which correspond to flow velocities of 3.7 and 153 cm/h, respectively. In the first case, after a passage of 1 L, the turbidity, total suspended solids （TSS）, fecal coliforms （FC）, and total coliforms （TC） were reduced to zero from 14 NTU, 6 ppm, 350 and 10,000 counts per 100 mL, respectively. In the second case, the numbers of FC and TC were reduced from 50,000/100 mL to zero after the passage of 14 L. The values of COD and BOD were reduced several-fold. The conclusion is that the incorporation of micelle-clay filters in the sewage treatment system with loose tertiary capability is promising and warrants larger scale experiments for optimization of the overall system.展开更多
The nexus between water, food and energy is one of the most fundamental relationships and challenges for society. Indeed, seepage of wastes stored into dumping sites of Edea township, favor their lixiviation. Soluble ...The nexus between water, food and energy is one of the most fundamental relationships and challenges for society. Indeed, seepage of wastes stored into dumping sites of Edea township, favor their lixiviation. Soluble components of matter are slowly dissolves, drained by meteoric water and flowed into tail bay vicinity. Knowledge of trace and toxic metal concentrations in the biotic matrices is important for assessing the effects of pollutants and the risk of exposure. In this study, A1, Mn, Cd, Cr, Cu, Pb and Zn were quantified respectively in 33 samples of soil and water, using ICP-MS （Inductively Coupled Plasma Mass Spectrometry）, Pb were found between 1.38-88.28 mg/L. Higher concentrations of Al were found in Alucam industrial wastes （315,502.33 mg/kg）, and in Hysacam domestic wastes （54,126.93 mg/kg）. Concentrations of Cd （1.955 mg/kg）, Pb （469.00 mg/kg） and Zn （853.00 rng/kg） are higher in domestic wastes. The ones of Mn （696.96 mg/kg） and Cu （1,320.10 mg/kg） are higher in industrial wastes. Higher concentrations of Pb and Cu let assume that it is a risk of poisoning relative to these elements around this area. These findings illustrate that lixiviation of dumping wastes has great influence on water and soils pollutions of the study ecosystem.展开更多
基金supported by the National Natural Science Foundation of China(21577036,21377038,21237003,21677048)the National Basic Research Program of China(973 Program,2013CB632403)+1 种基金State Key Research Development Program of China(2016YFA0204200)the Fundamental Research Funds for the Central Universities(22A201514021)~~
文摘The construction of novel inorganic‐organic hybrid nanomaterials for synchronous photocatalyticremoval of heavy metal ions and organic pollutants has received significant attention.We successfullysynthesized gold‐loaded graphene oxide/PDPB(polymer poly(diphenylbutadiyne))composites(Au‐GO/PDPB)through a facile mechanical agitation and photoreduction method.The compositeswere characterized by XPS and TEM images,which confirmed the presence of GO and Au nanoparticleson the PDPB.The as‐prepared Au‐GO/PDPB composites displayed enhanced photocatalytic activity compared with that of pure PDPB for the synchronous photoreduction of hexavalent chromium(Cr(VI))and photo‐oxidation of phenol.We also determined the optimal loading mass of GO and Au nanoparticles on the PDPB;the Au1‐GO2/PDPB(2.0wt%GO and1.0wt%Au)composite displayed the best photocatalytic activity among all the catalysts.Our study provides a facile way to prepare inorganic‐organic composites for the synchronous photocatalytic removal of heavy metal ions and organic pollutants.?2018,Dalian Institute of Chemical Physics,Chinese Academy of Sciences.Published by Elsevier B.V.All rights reserved.
文摘Adsorption of Cr(Ⅵ) and p-chloroaniline on three typical soil colloids and pH influence were studied using batch equilibrium method. Both of Cr(Ⅵ) and p-chloroaniline adsorption on the colloids could be well described by general adsorption simulation equations. The adsorption processes changed with media pH. When Cr(Ⅵ) and p-chloroaniline coexisted on soil colloids, their interactions could be observed in a certain pH range to be accompanied with Cr(Ⅵ) reduction, which clearly suggested that a surface catalytic reaction occurred in this system. Soil colloid acted as an efficient catalyst for the interaction of Cr(Ⅵ) and p-chloroaniline. The pH values at which no interaction was observed were 4.0, 4.5 and 5.0 for the colloids of indigotic black soil, yellow-brown soil and latosol, respectively. Capillary electrophoresis used to analyze p-chloroaniline provided a high separation efficiency and short separation time, and needed no more extensive pretreatment of samples.
基金Supported by the National Natural Science Foundation of China(51678408,51478314,51638011)the National Key Research and Development Program of China(2016YFC0400506)+1 种基金the Natural Science Foundation of Tianjin(14JCQNJC09000)the Research Fund of Tianjin Key Laboratory of Aquatic Science and Technology(TJKLASTZD-2016-06)
文摘Magnetic ion exchange(MIEX) resins have received considerable attention in drinking water treatment due to their fast and efficient removal of dissolved organic carbon(DOC). Two types of mechanisms, i.e., ion exchange,reversible and irreversible adsorption, may occur during pollutants removal by MIEX. This work examined the removal mechanism of 17α-Ethinylestradiol(EE2) by MIEX. As one of typical estrogen micro-pollutants,EE2 existed as neutral molecule in natural water, and its charge density was close to zero [(0.00000219 ±0.00000015) meq·(μg EE2)^(-1)] based on the potentiometric titration method. However, the removal of EE2 by MIEX was much higher than that of other micro-pollutants previously reported. Multi-cycle adsorptionregeneration experiments and ion exchange stoichiometry analysis were conducted to elucidate the removal mechanism of EE2 by MIEX resin. The results suggested that the main removal mechanism of EE2 by MIEX was ion exchange instead of reversible micro-pore adsorption. The experimental analysis based on Donnan theory indicated that the internal micro-environment of resin beads was alkaline, in the alkaline environment EE2 would be ionized into negatively charged groups. As a result, ion exchange reaction occurred inside the pore of MIEX resin, and the removal process of EE2 by MIEX was dominated by the ion exchange reaction.
基金Supported by the National Key Technologies R&D Program of the Tenth 5-year Plan Period (No. 2001BA805B01).
文摘The effect of chloride on the atmospheric corrosion of cast iron in sulphur or nitrogen-bearing pollutant was investigated by using periodic wet-dry test, electrochemical experiment and surface tension test. Scanning electron microscopy coupled with energy dispersive atomic （EDAX） and stereoscopic microscopy was used to identify the corrosion processes and products. Cl^- and NO3^- were shown accelerating effects during the whole corrosion process but depression effects were observed in Cl^- and HSO3^- bearing pollutant at the initial corrosion stage. However, with the corrosion going on, the depression effects was less obviously and the initial corrosion process was investigated from the viewpoint of surface activity. At the initial corrosion stage, the corrosion rate was proportional to the adsorptivity of anions, but as corrosion went on, the penetration effect of anions and different characteristics of the corrosion products began to dominate the corrosion process, which led to changes on the corrosion rate.
文摘Filters filled with a micelle-clay complex mixed with sand were employed to investigate their purification capability of tertiary treated wastewater with loose UF-membranes. The UF membrane was hollow fiber with a molecular weight cutoff of 100 kD. The complex was prepared from the organic cation octadecyltrimethylammonium （ODTMA） and the negatively charged clay-mineral, montmoriIIonite. This complex has a very large surface area, which includes large hydrophobic domains and is positively charged, about half of the cation exchange capacity of the clay. Two sets of filtration experiments were carried out at flow rates of 1.2 and 50 mL/min, which correspond to flow velocities of 3.7 and 153 cm/h, respectively. In the first case, after a passage of 1 L, the turbidity, total suspended solids （TSS）, fecal coliforms （FC）, and total coliforms （TC） were reduced to zero from 14 NTU, 6 ppm, 350 and 10,000 counts per 100 mL, respectively. In the second case, the numbers of FC and TC were reduced from 50,000/100 mL to zero after the passage of 14 L. The values of COD and BOD were reduced several-fold. The conclusion is that the incorporation of micelle-clay filters in the sewage treatment system with loose tertiary capability is promising and warrants larger scale experiments for optimization of the overall system.
文摘The nexus between water, food and energy is one of the most fundamental relationships and challenges for society. Indeed, seepage of wastes stored into dumping sites of Edea township, favor their lixiviation. Soluble components of matter are slowly dissolves, drained by meteoric water and flowed into tail bay vicinity. Knowledge of trace and toxic metal concentrations in the biotic matrices is important for assessing the effects of pollutants and the risk of exposure. In this study, A1, Mn, Cd, Cr, Cu, Pb and Zn were quantified respectively in 33 samples of soil and water, using ICP-MS （Inductively Coupled Plasma Mass Spectrometry）, Pb were found between 1.38-88.28 mg/L. Higher concentrations of Al were found in Alucam industrial wastes （315,502.33 mg/kg）, and in Hysacam domestic wastes （54,126.93 mg/kg）. Concentrations of Cd （1.955 mg/kg）, Pb （469.00 mg/kg） and Zn （853.00 rng/kg） are higher in domestic wastes. The ones of Mn （696.96 mg/kg） and Cu （1,320.10 mg/kg） are higher in industrial wastes. Higher concentrations of Pb and Cu let assume that it is a risk of poisoning relative to these elements around this area. These findings illustrate that lixiviation of dumping wastes has great influence on water and soils pollutions of the study ecosystem.
